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排序方式: 共有274条查询结果,搜索用时 15 毫秒
31.
Takehiko Tsukahara Hiroyasu Hotokezaka Masayuki Harada Yoshikuni Kikutani Manabu Tokeshi Yasuhisa Ikeda 《Microfluidics and nanofluidics》2013,14(6):989-994
We have developed a novel microchip equipped with a microchannel and Pt microelectrode array for electrochemically controlling valences of actinide (An) species. The square wave voltammograms of the redox reaction of potassium hexacyanoferrate(II) in the microchannel were measured. We found that the fabricated Pt microelectrode array has superior performances for the detection of the electrochemically active species in the microchannel. Therefore, the potentiostatic electrolysis experiments of uranium ions were carried out in the microchannel, and the concentration changes of uranium ions accompanied by the potentiostatic electrolysis were examined using thermal lens microscope. The results showed that the redox reactions between U(VI) and U(IV) can be performed completely in a microchannel in a few minutes, that is, the microscale reaction is accelerated by a factor of more than 10 compared with the bulk solution reactions taking hours mostly. The developed microchip was found to have enough performances for realizing rapid and highly efficient redox reactions for An species, which are impossible in the bulk reactions. 相似文献
32.
Shinichi Kitade Kazuo Asuka Isamu Akiba Yusuke Sanada Kazuo Sakurai Hiroyasu Masunaga 《Polymer》2013,54(1):246-257
Shear-induced crystallization of a long chain hyper-branched polypropylene (LCB-PP, denoted PP-3) was carried out at a relatively high temperature of 170 °C, close to its melting temperature of 158 °C. Small-angle X-ray scattering (SAXS) showed that the intensity ratio of the normal to the perpendicular to the shear (V/H) was always larger than 1 for PP-3, indicating that shish-like structures were predominately formed and further growth to kebab was suppressed in PP-3. The crystallization behavior of PP-3 can be explained by the nature of PP-3 that there were a large amount of crystallization nuclei due to their branching points, and the point-like precursors formed from these nuclei were arrayed linearly along the shear direction and transformed into thread-like precursors or premature shishs; however, owing to the large amount of branching, further progress in crystallization was suppressed. 相似文献
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34.
Hideaki Itoh Hisaaki Takao Hiroyasu Iwahara 《Journal of the American Ceramic Society》1993,76(11):2889-2895
Reaction sintering behavior of cBN, which is accompanied by the transformation from hBN to cBN in the presence of 30 wt% diamond seed grains, was investigated under high pressure conditions (6.0–7.5 GPa, 1400–1700°C, 0–30 min) using volatile catalysts such as NH4 NO3 , NH4 Cl, and NH2 NH2 . Fully dense sintered compacts having a Vickers microhardness of more than 5000 kg/mm2 were prepared with no residual catalytic solid components. The activation energy for the conversion from hBN to cBN was 200–230 kJ/mol. Adsorbed N2 , H2 , and/or NH x components which were formed by decomposition of these catalysts during high pressure and temperature treatments, would have a favorable kinetic effect on cBN formation from hBN and its simultaneous sintering. 相似文献
35.
36.
Oxide ion conductive solid electrolytes based on bismuthsesquioxide are reviewed. These electrolytes are characterized by their conductivities more than ten times higher than those of conventional oxide ion conductors such as stabilized zirconias. 相似文献
37.
Hiroyasu Ogiwara Osamu Horigami Yutaka Yamada Masako Satou Tasuku Kitamura Takayo Hasegawa 《Electrical Engineering in Japan》1996,116(2):10-20
Ag-sheathed Bi-2223 superconducting oxide conductors with a critical current density of 66,000 A/cm2 at 77 K and coils that have generated magnetic fields of approximately 1.5 Tesla at 4.2 K have been successfully developed. The conductors consist of piled-up bundles of four to six sheets of element tapes with transport currents of approximately 200 Amps. The core size limit (CSL) prevented the production of single conductors that had the capacity to transport a current as high as 200 Amps at 4.2 K. Until now, it was difficult to develop a conductor having both high critical current density and the capability of transporting a large amount of current simultaneously. The role of CSL in large scale applications of high temperature superconducting oxides is discussed. 相似文献
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39.
Tomohiro Maegawa Tohru Takahashi Masatoshi Yoshimura Hiroyasu Suzuka Yasunari Monguchi Hironao Sajiki 《Advanced Synthesis \u0026amp; Catalysis》2009,351(13):2091-2095
The chemoselective hydrogenation of unsaturated bonds and azide functionalities is achieved in the presence of nitro groups by a heterogeneous palladium catalyst supported on molecular sieves (MS3A). The present method shows a wide‐range of applicability with regard to substrates and the catalyst can be easily prepared and reused at least three times without any loss of activity. 相似文献
40.
Takashi Nozawa Takaaki Koyanagi Yutai Katoh Hiroyasu Tanigawa 《Journal of the European Ceramic Society》2019,39(8):2634-2647
SiC/SiC composites are promising structural candidate materials for various nuclear applications over the wide temperature range of 300–1000 °C. Accordingly, irradiation tolerance over this wide temperature range needs to be understood to ensure the performance of these composites. In this study, neutron irradiation effects on dimensional stability and mechanical properties to high doses (11–44 dpa) at intermediate irradiation temperatures (?600 °C) were evaluated for Hi-Nicalon Type-S or Tyranno-SA3 fiber–reinforced SiC matrix composites produced by chemical vapor infiltration. The influence of various fiber/matrix interfaces, such as a 50–120 nm thick pyrolytic carbon (PyC) monolayer interphase and 70–130 nm thick PyC with a subsequent PyC (?20 nm)/SiC (?100 nm) multilayer, was evaluated and compared with the previous results for a thin-layer PyC (?20 nm)/SiC (?100 nm) multilayer interphase. Four-point flexural tests were conducted to evaluate post-irradiation strength, and SEM and TEM were used to investigate microstructure. Regardless of the fiber type, monolayer composites showed considerable reduction of flexural properties after irradiation to 11–12 dpa at 450–500 °C; and neither type showed the deterioration identified at the same dose level at higher temperatures (>750 °C) in a previous study. After further irradiation to 44 dpa at 590–640 °C, the degradation was enhanced compared with conventional multilayer composites with a PyC thickness of ?20 nm. Multilayer composites have shown comparatively good strength retention for irradiation to ?40 dpa, with moderate mechanical property degradation beginning at 70–100 dpa. Irradiation-induced debonding at the F/M interface was found to be the major cause of deterioration of various composites. 相似文献