The kinetics of molybdenum dioxide oxidation

Powdered molybdenum dioxide was oxidized to MoO₃ in the temperature range 390 to 465°C under oxygen partial pressures of 0.016 and 0.18 atmospheres^* and under 0.009 atmospheres in the temperature interval 465 to 529°C. The course of the reaction was followed by observing weight change with time. Parabolic kinetics were evident for oxidation below 460°C. Above 460°C linear kinetics were observed. The partial pressure dependence at 407°C and 455°C was found to be approximately \(P_{O_2 }^{1/5} \) . Oxidation tests were restricted to an oxygen partial pressure of 0.009 atmosphere in the temperature range between 460°C and 530°C since above this partial pressure excessive heating occurred. For the low temperature range the oxidation was explained in terms of the diffusion of mono-and divalent oxygen interstitials. Activation enthalpies of 159±8 and 105±8 kJ/mole were obtained respectively for parabolic and linear rate processes.     

Eigenvalue sensitivity analysis of stiffened plates with respect to the location of stiffeners

This paper formulates the eigenvalue sensitivity of a stiffened plate with respect to stiffener location; the analysis is based on the generalized Rayleigh quotient of the combined platebeam system. The results show that the eigenvalue sensitivity is proportional to the force between the plate and the stiffener as well as to the slope of the eigenfunction at the interface between the plate and the stiffener.     

The cortisol response to psychological stress in temporomandibular dysfunction

Recombinant antibody fragments can be produced in large quantities using bacterial expression systems and could potentially be useful for the generation of biofilters for the selective removal of viral particles from fluids. A human single chain-Fv antibody library, derived from synthetic repertoires of germ line VH-gene segments rearranged in vitro and paired to a single light chain (Nissim et al., 1994, EMBO J., 13, 692-698), has recently been used to isolate hundreds of different binding specificities by panning with antigen. Antibodies from this library typically have affinities in the 10(6)-10(7) M-1 range. Occasionally, better binders are isolated but at other times the affinities recovered are poor. In the latter situation binding cannot be detected with soluble antibodies, but only by high-avidity display of multiple copies of antibodies on phage. By panning with human cytomegalovirus (HCMV)-coated immunotubes, we have isolated a number of antibody clones from this library that bound to the antigen only if displayed on the filamentous phage, but not in soluble form. One of these clones was selected for an affinity maturation procedure, achieved by combinatorial mutagenesis of the complementarity determining region 3 (CDR3) of the antibody light chain, followed by selection of the resulting library for HCMV binding. By this means, we were able to isolate a number of binders, some of which exhibited specific HCMV binding in soluble form. The clone that gave the strongest ELISA signal was expressed in bacteria, purified in solution, characterised using a novel capture methodology with surface plasmon resonance detection on a BIAcore instrument and used for the production of an immunofilter for the removal of HCMV form human serum. The filter removed more than 99% of applied HCMV in 10 min circulation time, while the amount of HCMV retained non-specifically in a cartridge derivatised with a non-specific antibody was less than 10% under similar conditions.     

星用光纤通信系统中的发光二极管的总剂量效应研究

介绍了星用光纤通信系统中的发光二极管在 6 0 Co- γ射线辐照下的总剂量效应试验研究 ,通过对不同剂量辐照情况下发光二极管的发光光谱、伏安特性及 P- I曲线进行测试 ,给出了在不同剂量的 γ- 6 0 Co射线辐照下发光二极管的发光光谱、伏安特性及 P- I曲线     

10 Gbit/s transmission over air-guiding photonic bandgap fibre at 1550 nm

The first data transmission over air-guiding photonic bandgap (PBG) fibre is demonstrated. A 10 Gbit/s signal was successfully transmitted at 1550 nm over 150 m of singlemode PBG fibre, thus demonstrating their applicability to optical communications. Furthermore, the impact of the polarisation properties of PBG fibres is highlighted experimentally.     

Relaxed multiple routing configurations: IP fast reroute for single and correlated failures

Multi-topology routing is an increasingly popular IP network management concept that allows transport of different traffic types over disjoint network paths. The concept is of particular interest for implementation of IP fast reroute (IP FRR). The authors have previously proposed an IP FRR scheme based on multi-topology routing called Multiple Routing Configurations (MRC). MRC supports guaranteed, instantaneous recovery from any single link or node failure in biconnected networks as well as from many combined failures, provided sufficient bandwidth on the surviving links. Furthermore, in MRC different failures result in routing over different network topologies, which gives a good control of the traffic distribution in the networks after a failure     

Mechanistic study of borosilicate glass growth by low-pressure chemical vapor deposition from tetraethylorthosilicate and trimethylborate

A reaction mechanism and film morphology as a function of reactor conditions and post growth thermal annealing for borosilicate glass (BSG), (SiO₂)_x(B₂O₃)_1−x, films deposited from tetraethylorthosilicate (TEOS), trimethylborate (TMB), and oxygen (O₂) precursors by low-pressure chemical vapor deposition (LPCVD) was determined. An empirically derived reaction model for BSG film growth is proposed that predicts the growth rate and composition of BSG films up to 70 mole% B₂O₃. The BSG reaction model includes a strongly adsorbed TEOS-derived intermediate that forms SiO₂ and a direct surface reaction of TMB, in O₂, to form B₂O₃. This model is supported by growth rate and mass spectroscopic data. The BSG film morphology, investigated using atomic force microscopy, was found to have a root-mean-square roughness of 0.5 nm, with the precise film morphology being a function of reactor conditions. The BSG film roughness increases with film thickness, temperature, and boron content. Thermal annealing of the films in a water-free environment leads to planarization of the BSG governed by the film composition and anneal temperature.     

用于频率合成的声表面波滤波器

介绍了几组用于扩频系统的声表面波滤波器的设计、制作和实验结果.器件频率为95～350MHz.插入损耗为9～24dB.阻带抑制优于45dB.     

Regularized Pre-image Estimation for Kernel PCA De-noising

The main challenge in de-noising by kernel Principal Component Analysis (PCA) is the mapping of de-noised feature space points back into input space, also referred to as “the pre-image problem”. Since the feature space mapping is typically not bijective, pre-image estimation is inherently illposed. As a consequence the most widely used estimation schemes lack stability. A common way to stabilize such estimates is by augmenting the cost function by a suitable constraint on the solution values. For de-noising applications we here propose Tikhonov input space distance regularization as a stabilizer for pre-image estimation, or sparse reconstruction by Lasso regularization in cases where the main objective is to improve the visual simplicity. We perform extensive experiments on the USPS digit modeling problem to evaluate the stability of three widely used pre-image estimators. We show that the previous methods lack stability in the is non-linear regime, however, by applying our proposed input space distance regularizer the estimates are stabilized with a limited sacrifice in terms of de-noising efficiency. Furthermore, we show how sparse reconstruction can lead to improved visual quality of the estimated pre-image.     

Cleaved and etched facet nitride laser diodes

Room-temperature (RT) pulsed operation of blue (420 nm) nitride-based multiquantum-well laser diodes grown on a-plane and c-plane sapphire substrates has been demonstrated. Structures investigated include etched and cleaved facets as well as doped and undoped quantum wells. A combination of atmospheric and low-pressure metal organic chemical vapor deposition using a modified two-flow horizontal reactor was employed. Threshold current densities as low as 12.6 kA/cm² were observed for 10×1200 μm lasers with uncoated reactive ion etched facets on c-plane sapphire. Cleaved facet lasers were also demonstrated with similar performance on a-plane sapphire. Laser diodes tested under pulsed conditions operated up to 6 h at RT. Lasing was achieved up to 95°C and up to a 150-ns pulselength (RT). Threshold current increased with temperature with a characteristic temperature T₀ of 114 K