白炭黑在ZSM-5分子筛工业合成中的应用

将不同比例的白炭黑替代B型硅胶作为固体硅源在水热体系中进行ZSM-5分子筛工业生产,合成质量合格的ZSM-5分子筛晶化料,且加入白炭黑后合成的分子筛晶化料相对结晶度较完全采用B型硅胶合成的分子筛晶化料明显提高。对白炭黑与B型硅胶物质的量比1:1作为固体硅源合成的ZSM-5分子筛晶化料进行改性,结果表明,改性后的成品ZSM-5分子筛质量稳定,理化性能优于100%B型硅胶合成的成品ZSM-5分子筛。     

Recent Advances on Black Phosphorus for Energy Storage,Catalysis, and Sensor Applications

As a new type of 2D semiconductor, black phosphorus (BP) possesses high charge‐carrier mobility and theoretical capacity, thickness‐dependent bandgap, and anisotropic structure, which has attracted tremendous attention since early 2014. To explore its full application in all aspects, studies based on BP nanostructures are swiftly expanding from the electronic field to energy storage and even biochemistry. The mechanism and application of BP in Li‐/Na‐ion battery anodes, oxygen evolution reaction/hydrogen evolution reaction catalysis, photocatalytic hydrogen production, and selective sensors are summarized. Based on the solid research on this topic, feasible improvements and constructive suggestions regarding these four fields are put forward.     

一个优化的低阶多项式累加和问题求解算法

本文针对低阶多项的多项式累加和问题∑n k=1 f(k),其中f(x)=c0+c1 x+…+cm-1 xm-1+cm xm,当多项式幂次m较小,累加项数n较大的情况下,根据二分求解思想,设计了一种高效的递推求解方法,其时间复杂度为O(m2 log n),而采用Horner格式计算多项式在每点的取值,再进行累加的朴素算法时间复杂度为O(mn),从而解决了在n>>m时,大大提高了低阶多项的多项式累加求和的效率.     

基于CPG的六足机器人运动步态控制方法

中枢模式发生器（CPG）在六足机器人的运动步态控制中起着至关重要的作用。为了研究六足机器人的运动控制方法,首先基于仿生学原理设计了六足机器人的机械结构,并在虚拟样机软件ADAMS中搭建其三维模型;其次选择Hopf振荡器作为CPG单元,并改进了振荡器模型;然后设计了六足机器人的CPG网络拓扑结构,包含单腿关节映射函数方案和腿间CPG环形耦合网络方案,并对其进行了改进;最后通过ADAMS和MATLAB联合仿真实验,验证了所设计六足机器人的运动稳定性和CPG控制方案的可行性与有效性。仿真结果表明,该方法能够满足六足机器人不同运动步态的控制需求,对六足机器人的运动控制具有一定的实际应用价值。     

φ7 800 mm吹风气余热回收装置在我厂的应用

南化公司氮肥厂大化肥装置目前正在进行改造，老合成氨系统造气炉采用低炉面温度操作，正常生产时，总吹风气量为62000m^3／h，其中C04340m^3／h，严重污染大气；另外，吹风气中含有一定量未燃烬的煤粉也对大气造成污染。新上φ7800mm吹风气回收装置利用水洗气、非渗透气和闪蒸气以及大化肥装置正常生产时产生的尾气作为助燃气，配入适当的空气后在燃烧炉内燃烧，放出热量加热格子砖，     

Grafting of glycidyl methylacrylate onto chlorinated polypropylene and its bonding to aluminum flake

Glycidyl methacrylate (GMA) was grafted onto chlorinated polypropylene (CPP) in the molten state using benzoyl peroxide (BPO) in the presence of styrene (St) as a comonomer. The differential scanning calorimetry (DSC) results indicated that the thermodynamic curve of unpurified grafted CPP was different from the purified, and showed a new broad endothermic peak at 100°C, which may be attributed to the glass transition temperature (T_g) of remained copolymer of GMA and St. Furthermore, transmission electron microscope (TEM) showed that there were two‐phase structures in the grafted CPP. Because the grafted CPP was to be used as a hot melt adhesive, so the influence of initiator concentration, monomer concentration, and reaction temperature on peel strength was investigated. The experiment results showed that a higher degree of grafting was obtained by using two kinds of monomers, such as GMA and St. Increasing the monomer concentration led to an initial rapid increase in the peel strength. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2515–2521, 2007     

Preparation and characterization of OH‐functionalized magnetic nanogels under UV irradiation

A novel preparation method of net magnetic polymer nanogels with swollen shell was developed. UV‐induced photopolymerization of 2‐hydroxyethyl methacrylate (HEMA) was performed in the magnetite aqueous suspension, free of any additive to obtain monodisperse magnetic nanogels with swollen shell. Owing to the step‐growth polymerization of the monomer, the particle size of magnetic nanogels can be conveniently manipulated by changing the irradiation time and the volume of the monomer dropped. The crystalline structure of Fe₃O₄ core and chemical composition of PHEMA magnetic nanogels were characterized by using X‐ray diffraction, Fourier transform infrared spectroscopy, and thermogravimetric analysis, respectively. Particle sizes, size distributions of magnetic nanogels in swollen state and dry state were measured by photo‐correlation spectroscopy (PCS) and transmission electron microscopy (TEM), respectively. The morphology of swollen magnetic nanogels and that of polymer capsules obtained from magnetic nanogels etched by hydrochloride acid were observed by TEM. The high magnetizations and superparamagnetic behaviors of naked Fe₃O₄ and magnetic nanogels at room temperature were confirmed by the measurement of hysteresis curves. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1283–1290, 2006     

基于单片机控制的程控开关电源研究

提出了基于单片机控制的程控开关电源解决方案,给出的主电路采用典型单端反激电路模式,控制电路采用51单片机为核心芯片,结合AD采样解决了控制功率开关管导通与关断信号PWM的控制问题.实现了开关电源输出电压为0.1 V/级的程控调节,其调节范围最大可达额定输出的76%.这种工作方式的建立使开关电源在设计上具有使用器件少、实...     

上海光源储存环磁铁支架隔振测试与分析

利用隔振原理,为磁铁支架设计了一种使用弹簧阻尼隔振器的隔振支撑方案,并在支架样机上进行了测试。测试结果显示,与刚性支撑方案对比,该支撑方式能有效地隔离垂向7 Hz以上,径向4 Hz以上的地面振动。由于低频的地面振动被放大,所以1～100 Hz总的振动幅度没有减小。因此,此支撑方案在实用前需要进一步研究采用主动控制的方法抑止低频振动放大。     

一种新型实用而简单的PCI系统配置方案

以PCI标准配置流程为基础，介绍了一种实用简单而又便于维护的技术方案，使得设计者可以根据系统的实际需要对PCI进行灵活配置。