Facile Synthesis of Red/NIR AIE Luminogens with Simple Structures,Bright Emissions,and High Photostabilities,and Their Applications for Specific Imaging of Lipid Droplets and Image‐Guided Photodynamic Therapy

Red/near‐infrared (NIR) fluorescent molecules with aggregation‐induced emission (AIE) characteristics are of great interest in bioimaging and therapeutic applications. However, their complicated synthetic approaches remain the major barrier to implementing these applications. Herein, a one‐pot synthetic strategy to prepare a series of red/NIR‐emissive AIE luminogens (AIEgens) by fine‐tuning their molecular structures and substituents is reported. The obtained AIEgens possess simple structures, good solubilities, large Stokes shifts, and bright emissions, which enable their applications toward in vitro and in vivo imaging without any pre‐encapsulation or ‐modification steps. Excellent targeting specificities to lipid droplets (LDs), remarkable photostabilities, high brightness, and low working concentrations in cell imaging application make them remarkably impressive and superior to commercially available LD‐specific dyes. Interestingly, these AIEgens can efficiently generate reactive oxygen species upon visible light irradiation, endowing their effective application for photodynamic ablation of cancer cells. This study, thus, not only demonstrates a facile synthesis of red/NIR AIEgens for dual applications in simultaneous imaging and therapy, but also offers an ideal architecture for the construction of AIEgens with long emission wavelengths.     

Self‐Healing Fibre Reinforced Composites via a Bioinspired Vasculature

This paper demonstrates the first steps towards self‐healing composites that exploit a design philosophy inspired by the damage tolerance and self‐repair functions of bone. Cracking in either fibre reinforced polymers (FRP) or bone, if left unattended, can grow under subsequent cyclic stresses eventually leading to catastrophic failure of the structure. On detection of cracks, an FRP component must be repaired or completely replaced, whereas bone utilises a series of complex processes to repair such damage. Under normal circumstances, these processes allow the skeleton to continually perform over the lifespan of the organism, a highly desirable aspiration for engineering materials. A simple vasculature design incorporated into a FRP via a “lost wax” process was found to facilitate a self‐healing function which resulted in an outstanding recovery (≥96%) in post‐impact compression strength. The process involved infusion of a healing resin through the vascule channels. Resin egress from the backface damage, ultrasonic C‐scan testing, and microscopic evaluation all provide evidence that sufficient vascule–damage connectivity exists to confer a reliable and efficient self‐healing function.     

BorderSense: Border patrol through advanced wireless sensor networks

The conventional border patrol systems suffer from intensive human involvement. Recently, unmanned border patrol systems employ high-tech devices, such as unmanned aerial vehicles, unattended ground sensors, and surveillance towers equipped with camera sensors. However, any single technique encounters inextricable problems, such as high false alarm rate and line-of-sight-constraints. There lacks a coherent system that coordinates various technologies to improve the system accuracy. In this paper, the concept of BorderSense, a hybrid wireless sensor network architecture for border patrol systems, is introduced. BorderSense utilizes the most advanced sensor network technologies, including the wireless multimedia sensor networks and the wireless underground sensor networks. The framework to deploy and operate BorderSense is developed. Based on the framework, research challenges and open research issues are discussed.     

Video mediated social interaction between groups: System requirements and technology challenges

This paper discusses results from research related to the use of television as a device that supports social interaction between close-knit groups in settings that include more than two locations, each location being potentially equipped with more than one camera. The paper introduces the notion of a framing experience, as a specific scenario or situation within which social communication takes place. It reports on the evaluation of some of the key attributes of social communication through semi-structured interviews, with 16 families across four European countries. The inferences drawn from this study are reduced to four system capabilities including the ability to support: excitement, engagement and entertainment; high quality, reliable audiovisual communications; flexibility and adaptability sufficient to support the unpredictable and reactive nature of human interaction and discourse. These system requirements are, in turn, reduced to a number of technology challenges which if solved will help enable effective social communications between groups, mediated by the television. These technology challenges include: high quality reliable audio visual communication; interaction orchestration, multimedia interpretation and multimedia composition. Finally the paper reflects on the impact the use of framing experiences, such as those described here, could have on strategy and policy for service providers and regulators.     

Investigating Morphology and Stability of Fac‐tris (2‐phenylpyridyl)iridium(III) Films for OLEDs

Stable film morphology is critical for long‐term high performance organic light‐emitting diodes (OLEDs). Neutron reflectometry (NR) is used to study the out‐of‐plane structure of blended thin films and multilayer structures comprising evaporated small molecules. It is found that as‐prepared blended films of fac‐tris(2‐phenylpyridyl)iridium(III) [Ir(ppy)₃] in 4,4′‐bis(N‐carbazolyl)biphenyl (CBP) are uniformly mixed, but the occurrence of phase separation upon thermal annealing is dependent on the blend ratio. Films comprised of the ratio of 6 wt% of Ir(ppy)₃ in CBP typically used in OLEDs are found to phase separate with moderate heating while a higher weight percent mixture (12 wt%) is found to be stable. Furthermore, it is found that thermal annealing of a multilayer film comprised of typical layers found in efficient devices ([tris(4‐carbazoyl‐9‐ylphenyl)amine (TCTA)/Ir(ppy)₃:CBP/bathocuproine (BCP)]) causes the BCP layer to become mixed with the emissive blend layer, whereas the TCTA interface remains unchanged. This significant structural change causes no appreciable difference in the photo­luminescence of the stack although such a change would have a dramatic effect on the charge transport through the device, leading to changes in performance. These results demonstrate the effect of thermal stress on the delicate interplay between the chemical composition and morphology of OLED films.     

Proposal for a novel and simple WDM NRZ-DPSK system

A novel and simple non-return-to-zero differential phase shift keying (NRZ-DPSK) wavelength division multiplexing (WDM) system, which can simultaneously demultiplex and demodulate multiple wavelengths, is proposed and investigated in this paper.The phase-to-intensity demodulation principle is based on detuned filtering, which is achieved by using a single commercial array waveguide grating (AWG) in our scheme.By properly choosing appropriate AWG channels at the transmitter, the AWG at the receiver can act as both the demultiplexer and the demodulator of the DPSK signals.Simulations at 10, 20, and 40 Gbit/s show good flexibility and performance for the proposed system.     

The Effect of Nanotube Content and Orientation on the Mechanical Properties of Polymer–Nanotube Composite Fibers: Separating Intrinsic Reinforcement from Orientational Effects

We have measured the mechanical properties of coagulation‐spun polymer–nanotube composite fibers. Both the fiber modulus, Y, and strength, σ_B, scale linearly with volume fraction, V_f, up to V_f ～10%, after which these properties remain constant. We measured dY/dV_f = 254 GPa and dσ_B/dV_f = 2.8 GPa in the linear region. By drawing fibers with V_f < 10% to a draw ratio of ～60%, we can increase these values to dY/dV_f = 600 GPa and dσ_B/dV_f = 7 GPa. Raman measurements show the Herman's orientation parameter, S, to increase with drawing, indicating that significant nanotube alignment occurs. Raman spectroscopy also shows that the nanotube effective modulus, Y_Eff, also increases with drawing. We have calculated an empirical relationship between the nanotube orientation efficiency factor, η_o, and S. This allows us to fit the data for Y_Eff versus η_o, showing that the fiber modulus scales linearly with η_o, as predicted theoretically by Krenchel. From the fit, we estimate the nanotube modulus to be; Y_NT = 480 GPa. Finally, we show that the fiber strength also scales linearly with η_o, giving an effective interfacial stress transfer of τ = 40 MPa and a nanotube critical length of l_c=1250 nm. This work demonstrates the validity of the Cox‐Krenchel rule of mixtures and shows that continuum theory still applies at the near‐molecular level.     

Algorithms to determine exact blocking probabilities for multiratetree networks

A circuit-switched network consisting of multiple-access links connected to a common link is considered. Each call requires circuits on one access link and on the common link. The network supports multiple classes of calls where each class specifies a bandwidth requirement, an arrival rate, and a holding-time distribution. Based on a product-form solution for these networks, four algorithms are developed to determine the exact blocking probability for each of the classes. The first two algorithms are based on convolution, the third on the fast Fourier transform, and the fourth on a recursion due to J.S. Kaufman (1981) and to J.W. Roberts (1981). Complexity bounds and numerical results demonstrate that these algorithms can determine blocking probabilities in reasonable CPU time for networks with thousands of circuits     

A Distributed Multicast Routing Scheme for Multi-Layered Satellite IP Networks

In this paper, a distributed multicast routing scheme is introduced for multi-layered satellite IP networks, which include GEO, MEO, and LEO layers. This scheme aims to minimize the total cost of multicast trees in the satellite network. Multicast trees are constructed and maintained in the dynamic satellite network topology in a distributed manner. Simulation results are provided to evaluate the performance of the new scheme in terms of end-to-end delay and multicast tree cost.     

An FIB-SEM slice-and-view study of three-dimensional beta phase distribution in Ti-6Al-4V

In the scanning electron microscope, weak secondary electron contrast between the alpha and beta phases of a Ti-6Al-4V alloy can be improved via imaging conditions such as beam voltage and current. Dual beam focussed ion beam-scanning electron microscopes are thereby suited for characterising micron and sub-micron microstructural features of Ti-6Al-4V in three dimensions via serial-sectioning procedures.