Prozesskette zum stofflichen Recycling von Kunststoffabfällen

The material recycling rate for post-consumer plastic in Austria currently ranges around 25?%, because only post-consumer plastic fractions which are disposed as clean mono-materials are available for material recycling. A significant enhancement of the material recycling rate can be achieved with a process chain consisting of wet mechanical processing and thermochemical conversion. The wet mechanical process step enriches polyolefin and polystyrene from different waste sources, which are used as feedstock for a solvent-based, thermal depolymerisation. Via thermal cracking petrochemical intermediates (i.e. short- and long-chained, aromatic and paraffinic hydrocarbons) are produced, which can be appropriately fed into a conventional crude oil refinery and processed to marketable products. In this way, the material cycle can be closed economically feasible. Both the wet mechanical processing and the thermochemical conversion have been proofed in laboratory scale and are currently transferred to pilot scale.     

The use of nested desirability functions and quality indices for multi-response robust parameter design problems

A multi-response robust parameter design (RPD) problem-solving technique based on desirability functions is presented in which the means and variances of all responses are placed on a level playing field. The proposal allows a decision maker to integrate their preferences for the individual means and variances. It is shown that the ensuing operating point is a system setting that produces a mutually robust set of responses. In addition, this article offers an approach to assess several RPD strategies via quality indices. The measures presented here allow for a more knowledgeable and comprehensive evaluation of the competing RPD strategies.     

Variable heat flux in numerical simulation of grinding temperatures

In this paper, temperature results obtained by numerical simulations based on three different methods of defining the heat flux load distribution are compared to directly measured temperatures acquired using infrared camera measurement techniques. The heat flux calculations are based on recorded instantaneous grinding power, average grinding power, and power calculated by multiplying the measured tangential forces and the cutting velocity (referred to as calculated power). The results show that the method applied to characterize the input flux load in the numerical model has a significant effect on the estimated grinding temperatures and that the calculated power data produce the best temperature results.     

Environmental Control of Triplet Emission in Donor–Bridge–Acceptor Organometallics

Carbene‐metal‐amides (CMAs) are a promising family of donor–bridge–acceptor molecular charge‐transfer (CT) emitters for organic light‐emitting diodes. A universal approach is demonstrated to tune the energy of their CT emission. A blueshift of up to 210 meV is achievable in solid state via dilution in a polar host matrix. The origin of this shift has two components: constraint of thermally‐activated triplet diffusion, and electrostatic interactions between guest and polar host. This allows the emission of mid‐green CMA archetypes to be tuned to sky blue without chemical modifications. Monte‐Carlo simulations based on a Marcus‐type transfer integral successfully reproduce the concentration‐ and temperature‐dependent triplet diffusion process, revealing a substantial shift in the ensemble density of states in polar hosts. In gold‐bridged CMAs, this shift does not lead to a significant change in luminescence lifetime, thermal activation energy, reorganization energy, or intersystem crossing rate. These discoveries offer new insight into coupling between the singlet and triplet manifolds in CMA materials, revealing a dominant interaction between states of CT character. The same approach is employed using materials which have been chemically modified to alter the energy of their CT state directly, shifting the emission of sky‐blue chromophores into the practical blue range.     

Power-to-X im Kontext der Energiewende und des Klimaschutzes in Deutschland

In order to examine the impact of different Power-to-X technologies on the transformation of the German energy system and meeting the climate change mitigation goals, a cross-sectoral energy system model was developed. The results show that Power-to-X will be essential for a successful energy transition. Especially in applications where high energy densities are required and only few other options for defossilization exist, Power-to-X technologies become essential.