Feasibility analysis of membrane reactors – discovery of reactive arheotropes

A feasibility analysis methodology adopted from reactive distillation is applied to membrane reactors. A model is formulated to depict the reactive liquid phase composition on the retentate side of a continuous type membrane reactor. The effects of both the chemical reaction kinetics and the membrane mass transfer kinetics on the feasible products are elucidated by means of retentate phase diagrams and bifurcation analysis. The proposed method can be applied to various membrane processes, independent of the specific structure of the membrane. Two quaternary reaction systems are considered to illustrate the methodology. In the first hypothetical system, it is shown how selective membranes can influence the sequence of effective volatilities which in turn affects the feasible products of the system. In the second example of practical importance, i.e. the heterogeneously catalysed synthesis of propyl acetate coupled with permeation through a porous polycarbonate membrane, the dusty gas model is applied to describe the component fluxes through the membrane. For the latter reaction system, the existence of reactive arheotrope is demonstrated. Arheotropes represent mass transfer controlled feasible products of membrane separation process.     

钛铜复合棒及其标准化

概述了钛铜复合棒研制开发及发展历程,并介绍了钛铜复合棒的主要性能,以及钛铜复合棒的标准化情况。     

Effects of contact shape on biological wet adhesion

Wet adhesion is widely adopted in biological adhesion systems in nature. Wet adhesion is studied in this paper with the focus on the effect of different contact shapes (flat, concave, convex, and ring-like) on the adhesion force. The evolution of the liquid bridge between a fiber tip and substrate during the detaching process shows two transition points. The first transition from the radius-controlled to the contact-angle controlled process is critical to influence the strength and robustness of adhesion. We show that a concave shape is more effective than a flat one, while a convex shape has no advantage. A ring-like contact shape has advantages in a hydrophobic environment and on a rough surface.     

Preparation of BaMgAl10O17∶Eu2+ and Its Phase Behavior in Microemulsion System

BaMgAl10O17∶Eu2 (BAM) was prepared in the microemulsion system and its phase behavior was studied. There exists a small region in the reverse microemulsion system where the dispersed particles are of spherical form. In this way, BAM blue phosphor with good dispersion can be synthesized. The microemulsion phase diagrams of the pseudo-ternary system (Triton X-100/cosurfactant-oil-BAM brine) were first established intuitively by the dilution method. The microstructure of microemulsions was determined through eyeballing, conductance technique, and polar optical microscopy. Its phase behavior is affected by various factors, such as temperature (room temperature, 30, 40 ℃), oil, surfactants, and cosurfactants in microemulsions. According to the phase diagrams, the microemulsion system of Triton X-100/1-hexanol-hexane-BAM brine was chosen to prepare the precursor. The BAM phosphor can be obtained via sintering the precursor at a comparatively low temperature. The phosphors were characterized by XRD and vacuum ultraviolet (VUV) spectra.     

Integrated carbon nanotube field emission differential amplifier: Modeling and measurement of the common-mode rejection ratio

A novel integrated vacuum field emission (VFE) differential amplifier (diff-amp) utilizing carbon nanotube (CNT) emitters has been developed. A dual-mask microfabrication process was employed to achieve a VFE diff-amp by integrating identical CNT VFE transistors with built-in split gates and integrated anodes. The identical pair of triode amplifiers was well-matched in their device characteristics. The measured ac small-signal characteristics of the diff-amp showed a common-mode-rejection ratio (CMRR) of ~ 320 (~ 50 dB). The proposed analytical model of the CMRR was verified to be in good agreement with the experimental data. The successful implementation of the CNT diff-amp demonstrates a new way to achieve temperature and radiation tolerant VFE integrated microelectronics.     

推行岩土工程体制,降低工程造价与勘探成本

推行岩土工程体制,在确保给定的安全水平条件下达到综合造价最低的目的。     

ERP管理系统下的物料代码体系研究和应用

随着计算机及网络技术在现代企业生产经营管理中的广泛应用，特别是以网络为信息交流平台的企业CMIS、ERP和MRPII等管理系统的应用推广，使得企业生产经营的管理技术和理念相比传统管理的方式、方法也发生了根本性的变化。企业内外形成和交流的信息量成倍增加，组织生产经营信息逐步表现为操作流程规范化、信息应用集成化和信息环境复杂化的趋势，从而使得组织信息交流语言及接口的规范统一，标准化也日显重要。     

A Low-Power CMOS Linear-in-Decibel Variable Gain Amplifier With Programmable Bandwidth and Stable Group Delay

This brief presents a new circuit architecture for linear-in-decibel, constant-bandwidth variable gain amplifier (VGA). To obtain high linearity under low-voltage operation, this VGA is a closed-loop structure. In loop amplifier design, two techniques are applied: first, the loop amplifier is given finite input impedance. This arrangement keeps the VGA bandwidth constant under different gain setting. Second, a current-buffered compensation is applied for loop stability. Compared to the Miller compensation, this method achieves wider bandwidth. The prototype chip using 0.18-mum CMOS technology demonstrates that -10- to 20-dB gain and 0.5- to 30-MHz bandwidth can be programmed independently. The group delay difference within 30-dB gain control range is smaller than 1%. The total circuit dissipates 1.35 mA from a 1.8-V supply