Additive-aided electrochemical deposition of bismuth telluride in a basic electrolyte

A new basic electrolyte with two cationic plating additives,polydiaminourea and polyaminosulfone,was investigated for the electrochemical deposition of the bismuth telluride film on a nickel-plated copper foil.Tellurium starts to deposit at a higher potential(-0.35 V) than bismuth(-0.5 V) in this electrolyte.The tellurium-to-bismuth ratio increases while the deposition potential declines from-1 to-1.25 V, indicating a kinetically quicker bismuth deposition at higher potentials.The as-deposited film featu...     

高等教育与农村经济发展关联分析

本文从高等教育的角度入手,采用关联分析的方法研究了高等教育对农村经济发展的作用。并根据研究结果得出了一些关于发展高等教育和农村经济的建议。     

非典型SVOC结构构式义分析

根据构式语法,典型SVOC结构（即NP2后是名词短语和形容词短语）的构式义是致使变化。而SVOC结构研究中争议较大之处是如何看待和界定NP2后是非限定结构的情况。根据语义分析,这类情况中有些是属于非典型SVOC结构,其意义仍然是致使变化,而另外一些则应视为其它句式,如SVO。不同的学者从不同的角度出发往往得出不同的结论,这种情况从原型范畴理论的角度来看是完全可以理解并且是非常正常的。     

基于PDCA循环工作法实施科学化管装

针对当前我军科学化管装的现状,本文从提高科学化管装的水平入手,综合运用PDCA循环工作法的相关原理,结合当前的实际,就如何提高科学化管装水平进行了探索性的思考,并提出了相关的改进措施。     

Synthesis and characterization of soluble aromatic azopolyamides containing sulfone and ether units

A series of new polyamides 3a–d containing aryl-azo, ether and sulfone groups in the main chain were synthesized from bis[4-(4-aminophenoxy)phenyl sulfone] 1 and several azo aromatic diacyl chlorides 2a–d by the low temperature solution polycondensation technique. FTIR spectroscopy, nuclear magnetic resonance (NMR) and elemental analyses confirmed the structure of these polymers. Owing to the aryl and amide groups in the main chain, these polymers exhibit photochromic properties as well as excellent thermal stabilities. The transition temperatures (T _g) are between 242 and 265 °C, and the char yields at 800 °C in nitrogen atmosphere were above 39%. Based on incorporation of flexible ether linkages and polar sulfone groups, the polyamides show desirable solubility in organic solvents such as DMAc, N,N-dimethylformamide (DMF), N-methyl-2-pyrroidinone (NMP) and dimethylsulfoxide (DMSO). And it is exemplified that polyamide containing 2 and 2′ substitutes performed better solubility. Funded by the National Natural Science Foundation of China (No. 50572081)     

Evolution of carbides and carbon content in matrix of an ultra-high carbon sintered steel during heat treatment process

DTA, thermal expansion, XRD, and SEM were used to evaluate the effect of quenching temperature on the mechanical properties and microstructure of a novel sintered steel Fe-6Co-1Ni-5Cr-5Mo-1C. Lattice parameters and the mass fraction of carbon dissolved in the matrix of the steel quenched were investigated. It is discovered that the hardness of the steel increases with quench-ing temperature in the range of 840-900℃ and remains constant in the range of 900 to 1100℃. It decreases rapidly when the tem-perature is higher than 1100℃. The mass fraction of carbon dissolved in the matrix of the steel quenched at 840℃ is 0.38, but when the quenching temperature is increased to 1150℃, it increases to 0.98. The carbides formed during sintering are still present at grain boundaries and in the matrix of the steel quenched at low quenching temperatures, such as 840℃. When the quenching temperature is increased to 1150℃, most of the carbides at grain boundaries are dissolved with just a small amount of spherical M23C6 existing in the matrix of the quenched steel.     

Failure mode and strength anisotropic characteristic of stratified rock mass under uniaxial compressive situation

A stratified rock mass model was founded by FLAC^3D. The failure mode and anisotropic characteristic of strength for stratified rock mass were analyzed. The analysis results show that the numerical simulation can visually reflect the failure modes of rock samples under different inclination angles β of structural plane. The stiffness of rock sample before peak strength changes in the compressive procedure. With the increase of β, the compressive strength σ _c of rock sample decreases firstly and then increases; when β is in the range of 20°–30° and 80°–90°, σ _c has the largest sensitivity to β; while β falls in the range of 30°–70°, σ _c varies little. When ϕ _j <β<90° (β _j is friction angle of structure plane), the results obtained from numerical simulation and theoretical analysis are in almost the same values; while β⩽ ϕ _j or β=90°, they are in great different values. The results obtained from theoretical analysis are obvious larger than those from numerical simulation; and the results from numerical simulation can reflect the difference of compressive strength of rock samples for the two situations of β⩾ ϕ _j and β=90°, which is in more accordance with the real situation. Foundation item: Project (50099620) supported by the National Natural Science Foundation of China     

Feasibility analysis for monitoring fatigue crack in hydraulic turbine blades using acoustic emission technique

In order to investigate the feasibility of monitoring the fatigue cracks in turbine blades using acoustic emission (AE) technique, the AE characteristics of fatigue crack growth were studied in the laboratory. And the characteristics were compared with those of background noise received from a real hydraulic turbine unit. It is found that the AE parameters such as the energy and duration can qualitatively describe the fatigue state of the blades. The correlations of crack propagation rates and acoustic emission count rates vs stress intensity factor (SIF) range are also obtained. At the same time, for the specimens of 20SiMn under the given testing conditions, it is noted that the rise time and duration of events emitted from the fatigue process are lower than those from the background noise; amplitude range is 49–74 dB, which is lower than that of the noise (90–99 dB); frequency range of main energy of crack signals is higher than 60 kHz while that in the noise is lower than 55 kHz. Thus, it is possible to extract the useful crack signals from the noise through appropriate signal processing methods and to represent the crack status of blade materials by AE parameters. As a result, it is feasible to monitor the safety of runners using AE technique. Foundation item: Project(50465002) supported by the National Natural Science Foundation of China     

Preparation and mechanical properties of polypropylene fiber reinforced calcined kaolin-fly ash based geopolymer

To improve the environmental benefits and solve the problems of large shrinkage and high brittleness, the partial replacement of calcined kaolin by fly ash as a raw material for geopolymer synthesis and the influences of polypropylene (PP) fiber on the mechanical properties and volume stability were investigated. The results show that compressive strength of the geopolymer containing 33.3%(mass fraction) fly ash by steam curing at 80 °C for 6 d is improved by 35.5%. The 3-day compressive strength, flexural strength and impacting energy of geopolymers containing 0.05%PP fiber increase by 67.8%, 36.1% and 6.25%, while the shrinkage and modulus of compressibility decrease by 38.6% and 31.3%, respectively. The results of scanning electron microscopy (SEM) and the appearances of crack growths confirm that PP fiber can offer a bridging effect over the harmful pores and defects and change the expanding ways of cracks, resulting in a great improvement of strength and toughness. Foundation item: Project(2006AA06Z225) supported by the National High-Tech Research and Development Program of China     

攻击型无人机鲁棒导引律研究

文章研究了攻击型无人机鲁棒导引系统,采用对干扰和摄动具有自适应能力的滑动模态变结构控制方法设计了攻击型无人机滑模导引规律.针对用于消除颤振的伪滑动模态不能实现精确跟踪的缺陷,对滑模导引规律中颤振消除进行了优化设计,引入系统运动状态轨迹接近角变量,使消除颤振的伪滑动模态边界层宽度随着系统状态到达滑动模态而逐渐减小为零,从而达到了既能消除颤振又能实现精确跟踪的设计目标.通过仿真验证了该导引规律具有攻击弹道平缓、抗目标机动扰动能力强、鲁棒性好、制导精度高的优点.