Integrated ion exchange mixed bed with reverse osmosis and nanofiltration for isolation of neutral dissolved organic matter from natural waters

The aim of this study was to isolate the neutral dissolved organic matter (NDOM) and the low molecular weight neutrals (LMWN) from natural waters. The coupling of an ion exchange mixed bed (IEXMB) with reverse osmosis (RO) and nanofiltration was the main hypothesis. IEXMB removed charged species, while the neutral molecules were isolated in the demineralised water and then concentrated by RO without any osmotic pressure or fouling limits. Neutrals isolation and unlimited concentration, gives this paper its originality. The nanofiltration (NF) step allows for the isolation of the LMWN. The studied reservoir water NDOM and LMWN represented respectively 35% of the dissolved organic matter (DOM) and 34% of the NDOM. Aromatic compounds were found in both fractions. The UV254 absorbance measured before and after the IEXMB evidenced the water quality ‘signature’. IEX has never been studied as fractionation method of DOM. This IEXMB approach is thus quite novel.     

Near- and Far-Field Characterization of Planar mm-Wave Antenna Arrays with Waveguide-to-Microstrip Transition

We present the design and characterization of planar mm-wave patch antenna arrays with waveguide-to-microstrip transition using both near- and far-field methods. The arrays were designed for metrological assessment of error sources in antenna measurement. One antenna was designed for the automotive radar frequency range at 77 GHz, while another was designed for the frequency of 94 GHz, which is used, e.g., for imaging radar applications. In addition to the antennas, a simple transition from rectangular waveguide WR-10 to planar microstrip line on Rogers 3003? substrate has been designed based on probe coupling. For determination of the far-field radiation pattern of the antennas, we compare results from two different measurement methods to simulations. Both a far-field antenna measurement system and a planar near-field scanner with near-to-far-field transformation were used to determine the antenna diagrams. The fabricated antennas achieve a good matching and a good agreement between measured and simulated antenna diagrams. The results also show that the far-field scanner achieves more accurate measurement results with regard to simulations than the near-field scanner. The far-field antenna scanning system is built for metrological assessment and antenna calibration. The antennas are the first which were designed to be tested with the measurement system.     

Stability analysis of inclined stratified two-phase gas-liquid flow

The present investigation involves the modeling of gas-liquid interface in a two-phase stratified flow through a horizontal or nearly-horizontal circular duct. The most complete and fundamental model used for these calculations is known as the one-dimensional two-fluid model. It is the most accurate of the two-phase models since it considers each phase independently and links both phases with six conservation equations. The mass and momentum balance equations are written in dimensionless form. The dimensionless mass and momentum balance equations are combined with the method of characteristics and an explicit method to simulate the flow. At first, the linear stability of the flow is investigated by disturbing the liquid flow with a small perturbation. An improved version of the one-dimensional two-fluid model for horizontal flows is developed as a set of non-linear hyperbolic governing equations. The importance of this research lies in obtaining a model that accounts for the effects of flow and geometrical conditions (such as liquid viscosity, surface tension). It is shown that, for positive values of the slope angle (upward inclination), the slug flow becomes more probable, whereas negative values of the slope angle (downward inclination) induce a more stable stratified flow.     

Scheduling commercial advertisements for television

The problem of scheduling the commercial advertisements in the television industry is investigated. Each advertiser client demands that the multiple airings of the same brand advertisement should be as spaced as possible over a given time period. Moreover, audience rating requests have to be taken into account in the scheduling. This is the first time this hard decision problem is dealt with in the literature. We design two mixed integer linear programming (MILP) models. Two constructive heuristics, local search procedures and simulated annealing (SA) approaches are also proposed. Extensive computational experiments, using several instances of various sizes, are performed. The results show that the proposed MILP model which represents the problem as a network flow obtains a larger number of optimal solutions and the best non-exact procedure is one that uses SA.     

Combined Effects of Baking Conditions and Bacterial α-Amylases on Staling Kinetics of Degassed and Porous Bread Crumb

Enzymes such as ??-amylase are extensively used to retard the staling process. Enzymes are acting both during fermentation and during baking. The objective of this work was to determine the relative action of ??-amylase during fermentation and during baking. The impact of the baking conditions (time, temperature) was also considered. To attain this aim, a degassed bread crumb was baked in a miniaturized system using two programs of baking: heating rates 10.27 and 6.88?°C/min corresponding to 180 and 220?°C baking temperatures, respectively. Mechanical and thermodynamic properties of the degassed crumb were assessed during aging of bread by determining the Young??s modulus E, the amount of freezable water, and the melting enthalpy of retrograded amylopectin. A first-order kinetic model was used to determine the different parameters of staling kinetics. Results showed that the hardening of crumb increased during storage. The kinetics were faster for samples baked with fast heating rate than for those baked with slow heating rates. The use of enzymes decreased the Young??s modulus but did not have any effect on the staling rate. Calorimetric analysis of the starch retrogradation showed a reduction of the amount of freezable water during storage with an increase of retrograded amylopectin. A comparison between mechanical properties of conventional crumb and of the degassed dough confirmed that experimental data fitted correctly the Gibson and Ashby??s model.     

Isolation and characterization of a new dimeric esterase from Lactobacillus sakei 23K

The M_w of a Lactobacillus sakei intracellular esterase, determined by gel filtration, was compared to those obtained from SDS-PAGE or MALDI-TOF, pointing to a dimeric structure. Its N-terminal sequence and peptide mass fingerprint suggest that it is the putative LSA044 protein from L. sakei 23K genome.     

The effect of various reaction parameters on bioremediation of perchlorate-contaminated water

The bioremediation was employed to treat perchlorate-contaminated water. All enrichments and growth of mixed cultures were performed in anaerobic acetate medium. Enrichment cultures were started with activated sludge obtained from a local wastewater treatment plant where it predominantly treats domestic wastewater. Several parameters affecting perchlorate removal were examined through batch experiments, these include the amount of domesticated sludge, the acetate concentration, pH, the C/N ratio and the reaction temperature. The results indicated that acetate was an effective carbon source and electron donor. Under the selected conditions, namely 1.0 g domesticated sludge, an acetate concentration of 1.2 g l(-1), pH 8.0, a C/N ratio of 20 at 40 degrees C, 50 mg l(-1) perchlorate could be rapidly reduced to non-detectable levels within 24 h.     

Effect of γ‐irradiation on the biophysical and morphological properties of corn

The effects of γ‐irradiation on the biophysical and morphological properties of corn plants were investigated. The irradiation doses were 0, 1, 1.5, 2.5, 5, and 10 krad. Corn grains exposed to 1.5 and 2.5 krad showed highly significant changes in all growth parameters. Fluorescence and light absorption spectra of chlorophyll attributed to different doses treatments of corn grains clearly confirmed the superiority of 1.5 krad irradiation dose in stimulating corn plants. Furthermore, the frequency dependence of the relative permittivity and the electric conductivity of the treated samples have been performed and discussed. The obtained results give another support via the biophysical properties for the 1.5 krad irradiation dose to be the most favorable one to improve the plant growth characteristics.