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961.
Reaction models are proposed to quantify the hydration products and to determine the composition of C–S–H from alkali-activated
slags (AAS). Products of the slag hydration are first summarized from observations in literature. The main hydration products
include C–S–H, hydrotalcite, hydrogarnet, AFm phases (C4AH13 and C2ASH8) and ettringite. Then, three stoichiometric reaction models are established correlating the mineral composition of slag (the
glass part) with the hydration products. Using the proposed models, quantities of hydration products and composition of C–S–H
are determined. The models are validated with a number of experimental investigations reported in literature, yielding good
agreement, i.e., these models can successfully predict the hydration reaction of AAS. The models are furthermore applied to
calculate the retained water in the hydration products of AAS in different hydration states and a general hydration equation
of AAS is derived. As an illustration to one of the model applications, chemical shrinkage of the AAS cement paste in different
hydration states are predicted. The chemical shrinkage of AAS is shown to be remarkably higher than OPC. Furthermore, phase
distribution in the hardened AAS paste and the porosity are calculated. 相似文献
962.
The effect of varying normalising and hardening temperatures on the prior austenite grain size in a low alloy Cr–Mo–Ni–V steel
has been examined. An initial relative insensitivity of grain size to increasing austenitising temperature was observed followed
by a sudden growth of grains at approximately 1000 °C. A detailed study of the precipitates in the steel showed the presence
of a bimodal size distribution of vanadium carbides. The grain size increase is attributed to a decrease in volume fraction
and an increase in size of V4C3 particles with increasing temperature. 相似文献
963.
The field emission characteristics of an oxidized porous polysilicon (OPPS) were investigated with a Pt/Ti multilayer electrode,
which showed highly efficient and stable electron emission characteristics compared with those of conventional Au/NiCr electrodes.
The thin Ti layer played an important role in promoting the adhesion of Pt to SiO2 surface and the distribution of the electric field on the OPPS surface. Additionally, the Ti layer efficiently blocked the
diffusion of emitter metal, which resulted in more reliable emission characteristics. 相似文献
964.
V. Thomas Paul S. Saroja P. Hariharan A. Rajadurai M. Vijayalakshmi 《Journal of Materials Science》2007,42(14):5700-5713
This paper presents the results of a study on the microstructural and microchemical variations in a multipass Gas Tungsten
Arc weld (GTAW) of modified 9Cr-1Mo steel. The changes brought about in the steel due to the heating and cooling cycles during
welding and the subsequent effects due to reheating effects during multipass welding are described. Detailed analytical transmission
electron microscopy has been carried to study the type and composition of the primary and secondary phases in this steel.
The systematic changes in microstructural parameters such as Prior Austenite Grain Size, martensite lath size, number density,
size and microchemistry of carbides, have been understood based on the different transformations that the steel undergoes
during the heating and cooling process. Based on the observed microstructure, an attempt has been made to identify distinct
microstructural zones and possible thermal cycles experienced by different regions of the weldment. 相似文献
965.
The present study concerns the effect of copper additions on the microstructural evolution and mechanical properties of directly
quenched Ti–B steels. Ti and B are added as microalloying elements with an aim of achieving adequate austenite hardenability
and Cu is added to retard the austenite (γ) → ferrite (α) transformation. Therefore, the microalloying and Cu additions together allow the transformation of austenite to occur at
a lower temperature, resulting in a finer microstructure containing martensitic constituents. The direct-quenching route is
adopted with an aim of facilitating the nucleation of the constituent phases from the deformed austenite. In order to circumvent
the hot-shortness due to the Cu addition, 0.79 wt% Ni has been added to one of the 1.5 wt% Cu microalloyed steels. The present
study has demonstrated that the Ni-containing 1.5Cu–Ti–B steel is capable of providing an attractive combination of strength
and ductility comparable to the high strength varieties of HSLA steels in directly quenched condition. 相似文献
966.
I. A. Ovid’ko 《Journal of Materials Science》2007,42(5):1694-1708
An overview of experimental study, computer simulations and theoretical models of fracture of nanocrystalline materials is
presented. The key experimentally detected facts on ductile and brittle fracture processes are discussed. Special attention
is paid to computer simulations and theoretical models of nucleation and growth of nanocracks and nanopores in deformed nanocrystalline
materials. Also, we discuss mechanisms for fracture suppression in such materials showing good ductility or superplasticity. 相似文献
967.
This article will review the development of the Fe–Ga (Galfenol) alloy system for magnetostriction applications including
work on substitutional ternary alloying additions for magnetic property enhancement. A majority of the alloying addition research
has focused on substitutional ternary elements in Bridgman grown single crystals with the intent of improving the magnetostrictive
capability of the Galfenol system. Single crystals provide the ideal vehicle to assess the effectiveness of the addition on
the magnetostrictive properties by eliminating grain boundary effects, orientation variations, and grain-to-grain interactions
that occur when polycrystals respond to applied magnetic fields. In almost all cases, ternary additions of transition metal
elements have decreased the magnetostriction values from the binary Fe–Ga alloy. Most of the ternary additions are known to
stabilize the D03 chemical order and could be a primary contribution to the observed reduction in magnetostriction. In contrast, both Sn and
Al are found to substitute chemically for Ga. For Sn additions, whose solubility is limited, no reduction in magnetostriction
strains are observed when compared to the equivalent binary alloy composition. Aluminum additions, whose effect on the magnetoelastic
coupling on Fe is similar to Ga, result in a rule of mixture relationship. The reviewed research suggests that phase stabilization
of the disordered bcc structure is a key component to increase the magnetostriction of Fe–Ga alloys. 相似文献
968.
Nina Georgieva Kostova Elka Kraleva Alla A. Spojakina Erika Godocikova Peter Balaz 《Journal of Materials Science》2007,42(10):3321-3325
The Al-MCM-41 has been used as support to prepare Mo-containing catalysts. The 12- molybdophosphoric heteropoly acid (HPMo)
is used as initial compound. The catalysts are synthesized by two different methods: incipient impregnation with aqueous solution
of the acid and mechanochemical synthesis. The samples were tested in the reaction of the thiophene hydrodesulfurization after
activation with mixture H2 + H2S. The effect of the preparation method of the catalysts on their physicochemical and catalytic properties has been studied.
A partial destruction of the loaded compound is observed in mechanochemically treated sample whereas the aggregates are formed
from the particles of different size in the impregnated sample. The specific surface area of the sample prepared by mechanical–chemical
treatment decreases 2–3 times, while the total pore volume is about four times lower. The HDS activity is higher on the impregnated
sample than on the mechanochemically treated one. 相似文献
969.
Improved visible-light responsive photocatalytic activity of N and Si co-doped titanias 总被引:1,自引:0,他引:1
Thermal reaction of titanium tetraisopropoxide and tetraethyl orthosilicate in 1,4-butanediol afforded nanocrystalline silica-modified
titanias having large surface area and superior thermal stability. In this study, the thus-obtained silica-modified titanias
were treated in an NH3 flow at high temperatures, and their physical and photocatalytic properties were investigated. Compared with NH3-treated TiO2 without silica modification, the NH3-treated silica-modified titanias showed a stronger absorption in the visible region (400–500 nm) and had a larger peak at
396 eV in the N 1s XPS spectrum. These results indicate that a larger amount of nitrogen was stably doped in the silica-modified
titania. The obtained products exhibited a high photocatalytic activity for degradation of Rhodamine B and decomposition of
acetaldehyde under visible light irradiation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
970.
The hydrolysis and condensation reactions of γ-APS have been studied in different acid content aqueous solution by using Fourier
Transform infrared (FT-IR) spectroscopy. The hydrolysis of γ-APS under the studied conditions can be followed by the increase
of the ethanol band located at 882 cm−1 and the decrease of the band due to the ρ(CH3) of γ-APS molecules located at 959 cm−1. Hydrolysis reaction is faster by increasing both H2O and acid concentrations, and it is completed when 3 moles of H2O per mole of γ-APS are used. The increase of the vibrational band located at 1146 cm−1 shows that condensation of the hydrolysed γ-APS molecules take place forming linear chains in poorly cross-linked structures.
Besides, both 8-membered cyclic siloxane formations and poorly cross-linked structures are formed and increase as the water
and acid content are increased. On the other hand, highly connected cross-linked structures do not appear due to the steric
hindrance of the non-hydrolysable aminopropyl group. The silanol band shows that hydrolysis is faster than condensation except
for samples with the lowest H2O content. 相似文献