Theoretical expressions and mathematical analysis in cyclic reciprocal derivative chronopotentiometry (CRDCP) are presented for totally irreversible electrode processes corresponding to the application of symmetrical and unsymmetrical programmed currents. For two successive unsymmetrical programmed currents, the effect of the currents ratio b (b = |I2(t)/I1(t)|) on the (dt/dE)–E curves is discussed. The electrochemical behavior of totally irreversible electrode processes has been studied corresponding to the application of the unique unsymmetrical programmed Φm(I0) proposed recently. CRDCP characteristic parameters obtained for totally irreversible electrode processes are different from those of reversible electrode processes. Therefore, a comparison of CRDCP between both mechanisms is presented. Based on the mathematical derivation, alternative methods for kinetic measuring are described. It is prospected that CRDCP is convenient and applicable for studying the reversibility of the electrode processes in form of CRDCP characteristic parameters. 相似文献
Summary: This paper introduces a new inorganic poly(phosphazene disulfide) material. With unique element composition and molecular structure, the polymer has noncombustible safety and preferable conductivity. When used as cathode material for rechargeable lithium batteries, the polymer's first discharge capacity is as high as 467.9 mAh · g?1, which can be retained at 409.9 mAh · g?1 after 60 repeated cycles. Therefore, it has a great application potential in the field of lithium batteries.
Replacement of the Cl atoms by S? S groups by refluxing Na2S2 and linear poly(dichloro‐phosphazene). 相似文献
The main purpose of the paper is to display the relaxation oscillations, known as the bursting phenomena, for the coupled oscillators with periodic excitation with an order gap between the exciting frequency and the natural frequency. For the case when the exciting frequency is much smaller than the natural frequency, different types of bursting oscillations such as fold/fold, Hopf/Hopf bursting oscillations can be observed. By regarding the whole exciting term as a slow-varying parameter on the fact that the exciting term changes on a much smaller time scale, bifurcations sets of the generalized autonomous system is derived, which divide the parameter space into several regions associated with different types of dynamical behaviors. Two cases with typical bifurcation patterns are focused on as examples to explore the dynamical evolution with the variation of the amplitude of the external excitation. Bursting oscillations which alternate between quiescent states (QSs) and repetitive spiking states (SPs) can be obtained, the mechanism of which is presented by introducing the transformed phase portraits overlapping with the bifurcation diagrams of the generalized autonomous system. It is found that not only the forms of QSs and SPs, but also the bifurcations at the transition points between QSs and SPs, may influence the structures of bursting attractors. Furthermore, the amplitudes and the frequencies related to SPs may depend on the bifurcation patterns from the quiescent sates. 相似文献