Influence of Ge addition on the morphology and properties of TiN thin films deposited by magnetron sputtering

Thin films of TM-X-N (TM stands for early transition metal and X = Si, Al, etc.) are used as protective coatings. The most investigated among the ternary composite systems is Ti-Si-N. The system Ti-Ge-N has been chosen to extend the knowledge about the formation of nanocomposite films. Ti-Ge-N thin films were deposited by reactive magnetron sputtering on Si and WC-Co substrates at T_s = 240 °C, from confocal Ti and Ge targets in mixed Ar/N₂ atmosphere. The nitrogen partial pressure and the power on the Ti target were kept constant, while the power on the Ge target was varied in order to obtain various Ge concentrations in the films. No presence of Ge-N bonds was detected, while X-ray photoelectron spectroscopy measurements revealed the presence of Ti-Ge bonds. Transmission Electron Microscopy investigations have shown important changes induced by Ge addition in the morphology and structure of Ti-Ge-N films. Electron Energy-Loss Spectrometry study revealed a significant increase of Ge content at the grain boundaries. The segregation of Ge atoms to the TiN crystallite surface appears to be responsible for limitation of crystal growth and formation of a TiGe_y amorphous phase.     

Behavior of Composite Unreinforced Masonry–Fiber-Reinforced Polymer Wall Assemblages Under In-Plane Loading

An experimental investigation was conducted to study the in-plane behavior of face shell mortar bedded unreinforced masonry (URM) wall assemblages retrofitted with fiber-reinforced polymer (FRP) laminates. Forty-two URM assemblages were tested under different stress conditions present in masonry shear and infill walls. Tests included prisms loaded in compression with different bed joint orientation (on/off-axis compression), diagonal tension specimens, and specimens loaded under joint shear. The behavior of each specimen type is discussed with emphasis on modes of failure, strength and deformation characteristics. Results showed that the application of FRP laminates on URM has a great influence on strength, postpeak behavior, as well as altering failure modes and maintaining the specimen integrity. The retrofitted specimens reached compressive strength of 1.62–5.64 times that of their unretrofitted counterparts, depending on the bed joint orientation, and joint shear strength increased by eightfold.     

Scheduling two-stage hybrid flow shop with availability constraints

Most of the literature on scheduling assumes that machines are always available. However, in real life industry, machines may be subject to some unavailability periods due to maintenance activities such as breakdowns (stochastic case) and preventive maintenance (deterministic case). In this paper we investigate the two-stage hybrid flow shop scheduling problem with only one machine on the first stage and m machines on the second stage to minimize the makespan. We consider that each machine is subject to at most one unavailability period. The start time and the end time of each period are known in advance (deterministic case) and only the non-resumable case is studied. First we discuss the complexity of the problem. Afterwards, we give the Branch and Bound model for this problem. Last, we calculate the worst-case performances of three heuristics: LIST algorithm, LPT algorithm and H-heuristic.     

Constraint-based performance comparison of multi-dimensional interconnection networks with deterministic and adaptive routing strategies

Several studies have examined the relative performance merits of the torus and hypercube taking into account the channel bandwidth constraints imposed by implementation technology. While the torus has been shown to outperform the hypercube under the constant wiring density constraint, the opposite conclusion has been reached when the constant pin-out constraint is considered. However, all these studies have assumed deterministic routing and have not taken into account the internal hardware cost of routers. This paper re-examines the performance merits of the torus and hypercube using both fully-adaptive and deterministic routing strategies. Moreover, it uses a new cost model which takes into account the internal hardware cost of routers.     

Design, manufacture and evaluation of a new and simple mechanism for transmission of power between intersecting shafts up to 135 degrees (Persian Joint)

This paper introduces a new mechanism which is designed for the transmission of power between two intersecting shafts. The mechanism consists of one drive shaft and one driven shaft, six guide arms, and three connecting arms. The intersecting angle between the input shaft and the output shaft can be varied up to 135° while the velocity ratio between the two shafts remains constant. The research also includes a kinematic analysis and a simulation using Visual NASTRAN, Autodesk Inventor Dynamic and COSMOS Motion. The softwares showed that this mechanism can transmit constant velocity ratios at all angles between two shafts. By comparing the graphs of analytical analysis and simulation analysis, validity of equations was proved. Finally, by fabrication and evaluation of the mechanism it was shown that this mechanism can transmit constant velocity practically.     

Scaling study of cavitation pitting from cavitating jets and ultrasonic horns

Cavitation erosion prediction and characterization of cavitation field strength are of interest to industries suffering from cavitation erosion detrimental effects. One means to evaluate cavitation fields and materials is to examine pitting rates during the incubation period, where the test sample undergoes localized permanent deformations shaped as individual pits. In this study, samples from three metallic materials, an Aluminum alloy (Al 7075), a Nickel Aluminum Bronze (NAB) and a Duplex Stainless Steel (SS A2205) were subjected to a vast range of cavitation intensities generated by cavitating jets at different driving pressures and by an ultrasonic horn. The resulting pitted sample surfaces were examined and characterized with a non-contact 3D optical scanner and the resulting damage computer-analyzed. A statistical analysis of the pit population and its characteristics was then carried out. It was found that the various cavitation field strengths can be correlated to the measured pit distributions and that two characteristic quantities: a characteristic number of pits per unit surface area and unit time, and a characteristic pit diameter or a characteristic pit depth can be attributed to a given “cavitation intensity level”. This characterization concept can be used in the future to study the cavitation intensity of the full scale and to develop methods of full scale predictions based on model scale erosion data.     

Discrete-time chaotic-map truly random number generators: design, implementation, and variability analysis of the zigzag map

In this paper, we introduce a novel discrete chaotic map named zigzag map that demonstrates excellent chaotic behaviors and can be utilized in truly random number generators (TRNGs). We comprehensively investigate the map and explore its critical chaotic characteristics and parameters. We further present two circuit implementations for the zigzag map based on the switched current technique as well as the current-mode affine interpolation of the breakpoints. In practice, implementation variations can deteriorate the quality of the output sequence as a result of variation of the chaotic map parameters. In order to quantify the impact of variations on the map performance, we model the variations using a combination of theoretical analysis and Monte-Carlo simulations on the circuits. We demonstrate that even in the presence of the map variations, a TRNG based on the zigzag map passes all of the NIST 800-22 statistical randomness tests using simple post processing of the output data.     

On the design of suboptimal sliding manifold for a class of nonlinear uncertain time-delay systems

This paper proposes a new method to design suboptimal sliding manifolds for a class of nonlinear uncertain systems with state and input delays. A switching control law is obtained based on the designed suboptimal sliding manifold. It is proved that the proposed method is able to guarantee the stability of the closed-loop system in the presence of uncertainty. Three numerical simulations are given to illustrate the effectiveness of the proposed method.     

Convenient synthesis of sulfonamides from amines and p‐toluene sulfonyl chloride mediated by crosslinked poly(4‐vinylpyridine)

A general, mild, and convenient method has been developed for the synthesis of various N‐substituted and N, N‐disubstituted sulfonamides, as a class of sulfa drugs, from the corresponding amines and p‐toluene sulfonyl chloride in the presence of readily available crosslinked poly(4‐vinylpyridine) as a catalyst, base or polymeric substrates. The use of polymeric catalyst simplifies routine sulfonylation of amines because it eliminates the traditional purification. The polymer can be removed quantitatively and it can be regenerated and reused for several cycles without losing its activity. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012