溶胶-凝胶法制备Na_2WO_4~-Mn/SiO_2催化剂及其甲烷氧化偶联反应性能的研究

采用溶胶-凝胶法制备了一系列5%Na2WO4-2%Mn/SiO2催化剂;用XRD、XPS、BET、O2-TPD和CO2-TPD等方法对催化剂进行了表征,并考察了对甲烷氧化偶联反应的催化性能。结果表明,与常规浸渍法相比,采用溶胶-凝胶法制备的Na2WO4-Mn/SiO2催化剂中W和Mn的原子浓度在催化剂表面和体相分布较为接近,而且两种制备方法所得的催化剂具有相似的催化性能,Na2WO4与α-方石英之间的相互作用,催化剂释放晶格氧的能力,碱性强弱是影响甲烷氧化偶联活性的关键因素。     

关于天然气水合物钻采工艺技术进展的研究

目前全球正面临着前所未有的能源危机，天然气水合物由于储量大、能量密度高而将成为一种诱人的新型能源。天然气水合物主要存在于冻土带和海洋，在地下处于低温和高压状态，以现有的技术，钻井和开采都存在很大的困难。简要介绍了天然气水合物的性质及储量，阐述了天然气水合物钻井的六个挑战及目前国外天然气水合物的两种钻探方法；同时阐述了以热力法、降压法和化学试剂注入法为主的天然气水合物开采方法，并针对天然气水合物钻采技术现状指出了下一步的研究方向。     

LNG冷量优化集成利用技术

我国将相继在沿海地区建成多个LNG接收站，每年将进口数以千万吨计的LNG，同时携带数着巨额冷量，而这些冷量可用于发电、空气分离、制造干冰、低温冷库等众多领域。基于国外LNG冷量利用现状，指出我国即将展开和实施此项技术还存在着：过程火用损较大，缺乏系统、全面的LNG冷量利用技术的研发指导机制，以及宏观调控力度薄弱等问题，进而提出了发展LNG冷量的集成利用方案，可为此类技术的研发利用提供新思路。以福建即将进口的LNG为例，模拟了空气分离与干冰制备的集成工艺流程，结果表明：福建每年进口的260×10⁴t LNG可以冷却290×10⁴t空气，相当于60000 m³/h的氧气制备规模，还可以生产100×10⁴t的干冰，其过程火用损较小；其剩余的高温位冷量可应用于低温冻结库或冰灯等项目，这对主体装置的实施效果和过程火用损的影响较小。该技术的优点在于可灵活控制冷却空气的液化率，基本不用冷却循环水，流程简单，设备投资少，能耗低等。     

空气钻井技术在普光气田的应用

普光气田是四川盆地已发现的最大天然气田。普光气田已钻井实践表明,常规钻井液钻井技术机械钻速低,钻井周期长,钻井复杂及事故多,无法满足普光气田开发要求。为了提高钻井速度,缩短钻井周期,加快普光气田的开发进程,在PD-1井、P2-2井、PA-2井、P4-2井、P6-3井等5口井进行了空气钻井试验。文中分析了普光气田进行空气钻井的可行性,介绍了空气钻井技术在普光气田的实践情况,并对空气钻井的效果进行了评价,分析了空气钻井技术在普光气田进一步应用需要重视和解决的问题,并提出了今后的研究方向。     

Multiscale fragile watermarking based on the Gaussian mixture model.

In this paper, a new multiscale fragile watermarking scheme based on the Gaussian mixture model (GMM) is presented. First, a GMM is developed to describe the statistical characteristics of images in the wavelet domain and an expectation-maximization algorithm is employed to identify GMM model parameters. With wavelet multiscale subspaces being divided into watermarking blocks, the GMM model parameters of different watermarking blocks are adjusted to form certain relationships, which are employed for the presented new fragile watermarking scheme for authentication. An optimal watermark embedding method is developed to achieve minimum watermarking distortion. A secret embedding key is designed to securely embed the fragile watermarks so that the new method is robust to counterfeiting, even when the malicious attackers are fully aware of the watermark embedding algorithm. It is shown that the presented new method can securely embed a message bit stream, such as personal signatures or copyright logos, into a host image as fragile watermarks. Compared with conventional fragile watermark techniques, this new statistical model based method modifies only a small amount of image data such that the distortion on the host image is imperceptible. Meanwhile, with the embedded message bits spreading over the entire image area through the statistical model, the new method can detect and localize image tampering. Besides, the new multiscale implementation of fragile watermarks based on the presented method can help distinguish some normal image operations such as JPEG compression from malicious image attacks and, thus, can be used for semi-fragile watermarking.     

"十五"期间水电前期工作取得重要成就

“十五”是我国水电建设发展最快、成绩最大的重要时期。在党的十六大精神和国家大力发展水电方针的指引下,水电前期工作取得了重要成就。“十五”期末,已经完成和正在开展的预可行性研究项目53项,总装机容量约9 000万kW;可行性研究项目35项,总装机容量约4 000万kW。完成了全国水力资源复查工作,开展了大江大河河流(河段)的水电规划工作,谱写了水电前期工作的新篇章。     

个性化公开密钥系统的设计

论文提出利用用户提供的个性化信息来随机产生关联大素数,保证了素数选取的随机化、个性化,提高了RSA算法的安全性。     

A survey of quality of service in IEEE 802.11 networks

Developed as a simple and cost-effective wireless technology for best effort services, IEEE 802.11 has gained popularity at an unprecedented rate. However, due to the lack of built-in quality of service support, IEEE 802.11 experiences serious challenges in meeting the demands of multimedia services and applications. This article surveys 802.11 QoS schemes, including service differentiation in the MAC layer, admission control and bandwidth reservation in MAC and higher layers, and link adaptation in the physical layer, designed to meet these challenges by providing the necessary enhancements for the required QoS. Furthermore, the article addresses issues that arise when end-to-end QoS has to be guaranteed in today's pervasive heterogeneous wired-cum-wireless networks. Among these challenges, protocol interoperability, multihop scheduling, full mobility support, and seamless vertical handoff among multiple mobile/wireless interfaces are specifically addressed.     

井下电视检测系统在水井施工中的应用

简要介绍了井下电视在大港油田水源井水井结构检测、井管故障检测、指导落物打捞、水源井验收、地层结构检测及水源井地层受力分析等方面的应用情况，及应用井下电视检测所取得的经济效益和社会效益。     

单向实时数字视频传输中帧同步锁定技术研究

提出一种适用于单向实时数字视频传输系统的帧同步锁定方案。其方法在接收端采用本地参考时钟、状态机、锁相环，并结合CIMT编码方式实现系统自动维持帧同步锁定，而无需周期性加入帧同步码。对该帧同步锁定方案与周期性加入帧同步码强制锁定方案进行性能比较．并将其应用到单向实时数字视频光纤传输系统中。实验证明，系统自动实现帧同步锁定的方案是单向实时数字视频传输系统实现帧同步锁定的最佳方案。