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951.
Reactions of N‐(2,4‐dinitrophenyl)pyridinium chloride (salt(Cl)) with H+MCl4?1 (M ≡ Fe and Bi) resulted in an anion exchange between Cl? and MCl4? to yield Zincke salts with metal chloride anions, namely salt(Fe) and salt(Bi), respectively. Reactions of the Zincke salts with piperazine resulted in ring‐opening of the pyridinium ring, yielding ionic polymers with 5‐piperazinium‐2,4‐dienylideneammonium metal chloride units, namely polymer(Fe) and polymer(Bi). The corresponding model compounds were synthesized via reactions using salt(Bi) or salt(Cl) as starting materials. The UV–visible spectra of the polymers had absorption maxima at longer wavelengths than those of the model compounds. This indicated that the π‐conjugation system is expanded along the polymer main chain. Superconducting quantum interference device measurements indicated that polymer(Fe) was paramagnetic. Cyclic voltammetry analysis suggested that the polymers underwent electrochemical oxidation. © 2019 Society of Chemical Industry 相似文献
952.
Panitha Phulkerd Takehiro Nakabayashi Shohei Iwasaki Masayuki Yamaguchi 《应用聚合物科学杂志》2019,136(7):47295
The effect of the nucleation efficiency of three commercial nucleating agents, such as 1,3:2,4-bis(3,4-dimethylbenzylidene)sorbitol (DMDBS), sodium 2,2′-methylene-bis-(4,6-di-tert-butylphenyl)phosphate (SMBP), and magnesium silicate (talc), on the melt-stretching performance of isotactic polypropylene (PP) is studied. It is found that the addition of 0.5 wt % of a nucleating agent enhances the crystallization temperature and that effect is pronounced for DMDBS and SMBP. Furthermore, DMDBS is more efficient than the other tested nucleating agents in enhancing the drawdown force, defined as a force required for stretching a molten strand. Nanofibers of DMDBS, which show significant alignment in the flow direction, are responsible for the rapid crystallization of PP in the flow field leading to an increase of drawdown force. The stretched strand shows a highly oriented structure in which the α-form crystals orient to the flow direction. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47295. 相似文献
953.
Masahito Ueda Tomoyuki Yamaguchi Teppei Ohno Yasuyuki Kato Tetsu Nishimura 《Advanced Composite Materials》2019,28(1):37-55
Carbon fiber reinforced plastic (CFRP) has electrical conductivity in both the parallel and transverse directions of the fiber. Because an electrical network may be changed with the applied strain, the electrical conductivity of the CFRP will also be changed for the piezoresistivity. Strain monitoring of CFRP can therefore be conducted, not by using an additional sensor, but by measuring the change in electrical resistance. There have been many studies on the gauge factors of unidirectional CFRPs, although significant mutual differences have been determined in the results reported. It is thought that the differences may be caused by the strong electrical anisotropy and inhomogeneity of the unidirectional CFRP. In this study, a new concept was introduced to precisely measure the gauge factors of a unidirectional CFRP. A finite element analysis was utilized to take into consideration a non-uniform electrical potential field in a unidirectional CFRP. The gauge factors were obtained as a result of minimizing the error sum of the squares of the electrical potentials between the experimental and analytical results. The gauge factor in the fiber direction was affected by this factor in the thickness direction depending on the specimen configuration. The results of the finite element analysis showed the possibility of a unidirectional CFRP showing both positive and negative gauge factors in the fiber direction. 相似文献
954.
This paper examines the cogging torque of a permanent magnet (PM) motor resulting from the asymmetry property of magnetic poles, which comes from the performance variation between magnets. A PM motor with 32 poles (= 16 pole pairs) and 36 slots is selected for verification, because the motor whose pole/slot ratio is 8/9 is sensitive to the performance variation between permanent magnets. Assuming that two different magnetization levels of magnets are mixed together in one rotor, the amplitude of the 2.25th and 4.5th components of cogging torque, which show 36 (= 2.25 × 16) and 72 (= 4.5 × 16) times of pulsation per rotation respectively and both of which result from the asymmetry property of the magnetic poles, are evaluated. As a result, it is clarified that the cogging torque characteristics depend on the alignment pattern of the two kinds of magnets. The amplitudes of the 2.25th and 4.5th components of cogging torque are proportional respectively to the amplitude of the 36th and 72nd order harmonics of the squared magnetic flux density around the rotor which is set in the space without stator. Using the proportional constants found from the finite element analyses in some alignment patterns, the cogging torque amplitudes of the motors with other alignment patterns can be predicted by calculating the squared magnetic flux density around the rotor only. The predicted cogging torque amplitudes correspond to the actually calculated results. © 2008 Wiley Periodicals, Inc. Electr Eng Jpn, 163(3): 57– 67, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20669 相似文献
955.
Satoshi Yamaguchi 《Electrical Engineering in Japan》2011,174(3):25-33
Differential Evolution (DE) is an evolutionary algorithm that has shown excellent ability for solving global optimization problems over continuous spaces. DE has a few control parameters that must be set by the user. The ability of DE depends on these control parameters, and in many cases, trial‐and‐error processes are required for finding suitable values. This paper proposes a method for tuning the DE control parameters automatically. The control parameters are tuned within the DE search process. When this method is used, the finding of appropriate control parameter values by trial and error is not required. To evaluate its performance, the proposed method was applied to nine benchmark function optimization problems. The results indicate that the proposed method achieved 100% success in solving optimization problems without a major increase in the number of generations required for finding the optimum solution. © 2010 Wiley Periodicals, Inc. Electr Eng Jpn, 174(3): 25–33, 2011; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.21047 相似文献
956.
Naoki Sasaki Toyohiro Uchiumi Yoshihisa Sugo Noboru Nishida Shigeatsu Yamaguchi 《Polymer Bulletin》1984,12(3):215-222
Summary Molecular motions of elastomers under deformations were observed through dynamic mechanical measurements. Composite master curves of dynamic moduli E and E and loss tangent tan over a wide range of frequency and in a state of elongation were obtained by the time-temperature superposition procedure. It is found that both moduli increase with strain, . The slope of the dispersion curve of E become more gradual with the increase in , while that of E is almost unchanged. The increment of E is generally larger than that of E, which does not agree with the N. W. Tschoegl prediction, E
*
()=f() E
o
*
(), where E
*
() and E
o
*
() are complex moduli at the strain of and O, respectively, and f() is the function of only . The difference in the strain dependence of E from E was found to correspond to the strain dependence of the equilibrium modulus. 相似文献
957.
We propose a new method of color management for a full-color holographic, three-dimensional (3D) printer, which produces a volume reflection holographic stereogram using red, green, and blue three-color lasers. For natural color management in the holographic 3D printer, we characterize its color reproduction characteristics based on the spectral measurement of reproduced light. Then the color conversion formula, which comprises a one-dimensional lookup table and a 3×3 matrix, was derived from the measurement data. The color reproducibility was evaluated by printing a color chart hologram, and the average CIELAB ΔE=13.19 is fairly small. 相似文献
958.
The modifications of dip-coated lead titanate (PT) and lead zirconate titanate (PZT) films strongly depend on the film thickness and the substrate in addition to the heat-treatment temperature. At 500 to 600 ° C, metastable paraelectric pyrochlore grew on glass plates (amorphous plates) when the thickness of the coated films produced by one coating cycle was below 100 nm, while ferroelectric perovskite formed on crystalline substrates or when thick films were coated on amorphous plates. This tendency is discussed in terms of an inhomogeneous reaction and the epitaxial effect. The perovskite PT films coated on single-crystal SrTiO3 plate at 700 ° C were strongly oriented to thec-axis. 相似文献
959.
Copolymerization of styrene (St) and butadiene (Bd) with CpTiCl3/methylaluminoxane (MAO) catalyst in the presence or absence of chloranil (CA) was investigated. The CpTiCl3/MAO catalyst showed a high activity for the copolymerization of St with Bd. The 1,4‐cis contents in the Bd units for the copolymerization of St and Bd with the CpTiCl3/MAO catalyst was observed, and the 1,4‐cis content was optimum at a MAO/Ti mole ratio of around 225. The effect of the polymerization temperature on the copolymerization was noted, as was the effect of the 1,4‐cis microstructure in the Bd units for the copolymerization of St and Bd. The addition of CA to the CpTiCl3/MAO catalyst was found to influence the molecular weight of the copolymer. The high weight‐average molecular weight copolymer (Mw = ca. 50 × 104) consisting of mainly a 1,4‐cis microstructure of Bd units (1,4‐cis = 80.0%) was obtained from the copolymerization with the CpTiCl3/MAO catalyst in the presence of CA (CA/Ti mole ratio = 1) at 0°C. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2942–2946, 2003 相似文献
960.
Surface instabilities in a capillary extrusion have been studied for various ethylene/α-olefin copolymers. It is found that the onset stress of shark-skin failure for ethylene/1-hexene copolymer (EHR) decreases rapidly with increasing 1-hexene content, whereas that of ethylene/propylene copolymer (EPR) is independent of propylene content in the experimental region. Consequently, EHR with high 1-hexene content exhibits shark-skin at low stress level compared to EPR. Lower rubbery plateau modulus, leading to higher Deborah number at the same stress level, is attributed to the lower onset stress. Further, the low entanglement density will cause cracks at lower stress level like glassy polymers, which is also responsible for the low onset stress for shark-skin. 相似文献