Short-Injector Quantum Cascade Laser Emitting at 8-$mu$m Wavelength With High Slope Efficiency

This letter presents experimental results of a three-alloy-based short-injector quantum cascade laser (QCL). The investigated 4-mm-long device shows a pulsed threshold current density of 1.24 kA/cm² , a slope efficiency of 1.4 W/A, a characteristic temperature above 250 K, and a peak average output power above 726 mW at room temperature. A good high-temperature performance is attributed to the diagonal transition design and better depopulation of the lower laser levels at higher temperatures. The laser emission wavelength at room temperature is 8 mum, resulting in a low voltage defect of 71 meV per period for the QCL structure.     

Detailed energy saving performance analyses on thermal mass walls demonstrated in a zero energy house

An insulated concrete wall system¹ was used on exterior walls of a zero energy house. Its thermal functions were investigated using actual data in comparison to a conventional wood frame system. The internal wall temperature of massive systems changes more slowly than the conventional wall constructions, leading to a more stable indoor temperature. The Energy10 simulated equivalent R-value and DBMS of the mass walls under actual climate conditions are, respectively, 6.98 (m² °C)/W and 3.39. However, the simulated heating energy use was much lower for the massive walls while the cooling load was a little higher. Further investigation on the heat flux indicates that the heat actually is transferred inside all day and night, which results in a higher cooling energy consumption. A one-dimensional model further verified these analyses, and the calculated results are in good agreement with the actual data. We conclude that the thermal mass wall does have the ability to store heat during the daytime and release it back at night, but in desert climates with high 24-h ambient temperature and intense sunlight, more heat will be stored than can be transferred back outside at night. As a result, an increased cooling energy will be required.     

The Effect of ultra‐high speed twin screw extrusion on ABS/organoclay nanocomposite blend properties

Acrylonitrile butadiene styrene (ABS) nanocomposites containing Cloisite 11 organoclay at 2 wt% were prepared using a 60 L/D ultra‐ high speed twin screw extruder (TSE), with speeds ranging from 400 to 4000 rpm. The purpose of this study was to investigate the effect of high shear melt processing on the intercalation and exfoliation of organoclay in the polymer, as well as the mechanical and rheological properties of the material. X‐ray Diffraction (XRD), and Transmission Electron Microscopy (TEM) results showed better intercalation of the nanofiller with increasing screw speed up to a point, and indicated an exfoliated structure of the nanocomposites extruded at 4000 rpm. Mechanical and rheological testing results indicated that by adding organoclay to ABS, the properties improved with increasing screw speed up to an optimum value of 2000 rpm. However, at the higher screw speeds of 3000 and 4000 rpm, the intense shear history led to a decrease in properties, most likely due to chain scission and molecular weight reduction. Similar trends were observed in rheological properties of the nanocomposite as well. At 2000 rpm, the results indicate that the lowering of the molecular weight due to shear effects is balanced by good intercalation/exfoliation of the organoclay. POLYM. ENG. SCI., 57:60–68, 2017. © 2016 Society of Plastics Engineers     

Modeling of phase change material peak load shifting

This paper addresses potential peak air conditioning load shifting strategies using encapsulated phase change materials. The materials being considered here are designed to be installed within the ceiling or wall insulation to assist in delaying the peak air conditioning demand times until later in the evening. To assist in understanding the behavior of this material, an idealized model has been developed which uses the one-dimensional diffusion equation driven by time varying temperature functions imposed at the boundaries. In developing the model, the phase change temperature is a critical parameter, as is the latent heat of melting. These variables are treated parametrically. Other variables such as the characteristic ambient temperature variations and the thermostat set point are varied relative to the phase change temperature. Comparisons are made to the temporal variations of the heat flows without the application of the phase change material to those with the phase change material.     

Fecal indicator bacteria and Salmonella in ponds managed as bird habitat, San Francisco Bay, California, USA

Throughout the world, coastal resource managers are encouraging the restoration of previously modified coastal habitats back into wetlands and managed ponds for their ecosystem value. Because many coastal wetlands are adjacent to urban centers and waters used for human recreation, it is important to understand how wildlife can affect water quality. We measured fecal indicator bacteria (FIB) concentrations, presence/absence of Salmonella, bird abundance, and physico-chemical parameters in two coastal, managed ponds and adjacent sloughs for 4 weeks during the summer and winter in 2006. We characterized the microbial water quality in these waters relative to state water-quality standards and examined the relationship between FIB, bird abundance, and physico-chemical parameters. A box model approach was utilized to determine the net source or sink of FIB in the ponds during the study periods. FIB concentrations often exceeded state standards, particularly in the summer, and microbial water quality in the sloughs was generally lower than in ponds during both seasons. Specifically, the inflow of water from the sloughs to the ponds during the summer, more so than waterfowl use, appeared to increase the FIB concentrations in the ponds. The box model results suggested that the ponds served as net wetland sources and sinks for FIB, and high bird abundances in the winter likely contributed to net winter source terms for two of the three FIB in both ponds. Eight serovars of the human pathogen Salmonella were isolated from slough and pond waters, although the source of the pathogen to these wetlands was not identified. Thus, it appeared that factors other than bird abundance were most important in modulating FIB concentrations in these ponds.     

Bayesian analysis of empirical software engineering cost models

Many parametric software estimation models have evolved in the last two decades (L.H. Putnam and W. Myers, 1992; C. Jones, 1997; R.M. Park et al., 1992). Almost all of these parametric models have been empirically calibrated to actual data from completed software projects. The most commonly used technique for empirical calibration has been the popular classical multiple regression approach. As discussed in the paper, the multiple regression approach imposes a few assumptions frequently violated by software engineering datasets. The paper illustrates the problems faced by the multiple regression approach during the calibration of one of the popular software engineering cost models, COCOMO II. It describes the use of a pragmatic 10 percent weighted average approach that was used for the first publicly available calibrated version (S. Chulani et al., 1998). It then moves on to show how a more sophisticated Bayesian approach can be used to alleviate some of the problems faced by multiple regression. It compares and contrasts the two empirical approaches, and concludes that the Bayesian approach was better and more robust than the multiple regression approach     

Tuneable catalytic properties of hybrid microgels containing gold nanoparticles

A novel type of submicrometer-sized hybrid microgels containing gold nano-particles (AuNPs) has been tested as catalyst in reduction of 4-nitrophenol in aqueous medium. The influence of microgel concentration, gold content, as well as temperature of reaction medium on kinetics of 4-nitrophenol reduction process has been investigated. The pseudo-first-order kinetics was used to evaluate the catalytic reaction rate. It has been demonstrated that reaction rate of 4-nitrophenol reduction can be accelerated if the concentration of microgel in the reaction system or amount of gold nanoparticles loaded into microgels increases. Increase of reaction temperature resulted in rapid increase of reduction rate. Compared to pure gold nano-particles hybrid microgels at similar conditions reduce the activation energy of reduction process by a factor of 2. This indicates that localization of AuNPs within microgel template prevents their aggregation and therefore high catalytic activity can be preserved independently from reaction conditions. Additionally, polymeric template provides suitable environment for better mass transfer in present system that improves the catalyst efficiency.     

Passive building energy savings: A review of building envelope components

A significant portion of the total primary energy is consumed by today's buildings in developed countries. In many of these buildings, the energy consumption can be significantly reduced by adopting energy efficiency strategies. Due to environmental concerns and the high cost of energy in recent years there has been a renewed interest in building energy efficiency. This article strives to make an exhaustive technical review of the building envelope components and respective improvements from an energy efficiency perspective. Different types of energy efficient walls such as Trombe walls, ventilated walls, and glazed walls are discussed. Performance of different fenestration technologies including aerogel, vacuum glazing and frames are presented. Advances in energy efficient roofs including the contemporary green roofs, photovoltaic roofs, radiant-transmittive barrier and evaporative roof cooling systems are discussed. Various types of thermal insulation materials are enumerated along with selection criteria of these materials. The effects of thermal mass and phase change material on building cooling/heating loads and peak loads are discussed. Application of thermal mass as an energy saving method is more effective in places where the outside ambient air temperature differences between the days and nights are high. Air tightness and infiltration of building envelopes are discussed as they play a crucial role in the energy consumption of a building. Energy efficiency approaches sometimes might not require additional capital investment. For example, a holistic energy efficient building design approach can reduce the size of mechanical systems compensating the additional cost of energy efficiency features.