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991.
研究天然胶乳/椰丝的硫化性能,探讨硫化促进体系和防老化体系对材料性能的影响。结果表明,促进剂TMTD/CZ体系材料焦烧时间为8min,具有较好的加工安全性;防老剂DOD体系尽管防热氧老化性能相对于防老剂4010/D体系稍差,但无毒、无害,可最大限度地提高二次使用的回收率。 相似文献
992.
993.
This work has demonstrated that the addition of an optimum content of dimethyldioctadecylammonium chloride (DDAC)-modified montmorillonite clay (Dclay) enhances the ionic conductivity of the plasticized poly(methyl methacrylate)-based electrolyte by nearly 40 times higher than the plain system. Specific interactions among silicate layer, carbonyl group (CO) and lithium cation have been investigated using Fourier-transform infrared (FTIR), solid-state NMR, alternating current impedance. The FTIR characterization confirms that both of the relative fractions of ‘complexed’ CO sites and ‘free’ anions increase with the increase of the Dclay content, indicating that strong interaction exists between the CO group and the lithium salt. In addition, the solid-state NMR demonstrates that the interaction between the PMMA and the clay mineral is insignificant. The addition of clay mineral promotes the dissociation of the lithium salt and thus, the specific interaction can be enhanced between the CO and the free lithium cation. However, the balanced attractive forces among silicate layers, CO groups, lithium cations and anions is critical to result in the higher ionic conductivity. 相似文献
994.
995.
微生物降解是磺酰脲类除草剂降解的重要途径之一。笔者对磺酰脲类除草剂微生物降解途径及影响微生物降解的因素进行了分析,对磺酰脲类除草剂微生物降解的研究现状做了简要综述,提出了微生物降解领域的发展趋势和有待解决的问题。 相似文献
996.
Huang Yung-Sheng Lin Xiaorong Redden Peter R. Horrobin David F. 《Journal of the American Oil Chemists' Society》1995,72(6):625-631
The present study compared thein vitro hydrolysis of two 18:3n-6-rich oils—evening primrose oil (EPO) and borage oil (BO)—and different synthetic 18:3n-6-containing
triacylglycerols (TG). Incubation of EPO and BO with pancreatic lipase lipolyzed 18:3n-6 from the TG species. The rate of
lipolysis of TG species containing two or three molecules of 18:3n-6, which comprised 36% of total 18:3n-6 in BO and only
7% in EPO, was significantly slower than those containing only one molecule of 18:3n-6. This was found especially in those
with two molecules of linoleic acid, which constituted 20% of total 18:3n-6 in BO, whereas over 80% were present in EPO. In
a separate study, various synthetic 18:3n-6-containing TG were also subjected toin vitro hydrolysis by pancreatic lipase. Results showed that release of 18:3n-6 from thesn-1/sn-3 positions was significantly slower when two other stereospecific positions in the same TG molecule were occupied by either
palmitic acid (16:0) or monounsaturated (18:1 and 20:1) fatty acids than when occupied by 18:2n-6. The rate of hydrolysis
ofsn-2-γ-linolenyl-sn-1(3)-diacylglycerol to formsn-2-mono-γ-linolenyl glycerol was also significantly slower when both thesn-1 andsn-3 positions in TG molecules were occupied by either saturated fatty acids (16:0 and 18:0) or long-chain monounsaturated fatty
acids than when occupied by 18:2n-6. These findings suggest that the stereospecific position of 18:3n-6 in TG molecules and
the constituent of its neighboring fatty acids modulated availability of 18:3n-6 from 18:3n-6-containing TG or 18:3n-6-rich
oils. 相似文献
997.
Prakorn Ramakul Milan Hronec Ura Pancharoen 《Korean Journal of Chemical Engineering》2007,24(2):282-287
−Purification of 2-mercaptobenzothiazole (91.9% purity) by solvent extraction was studied. The extraction of impurities present
in crude 2-MBT (e.g. benzothiazole, sulfides and sulfur containing compounds) was carried out at temperatures between 70-180°C
using various solvents and their mixtures of different polarity. The highest purity of 2-MBT, above 99% was obtained using
nitrobenzene, toluene and ethanol, even at a concentration of 2-MBT above 50 wt%. Increasing temperature and decreasing concentration
of the raw material have a positive influence on the purification process. A comparable efficiency of purification was observed
also with mixed solvents, (toluene with ethanol, acetone and aniline) possessing the same polarities. A correlation between
the polarity indexes (PI) of mixed solvents and experimentally obtained purity of 2-MBT was found. The highest purity of 2-MBT
provides extraction of the raw material with mixed solvents having PI 3.8-4.4. 相似文献
998.
水溶性氨基丙烯酸漆的研制 总被引:7,自引:0,他引:7
研制了高温烘烤 (145~ 15 0℃ )和中温烘烤 (12 0~ 12 5℃ )两种水溶性氨基丙烯酸漆。当羟基树脂的玻璃化温度为 - 5~ 0℃ ,丙烯酸和丙烯酸羟乙酯占总单体的质量分数分别为 7 5 %~ 8 5 %和 8 0 %~ 12 0 % ,羟基树脂和氨基树脂的质量比为 (0 0 5∶1 0 0 )~ (0 10∶1 0 0 ) ,颜基质量比为 0 2 9∶1 0 0时 ,两种漆的附着力达到 1级 ,抗冲击强度 >490N·cm ,柔软性 <1mm ,硬度 >2H ,光泽度 >80 (45℃ ) ,耐水 (2 0~ 2 5℃ ) 1d以上 ,遮盖力及施工性能良好 相似文献
999.
采用两段热处理技术,利用X射线衍射分析、扫描电镜观察等方法研究广2MgO-B_2O_3-SiO_2系的晶化过程,晶化析出相2MgO·B_2O_3的微观形貌具有分形特征,采用密度-密度相关函数法计算其分形维数为1.63。为揭示2MgO·B_2O_3生长机制,采用Monte-Carlo方法及改进的DLA模型对分形生长过程进入计算机模拟。模拟结果与实际分形结构、分形维数相符,表明2MgO·B_2O_3生长是扩散控制凝聚过程。可以预见,分形理论与计算机模拟相结合,将会在探讨未知机理方面发挥重要作用。 相似文献
1000.
The diffusion of 57 Co isotope on the MgO (100) surface was investigated by the edge-source method. The surface diffusion parameter, αDs δ, where α is the segregation factor, Ds the surface diffusion coefficient, and δ the thickness of the high-diffusivity layer, was determined over the temperature region 750° to 1250°C. An Arrhenius plot shows a break at ∼1100°C. Below this temperature ionic or localized transport predominates and above it nonlocalized transport seems to predominate. The divalent Co ion diffuses faster than the trivalent Cr ion in the surface layer. The apparent activation energies for the localized surface diffusion of 57 Co and 59 Cr are 59±12 and 110±12 kj/mol, respectively. 相似文献