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排序方式: 共有1848条查询结果,搜索用时 15 毫秒
91.
92.
Hitoshi Kusama Yoshinari Konishi Hideki Sugihara Hironori Arakawa 《Solar Energy Materials & Solar Cells》2003,80(2):2533
The influence of alkylpyridines additive to an I−/I3− redox electrolyte in acetonitrile on the performance of a bis(tetrabutylammonium)cis-bis(thiocyanato)bis(2,2′-bipyridine-4-carboxylic acid, 4′-carboxylate)ruthenium(II) dye-sensitized TiO2 solar cell was studied. I–V measurements were performed using more than 30 different alkylpyridines. The alkylpyridine additives showed a significant influence on the performance of the cell. All the additives decreased the short-circuit photocurrent (Jsc), but most of the alkylpyridines increased the open-circuit photovoltage (Voc) and fill factor (ff) of the solar cell. The results of the molecular orbital calculations suggest that the dipole moment of the alkylpyridine molecules correlate with the Jsc of the cell. These results also suggest that both the size and ionization energy of pyridines correlate with the Voc of the cell. Under AM 1.5 (100 mW/cm2), the highest solar energy conversion efficiency (η) of 7.6% was achieved by using 2-propylpyridine as an additive, which was more effective than the previously reported additive, 4-t-butylpyridine. 相似文献
93.
94.
The H infin loop-shaping method is known to be an effective control method. However, it has two drawbacks. The first is that it is difficult to select appropriate loop-shaping weights, and the second is that the resulting controller is very complex. For the first drawback, Lanzon has proposed a suboptimal loop-shaping weight design method. It is formulated as a generalized eigenvalue minimization problem (GEVP). This suboptimal loop-shaping weight design method provides high-order weights, exacerbating the second drawback. To resolve these two drawbacks, a reduced-order loop-shaping weight design method is proposed for SISO systems in this paper. In the proposed method, the weight structure is first fixed, and the weight is then decomposed into a frequency-dependent vector and parameter matrices characterizing the loop-shaping weight. Since the open-loop constraints are represented as linear matrix inequalities with respect to the parameter matrices, the proposed reduced-order loop-shaping weight design problem for SISO systems is formulated as a GEVP, as well as Lanzon's suboptimal loop-shaping weight design method. The proposed method can reduce the designer's burden, although it is only valid for SISO systems. The effectiveness of the proposed method is verified experimentally by velocity control of a belt-driven two-mass system. 相似文献
95.
We attempted to produce a Ti45Zr38Ni17 bulk icosahedral (i) quasicrystal by a shock compression technique, in which a single-stage powder gun discharges a flyer plate that consolidates the target powders. The results were also compared with those by a conventional hot-pressing. The powder mixtures for the shock compression were blended by two kinds of methods; that is, gently mixing in a vial, and mechanically alloying by a planetary ball mill. A large bulk i-phase sample, with a Ti2Ni crystal phase, was synthesized from mechanically alloyed powders after shock compression at a higher flyer velocity, although the conventional hot-pressing at 3 MPa synthesized only the Ti2Ni phase. For the gently mixed powders, no reaction occured even after shock compression. High-pressure and high-temperature produced during shock compression, and milling process were key factors to obtain the i-phase. The Vickers hardness and the wetting contact angle with pure water under an atmospheric pressure for the bulk sample containing the i-phase were about 7 GPa and about 70°, respectively. 相似文献
96.
Hitoshi WADA Yasuhiro NISHISAKA Ryoichi ICHINO Masazumi OKIDO 《中国有色金属学会会刊》2009,19(4):791-794
The relatively uniform bismuth-copper film was electrodeposited between −15 and −20 mV in the sulfate electrolyte containing 4 mmol/L bismuth ion and 2 mmol/L copper ion. Only copper was electrodeposited at −5 mV. The dendritic bismuth-copper film was electrodeposited under −20 mV. The cathodic current became constant between −20 and −400 mV. Therefore, bismuth-copper electrodeposition changes from charge transfer controlling to diffusion controlling at −20 mV. On the other hand, the uniform bismuth-copper film was electrodeposited between −5 and −35 mV in the methanesulfonate electrolyte containing 4 mmol/L bismuth ion and 2 mmol/L copper ion. The dendritic bismuth-copper film was electrodeposited under −35 mV. The potential region for good electrodepositon in methanesulfonate electrolyte is wider than that in sulfate electrolyte. Therefore, it is easy to control electrodeposition conditions by using methanesulfonate electrolyte. 相似文献
97.
Naoya Katayama 《时间序列分析杂志》2009,30(5):487-504
Abstract. The portmanteau statistic based on the first m residual autocorrelations is used for diagnostic checks on the adequacy of fitting a model with varying m. In this article, we propose an approximation of the joint probability of multiple portmanteau tests with different degrees of freedom (DF). This distribution is easy to compute when all DF are even integers; its empirical behaviour is clarified in terms of asymptotic theory. 相似文献
98.
β-FeOOH thin film was prepared on the surface of a foamed Ni substrate by liquid phase deposition (LPD) method with a chemical equilibrium reaction between metal-fluoro complex and oxyhydroxide to make a low-cost and environmentally friendly positive electrode for high-power batteries. The new film electrode, with a thickness of 316 nm, was found out to give a large discharge capacity of 260 mAh g−1 at 0.05 C rate even without an electro-conductive material. Furthermore, the electrode also showed good discharge performance with the retention of 69.9% at 10-0.05 C current rate, which means a promising positive active material for high-power use. 相似文献
99.
S Katayama N Okada T Ohgitani T Kokubu Y Shimizu 《Canadian Metallurgical Quarterly》1998,60(8):905-909
The wild-type pseudorabies virus (WT-PRV) produced a round-type cytopathic effect (CPE) in PK-15 cell line of porcine kidney origin, while PRVgCs lacking in gC-transmembrane-anchor region and PRVgC-defecting in gC gene produced a syncytium-type CPE. The mouse embryo cell line (BALB/3T3 clone A31) were transfected with recombinant plasmid of pcDNA3 which incorporated with gC gene. The transfected A31/gC cells were stably expressing gC. Only a round-type CPE was observed in these cells infected with WT-PRV, while a syncytium-type CPE was observed in the cells infected with each of the PRVgCs and PRVgC-. Any viruses described above induced a syncytium-type CPE in A31/pcDNA cells transfected with a plasmid without gC gene. By WT-PRV infection, PK-15 cells generated about 2- or 8-fold more gC than the A31/gC and A31/pcDNA cells when gC was measured by hemagglutination test. Flowcytometric analysis revealed that amount of gC on the cell surface of A31/gC and PK-15 cells increased after infection with WT-PRV. Round-type CPE was observed with the increase of gC. These results suggest that the type of CPE formation induced by PRV is dominated by the amount of gC on the infected cell surface. 相似文献
100.
Hitoshi Maruyama Tohei Moritani Toshiyuki Akazawa Toshiaki Sato 《Polymer International》1988,20(4):345-351
Poly(vinyl alcohol) (PV-OH), prepared from poly(viny) acetate), is used widely in many industries. Various grades have been produced, with different degree of polymerization and degree of hydrolysis. Recently, novel modified (PV-OH)s with anion, cation, silanol or hydrophobic groups have been studied and developed. They have new properties in addition to those of ordinary PV-OH and have new applications. The methods of modification and the characteristics and some applications of the modified polymers are described. 相似文献