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41.
42.
Koo Hyun Lee Ki Suk Nam Youl Min Park Pyung Woo Shin Deuk Yong Lee Yo-Seung Song 《Metals and Materials International》2002,8(4):381-385
Plasma nitrocarburized AISI 1020 steels were oxidized for 15, 30 and 60 min to evaluate their corrosion and microstructural properties. After plasma nitrocarburizing for 3 h at 570°C in a gas mixture comprising 85 vol.% N2, 12vol.% H2 and 3 vol.% CH4, the compound layer composed of ɛ-Fe2–3(N,C) and γ’-Fe4(N,C) phases and the diffusion layer above the matrix were observed. The top oxide layer, consisting mainly of magnetite (Fe2O4) and hematite (Fe2O3) phases, forms after post-oxidation treatment at 500°C. However, the oxide layer was severely degraded by spallation as a result of increases in post-oxidizing time. The difference in corrosion resistance should be attributed to the thickness of the top oxide layer, which was governed by post-oxidizing time. 相似文献
43.
Jun T. Kim Dong S. Cha Gee D. Lee Tae W. Park Dong K. Kwon Hyun J. Park 《应用聚合物科学杂志》2002,83(2):423-434
Biodegradable plastics were produced from sweet potato pulp (SPP) and cationic starch (CS) or chitosan composite (CC) by compression molding and their mechanical properties were tested. A universal testing machine, Rockwell hardness tester, and Izod impact tester were used for testing the mechanical properties (flexural strength, Rockwell hardness, and Izod strength) of the plastics. A central composite second‐order design was used to study the effects of temperature, time, and moisture content on the flexural strength, Rockwell hardness, and Izod strength of SPP/CS and SPP/CC blended plastics. The flexural strength, Rockwell hardness, and Izod strength of SPP‐based plastics was 101.1–305.9 kg/cm2, R29.0–R96.7, and 0.6–3.0 kg cm cm?2, respectively. Regression analysis predicted the optimal mechanical properties (flexural strength, Rockwell hardness, and Izod strength) to be attained with a 150–160°C temperature, 15–20‐min reaction time, and 20–23% moisture content. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 423–434, 2002 相似文献
44.
Baik Joon Hyun Yim Sung Dae Nam In-Sik Mok Young Sun Lee Jong-Hwan Cho Byong K. Oh Se H. 《Topics in Catalysis》2004,30(1-4):37-41
Topics in Catalysis - Among the catalysts screened, Cu-ion exchanged ZSM5 zeolite exhibited the highest NO removal activity, particularly at low reaction temperatures below 200 °C,... 相似文献
45.
Xuejun Cao Ho-Joon Lee Hyun Shik Yun Yoon-Mo Koo 《Korean Journal of Chemical Engineering》2002,19(2):301-304
Crystallization and dissolution behavior of L(+) calcium and zinc lactate in 50% ethanol-water solution was studied. The effects
of stirring, standing, ultrasonic wave, and temperature on the crystallization of L(+) calcium and zinc lactate were evaluated.
It was found that standing had a positive effect on crystallization of L(+) calcium and zinc lactate, while stirring promoted
dissolution of crystallized particles and resulted in high residual concentration in mother liquor. The application of ultrasonic
wave did not influence much on crystallization process. L(+) calcium and zinc lactate crystallized easily at 5 ‡C; however,
complete crystallization took more than 72 hours. These two salts dissolved rapidly and reached equilibrium within 1 hour. 相似文献
46.
Hyun Ju Lim Sung Jun Lee Han Gon Choi Jung Ae Kim Chul Soon Yong Sung Soo Han Seok Kyun Noh Jinho Jang Won Seok Lyoo 《应用聚合物科学杂志》2007,106(5):3268-3272
High‐molecular‐weight atactic poly(vinyl alcohol) (a‐PVA) gels loaded with (R,S)‐2‐(3‐benzoylphenyl)propionic acid (ketoprofen) were prepared from 5, 6, 7, and 8 g/dL solutions of a‐PVA with a number‐average degree of polymerization of 4000 in an ethylene glycol/water mixture with an aging method to identify the effect of the initial polymer concentration on the swelling behavior, morphology, and thermal properties of a‐PVA gels. Then, the release behavior of ketoprofen from a‐PVA gels was investigated. As the polymer concentration decreased, the ability for network formation decreased, and the degree of swelling of the a‐PVA gels increased. In addition, the enthalpy increased with an increase in the a‐PVA concentration, but the melting temperatures of the gels prepared at different initial polymer concentrations were the same; this indicated that tighter gel networks would be formed by a higher polymer chain density. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
47.
Shear creep resistance of styrene–isoprene–styrene (SIS)‐based hot‐melt pressure‐sensitive adhesives
The effects of the properties of substrates and tackifier on the shear creep of SIS‐based HMPSAs were investigated. The holding power (tb) and shear adhesion failure temperature (SAFT) were measured. The relationship between the complex viscosity and the holding power was examined. The holding power and SAFT values of the triblock SIS blends were higher than those of the diblock‐containing SIS blends, perhaps because blends using triblock SIS have higher crossover temperature and complex viscosity than those using diblock‐containing SIS. Higher levels of aromatic resin‐modified aliphatic tackifier and rosin ester were found to decrease the holding power of the HMPSAs. This maybe due to the fact that rosin ester and aromatic‐modified aliphatic resin are compatible with both the ends and midblocks of SIS. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 825–831, 2006 相似文献
48.
Ozonolysis of cyclododecene was carried out to produce an w-formyl carboxylic acid (12-oxododecanoic acid) which is derived
from zwitterion and aldehyde moiety that are formed during the reaction. The ozonolysis was performed to examine the product
distribution under such reaction variables as temperature, kinds of solvent, and presence of catalyst. The yield of polymeric
ozonide, which is undesirable product, was measured to be dominantly 86% without pyridine catalyst, whereas, only 10.25% with
the catalyst. The optimum reaction condition was to be in MC (methylene chloride) solvent, and in the presence of equimolar
olefin and pyridine catalyst at O°C, at which the yields of polymeric ozonide, 1,12-dodecanedialdehyde, 1,12-dodecanedicarboxylic
acid, and 12-oxo-dodecanoic acid were 10.25%, 26.72%, 26.31%, and 36.72%, respectively. 相似文献
49.
Biodegradability and mechanical properties of agro‐flour–filled polybutylene succinate biocomposites
The objective of this study was the production of rice husk flour (RHF) and wood flour (WF) filled polybutylene succinate (PBS) biocomposites as alternatives to cellulosic material filled conventional plastic (polyolefins) composites. PBS is one of the biodegradable polymers, made from the condensation reaction of 1,4‐butanediol and succinic acid that can be naturally degraded in the natural environment. We compared the mechanical properties between conventional plastics and agro‐flour–filled PBS biocomposites. We evaluated the biodegradability and mechanical properties of agro‐flour–filled PBS biocomposites according to the content and filler particle size of agro‐flour. As the agro‐flour loading was increased, the tensile and impact strength of the biocomposites decreased. As the filler particle size decreased, the tensile strength of the biocomposites increased but the impact strength decreased. The addition of agro‐flour to PBS produced a more rapid decrease in the tensile strength, notched Izod impact strength, and percentage weight loss of the biocomposites during the natural soil burial test. These results support the application of biocomposites as environmentally friendly materials. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 1513–1521, 2005 相似文献
50.
Mesoporous molecular sieve MCM-41 with a Si/Al ratio of 35 was obtained by hydrothermal synthesis using a gel mixture with a molar composition of 6 SiO20.1 Al2O31 hexadecyltrimethylammonium chloride 0.25 dodecyltrimethylammonium bromide 0.25 tetrapropylammonium bromide0.15 (NH4)2O1.5 Na2O300 H2O. The MCM-41 sample was calcined in O2 flow at 813 K and subsequently ion exchanged with Ca2+. A small Pt cluster has been supported on the MCM-41 sample following a procedure using ion exchange of Pt(NH3)
4
2+
. The Pt(NH3)
4
2+
ion supported on MCM-41 has been activated in O2 flow at 593 K and subsequently reduced with Fh flow at 573 K, in the same way used for the preparation of a Pt cluster entrapped inside the supercage of zeolite NaY. The resulting Pt cluster supported on the MCM-41 shows hydrogen chemisorption oftotal two H atoms per Pt at 296 K (based on the total amount of Pt) and high catalytic activity for hydrogenolysis of ethane. The chemical shift in129Xe NMR spectroscopy of adsorbed xenon indicates that the Pt cluster is located inside the mesoporous molecular sieve. 相似文献