Efficient PL Emission from p-type Porous Silicon: A Comparative Study for Selection of Effective Anodization Parameters

The physical mechanism of highly efficient photoluminescence (PL) emission from p-type silicon is described by a comparative study of the effectiveness of the etching parameters in an electrochemical anodization technique. Two series of porous silicon samples were prepared in a combination of anodization current and time, to maintain the total amount of anodic charge transfer constant. Photoluminescence studies show that irrespective of the amount of charge transfer, the samples prepared with comparatively higher current density show an efficient PL as well as stronger blueshift in the emission energy vis-à-vis the samples prepared for longer durations. An overall decrease in crystallite size, as estimated by Raman spectral analysis, was observed for both series of samples with the progress of charge transfer. Comparative analysis shows a marginal difference in crystallite size for both series of samples in the initial state of charge transfer, whereas major differences arise at higher values. This is explained with the formation of silicon suboxide on the porous surface at higher current density, leading to initiation of side wall reaction, and higher reduction rate in crystallite size as well as strong luminescence due to the carrier quantum confinement effect.     

Throughput performance of NOMA in WLANs with a CSMA MAC protocol

Wireless Networks - The existing medium access control (MAC) protocols are not able to utilize the full opportunities from power-domain non-orthogonal multiple access (NOMA) technique in wireless...     

Estimation of Limit Energy Characteristics of Volumetric Pneumatic Motors Taking into Account the Process Dynamics in Working Chambers

A methodology for estimation of the limit energy characteristics of volumetric pneumatic motors based on the Parameter Space Investigation method and a generalized mathematical model in dimensionless (normalized) form taking into account the dynamics of working processes is proposed. A calculated example is presented. The methodology is applicable for determination of the limit energy characteristics of newly created design solutions, of prospects to improve the known designs of pneumatic motors, of evaluation of energy capacity of several pneumatic motors supplied from a single source of compressed air, and of the initial data preparation for parametric synthesis of rotational pneumatic drives for two or more robots taking into account their interaction.     

Matrix Transformation in Boron Containing High-Temperature Co–Re–Cr Alloys

An addition of boron largely increases the ductility in polycrystalline high-temperature Co–Re alloys. Therefore, the effect of boron on the alloy structural characteristics is of high importance for the stability of the matrix at operational temperatures. Volume fractions of ε (hexagonal close-packed—hcp), γ (face-centered cubic—fcc) and σ (Cr₂Re₃ type) phases were measured at ambient and high temperatures (up to 1500 °C) for a boron-containing Co–17Re–23Cr alloy using neutron diffraction. The matrix phase undergoes an allotropic transformation from ε to γ structure at high temperatures, similar to pure cobalt and to the previously investigated, more complex Co–17Re–23Cr–1.2Ta–2.6C alloy. It was determined in this study that the transformation temperature depends on the boron content (0–1000 wt. ppm). Nevertheless, the transformation temperature did not change monotonically with the increase in the boron content but reached a minimum at approximately 200 ppm of boron. A probable reason is the interplay between the amount of boron in the matrix and the amount of σ phase, which binds hcp-stabilizing elements (Cr and Re). Moreover, borides were identified in alloys with high boron content.     

Waves in generalized thermo-viscoelastic infinite continuum with cylindrical cavity due to three-phase-lag time-nonlocal heat transfer

Abstract

Generalized thermoelastic interactions due to three-phase-lag time-nonlocal heat transfer in a Kelvin-Voigt type infinitely extended visco-thermoelastic continuum with cylindrical cavity has been investigated. The two-temperature generalized thermoelasticity theory has also been taken into account. The problem has been solved in the domain of Laplace on the assumption that the surface of the cavity is free from traction and is subjected to a smooth and time-dependent-heating effect. Laplace inversion of the transformed solutions has been carried out numerically. The obtained numerical data for different considerations are plotted in graphs to study the effects of time-nonlocal parameter, two-temperature parameter and visco-thermoelastic relaxation parameter on different thermoelastic quantities of physical interest.     

Conveyer-belt accidents in mining and metallurgy

The dynamic interaction between the mechanical and electrical drive parameters when damage suddenly appears in the mechanical part of a conveyer belt is investigated. The possibility of using the change in the motor’s electrical parameters as a diagnostic signal is assessed. A model for investigating the dynamic processes in the system consisting of the grid, the induction motor, and the conveyer belt is proposed. The grid and induction motor are described by a model of fourth-order state space, whose output is the torque at the motor shaft. The moments of inertia and pliability of the links between the elements in the mechanical part of the conveyer belt are determined. By gradually identifying the elements with the minimum moment of inertia and distributing their moments of inertia and pliabilities among the adjacent elements, we obtain a three-mass system simulating the mechanical part of the conveyer belt. This dynamic model is solved by means of Matlab Simulink software. The energy characteristics of the drive are determined in dynamic processes following a mechanical accident.     

Influence of Different Additives on the Interaction of Quinolone Antibiotic Drug with Surfactant: Conductivity and Cloud Point Measurement Study

Conductometric and cloud point (CP) measurement studies have been performed to investigate the interaction of tetradecyltrimethylammonium bromide (TTAB) and Triton® X-100 (TX-100) with ciprofloxacin hydrochloride (CFH) in different solvents over the temperature range of 295.15–315.15 K. CFH is used for the treatment of various bacterial infections. The observed critical micelle concentration (CMC) values of TTAB were found to be reduced in the presence of electrolytes (Na₂SO₄/Na₃PO₄), and this reduction proceeds with the elevation of salt concentration. The order of the CMC of TTAB follows the trend: > >. The observed CMC values of TTAB were found to increase with increasing temperature and decrease with increasing concentration of CFH in aqueous medium. The values of Gibbs free energy of micellization () for the TTAB/TTAB + CFH mixture were found to be negative, implying spontaneous micellization. The estimated CP of TX-100 decreases with increasing concentration of TX-100 in aqueous medium. The CP values first decrease with increasing concentration of CFH and then increase at higher concentration of CFH almost in all cases investigated. The values of free energy of clouding were found to be positive in all cases studied implying that phase separation of TX-100 was nonspontaneous. The other thermodynamic parameters associated with the micellization of TTAB and the phase separation of TX-100 were estimated and explained.     

Imaging of two-dimensional unsaturated moisture flows in uncracked and cracked cement-based materials using electrical capacitance tomography

The development of visualizing tools to monitor unsaturated moisture flow in cement-based materials is of great importance, as most degradation processes in cement-based materials are connected to and take place in the presence moisture. This paper investigates the ability of electrical capacitance tomography (ECT) to image two-dimensional (2D) unsaturated moisture flow in cement-based materials. In ECT, the electrical permittivity distribution within an object is reconstructed based on measured capacitances between electrodes attached on the object’s surface. In a series of experiments, mortar specimens with and without discrete cracks were imaged with ECT during a 2D moisture ingress. The results show that ECT is able to monitor the evolution of the moisture flow, and to approximate the shape and position of the moisture front. These findings indicate that ECT is a viable method for monitoring and visualizing 2D unsaturated moisture flow in cement-based materials in the presence and absence of discrete cracks.