Ozonation of CI Reactive Black 5 using rotating packed bed and stirred tank reactor

This study investigates the ozonation of CI Reactive Black 5 (RB5) by using the rotating packed bed (RPB) and completely stirred tank reactor (CSTR) as ozone contactors. The RPB, which provides high gravitational force by adjusting the rotational speed, was employed as a novel ozone contactor. The same ozone dosage was separately introduced into either the RPB or the CSTR for the investigation, while the experimental solution was continuously circulated within the apparatus consisting of the RPB and CSTR. The decolorization and mineralization efficiencies of RB5 in the course of ozonation are compared for these two methods. Moreover, the dissolved and off‐gas ozone concentrations were simultaneously monitored for the further analysis. As a result, the ozone mass transfer rate per unit volume of the RPB was significantly higher because of its higher mass transfer coefficient and gas–liquid concentration driving force. Furthermore, ozonation kinetics was found to be independent of the gravitational magnitude of an ozone gas–liquid contactor. Therefore, the results suggest employing RPBs as ozone‐contacting devices with the advantage of volume reduction. The experimental results, which can be used for further modeling of the ozonation process in the RPB, also show the requirement of correct design for the RPB. Consequently, the present study is useful for the understanding of practical application of RPBs. Copyright © 2004 Society of Chemical Industry     

A neural network model for fault detection in conjunction with a programmable logic controller

This paper discusses the feasibility of using neural networks as a tool in the fault detection process. A neural network is integrated with a state language programmable logic controller, an important device in an automatic control system. Time series data related to time spent in a state is gathered and used as input into a neural network, for the purpose of identifying when a fault has occurred. A feedforward neural network is used to identify which (if any) of three types of faults may have occurred. Experimental results related to sensitivity and accuracy measures are presented. A brief review of related applications and research is also presented.     

Benign seizures associated with mild diarrhea: clinical analysis of 20 cases

Even without electrolyte imbalance, dehydration and fever, seizures are found occasionally in the cases of mild diarrhea. Such patients have shown favorable outcome during long-term follow-up. Twenty cases (10 boys and 10 girls) of benign seizure with mild diarrhea have been diagnosed at the Pediatric Department of Cathay General Hospital from January 1987 to March 1991. Ages-of-onset ranged from 3 months to 43 months (mean 19 months). Most cases were found between December and March (16 cases, 80%). Most seizure episodes were from 2 to 5 times (10 cases, 50%); the durations of seizures were mostly within a 5-minute period (16 cases, 80%). All seizures were generalized and symmetric, including tonic-clonic (13 cases, 65%), tonic (5 cases, 25%), and clonic (2 cases, 10%). Six out of 11 cases (54.5%) showed Rotazyme (Latex agglutination) positive. After six month to four year follow up, no patient had suffered any type of epilepsy, and psychomotor development was normal in all. Further discussion of clinical features is provided.     

Efficacy of surgical treatment in traumatic central cord syndrome

BACKGROUND: Controversy surrounds the treatment of traumatic central cord syndrome (TCCS), as there are strong advocates for nonsurgical treatment for most patients. However, conservative treatment has been shown to yield a longer period of discomfort from pain and weakness in certain cases. METHODS: In a retrospective review of 114 patients presenting with acute or chronic TCCS from 1988-94, four different age groups were separately observed under different treatments. Motor and sensory recovery were assessed. RESULTS: Better results were achieved in younger patients, with or without radiographic abnormalities, and in patients with clinically correlated encroaching cord lesions who received early surgical decompression. CONCLUSIONS: Surgical intervention for TCCS must be addressed with careful clinical and radiographic survey. Removal of offending lesions in the subacute period results in significant motor and sensory improvement in short-term and long-term follow-up.     

High performance analog VLSI computational circuits

Simple linear voltage/current-controlled voltage-to-current (V-T) converters, which are to first-order insensitive to the threshold voltage variation, are introduced. The circuits can be used as basic building blocks to construct simple analog computational circuits, which can perform functions such as square rooting, squaring, multiplication, sum of squares, difference of squares, etc. Some of the key features are: good linearity, floating inputs [high common-mode rejection ratio (CMRR)], simplicity, and good transconductance tuning range. The circuits can be realized with CMOS devices in saturation, however, BiCMOS devices extend their speed and input voltage range. Realistic simulations and experimental results clearly demonstrate the claims     

Crystallinity variations in kaolinite induced by grinding and pressure treatments

Kaolinite samples treated with uniaxial pressures higher than 0.1 GPa or grinding times greater than 0.3 h show changes in their crystallinity. These changes are easily detected by the X-ray diffraction (XRD) technique and can be quantified from Hinckley (HI), Lietard (R₂) and also reference intensity ratio (RIR) index studies. The sensitivity of these indices to the Crystallinity changes is; HI>RIR>R₂. In the range of pressures and grinding times considered, these values can be diminished by 50%. The variations in these indices with either the pressure or grinding time follow logarithmic laws whose correlation coefficients are closed to unity. Infrared (IR) spectroscopy and thermal analysis studies show low sensitivity to the changes introduced by grinding or pressure. Nevertheless, thermal gravimetric curves confirm the decrease in the dehydroxylation starting point of about 100°C for the pressed and ground samples. Transmission electron microscopy (TEM) reveals important changes in kaolinite particle morphologies after pressure and grinding treatments. The samples compressed at 0.1, 0.32, 0.85, 1.0 and 2.0 GPa show a large number of defects (fractures, bending, deformations and rolling of layers, glide and rotation of the shell). The ground samples show grain boundaries, dislocations, twins and rounded voids. These defects are responsible for the decrease in crystallinity of the kaolinite samples shown in the XRD and IR studies.     

Fast acquisition clock and data recovery circuit with low jitter

This paper presents a half-rate clock and data recovery circuit (CDR)that combines the fast acquisition of a phase selection (PS) delay-locked loop (DLL) with the low jitter of a phase-locked loop (PLL). The PLL acquisition time improves considerably with use of a phase frequency magnitude detector(PFMD) that feeds back an estimate of the magnitude of the frequency difference in addition to the sign. Measurements in 0.5/spl mu/m CMOS technology show operation up to 700 Mb/s, a 7% acquisition range, an initial acquisition time of 8 bit times with jitter of 30% bit time, and jitter of 16 ps after the PLL acquires lock. With a phase frequency detector (PFD), the PLL locks in about 700 ns from an initial frequency difference of 7%. Measurements using a PFMD show the 700 ns PLL acquisition time is reduced on average by about a factor of 5 to 140 ns from an initial 7% frequency difference. The power dissipation is 300mW.     

Characterization of ultrashort optical pulses with third-harmonic-generation based triple autocorrelation

We present a method to obtain complete information of femtosecond pulses. By measuring triple-optical autocorrelation directly with third-harmonic generation, without spectral information, a temporal pulse shape can be obtained by analytical calculation without direction-of-time ambiguity. Combining the resulting optical pulse shape with its corresponding optical spectrum, the exact phase and color variations in time can all be recovered with a Gerchberg-Saxton algorithm through an iterative calculation with an O(n) complexity.     

The geometric nature of plasticity laws

This paper concerns the plasticity constitutive laws in small strain. In the thermodynamic approach developed here, the key concept is that of internal variables. The differential nature of plasticity law has been pointed out for a long time. If we unite the invariance condition of these laws in a state variable transformation, this involves, ultimately, that the natural mathematic frame of plasticity theory is Differential Geometry. The system state is defined as a point of a differentiable manifold. The state variable are the local coordinates of this point in a chart. The internal stresses are the components of a covariant vector of the cotangent bundle to internal state manifold and the elastic domain is a convex part of cotangent vector space. The plastic yield criteria such as von Mises condition define a Riemannian structure over the manifold. The metric element is identified with the internal dissipation element. Constitutive laws link the covariant derivatives of the thermodynamic stress with the state variable. Hardening modulus splits up in two parts, kinematic hardening and metric hardening. This last is defined by Christoffel connection coefficients. Applied to von Mises isotropic yield condition, the metric hardening is identified with isotropic hardening. The Baltov-Sawczuk model is also analysed. The use of appropriate polar coordinates simplifies significantly the computations. Generalization to a significant category of non-differentiable yield criteria, such as Tresca condition, is considered by introducting a metric tensor family. The adaptation of Drucker's postulate to the proposed model requires the introduction of parallel transport of the internal stress covector. Generally, this transport is different over distinctive paths joining two points. This fact expresses internal state manifold curvature. The Riemann-Christoffel tensor is computed for von Mises, Baltov-Sawczuk and Tresca models.