Improving the dyeing properties of textiles via utilization of redox systems. II. Dyeing of nylon-6 with acid dye

Redox systems based on potassium, sodium or ammonium peroxodisulphate or potassium periodate as oxidant and glucose, thiourea, sodium thiosulphate or potassium pyrosulphite as reductant were incorporated in the dyeing bath of nylon-6 under a variety of conditions. An acid dye, namely Kiton Scarlet 4 R was used. The colour strength and dye fixation enhanced outstandingly in presence of the redox system, depending upon kind and concentration of the redox components. Raising the dyeing temperature from 30 to 60°C caused significant improvement in colour strength. The same holds true for duration of dyeing up to 60 min. Beside association of the dye with nylon-6 by salt-like bond, a free radical mechanism was suggested.     

Essential fatty acids in trout serum lipoproteins,vitellogenin and egg lipids

This paper describes evidence of (n−3) and particularly of 22∶6 (n−3) fatty acid enrichment in trout lipoproteins as well as in vitellogenin, egg lipovitellin and oil globule. Among the lipoproteins, HDL and LDL were the main forms of blood lipid transport, whereas phospholipids and cholesteryl esters are the preferential chemical carriers for (n−3) fatty acid transport. However, cholesteryl esters were less important as esterified fatty acid carriers than in man. Taken together with the data obtained in mammals, our results suggest that there may be a relationship between EFA activity and the distribution of the EFA among the lipoprotein lipid fractions in vertebrates, irrespective of the EFA series. Administration of an (n−3) fatty acid deficient diet for three months prior to trout spawning produced a significant increase in egg lipid content, primarily as a result of the increase of the oil globule composed almost exclusively of triacylglycerols. This diet decreased the 22∶6 (n−3), as well as the (n−3) fatty acid contents of lipoproteins, lipovitellin, vitellogenin and the oil globule. In contrast, the (n−3) fatty acid level was always higher in lipoproteins and lipovitellin than in the vitellogenin and the oil globule. Moreover, the relative levels of 22∶6 (n−3) and total (n−3) fatty acids were quite similar in lipoproteins and lipovitellin on the one hand, and in vitellogenin and the oil globule on the other. These findings suggest a direct relationship between the two forms of plasma lipid transport and the two egg compartments. During ovogenesis, dietary lipids seemed to be diverted from the adipose tissue and essentially deposited in the egg.     

Proteome Based Approach Defines Candidates for Designing a Multitope Vaccine against the Nipah Virus

Nipah virus is one of the most harmful emerging viruses with deadly effects on both humans and animals. Because of the severe outbreaks, in 2018, the World Health Organization focused on the urgent need for the development of effective solutions against the virus. However, up to date, there is no effective vaccine against the Nipah virus in the market. In the current study, the complete proteome of the Nipah virus (nine proteins) was analyzed for the antigenicity score and the virulence role of each protein, where we came up with fusion glycoprotein (F), glycoprotein (G), protein (V), and protein (W) as the candidates for epitope prediction. Following that, the multitope vaccine was designed based on top-ranking CTL, HTL, and BCL epitopes from the selected proteins. We used suitable linkers, adjuvant, and PADRE peptides to finalize the constructed vaccine, which was analyzed for its physicochemical features, antigenicity, toxicity, allergenicity, and solubility. The designed vaccine passed these assessments through computational analysis and, as a final step, we ran a docking analysis between the designed vaccine and TLR-³ and validated the docked complex through molecular dynamics simulation, which estimated a strong binding and supported the nomination of the designed vaccine as a putative solution for Nipah virus. Here, we describe the computational approach for design and analysis of this vaccine.     

Cathodic electrodeposition of Y(OH)3 and Y2O3 nanostructures from chloride bath. Part II: Effect of the bath temperature on the crystal structure,composition and morphology

Ultra-fine nanoparticles, mono-dispersed nanospheres and nanorods of Y(OH)₃ and Y₂O₃ were successfully prepared via electrodeposition from chloride bath at different temperatures of 10, 25, 40 and 80 °C followed by heat-treatments at 600 °C in dry air atmosphere. Thermal behavior of the hydroxide samples was investigated by differential scanning calorimetry (DSC) and thermogravimetric (TG) analysis. The structural and morphological characteristics of the products were determined by X-ray diffraction (XRD), FT-IR, scanning and transmission electron microscopy (SEM and TEM). Effects of bath temperature on the mechanism of base electrogeneration and deposit formation on the cathode surface were proposed and discussed. The results showed that the crystal structure, composition and morphology of the products are mainly affected by the temperature of electrodeposition bath.     

Theoretical Analysis of the Onset of Gas Entrainment from a Stratified Region through a Single Side‐Oriented Branch at Moderate Froude Numbers

A theoretical investigation has been conducted for the prediction of the critical height at the onset of gas entrainment during single discharge from a stratified, two‐phase region, through a branch installed on an inclined flat wall. The predicted critical height at the onset of gas entrainment was proven to be a function of Froude number (Fr) and density ratio of the interface fluids. Three different experimental data sets at wall inclination angles of zero, 45 and 90 degrees (i.e. side, inclined and bottom branches) were used for comparisons. A good concurrence was illustrated between the experimental and theoretical values.     

Tensile modulus modeling of carbon‐filled nylon 6,6 and polycarbonate‐based resins

Electrically and thermally conductive resins can be produced by adding conductive fillers to insulating polymers. Mechanical properties, such as tensile modulus, are also important. This research focused on performing compounding runs followed by injection molding and tensile testing of carbon‐filled nylon 6,6 and polycarbonate‐based resins. The three carbon fillers investigated included an electrically conductive carbon black, synthetic graphite particles, and a milled pitch–based carbon fiber. For each polymer, resins were produced and tested that contained varying amounts of these single‐carbon fillers. In addition, combinations of fillers were investigated by conducting a full 2³ factorial design and a complete replicate in each polymer. These tensile modulus experimental results were then compared to results predicted by several different models. For the composites containing only one filler type, the Nielsen model with the modified Ψ term provided the best prediction of the actual experimental values. For the composites containing more than one filler type, a new parameter, which includes the vibrated bulk density (VBD) of the fillers, was incorporated into the Nielsen model with the modified Ψ term. This model with the new VBD parameter provided the best estimate of experimental tensile modulus for composites containing multiple‐filler types. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1716–1728, 2003     

Synthetic absorbent for dyestuffs based on gamma crosslinked poly(vinyl alcohol) (PVA)

This work reports on the characterization and uses of gamma radiation‐crosslinked poly(vinyl alcohol) (PVA) films as absorbents for different classes of dyestuffs normally released from textile factors. Dyestuffs were selected from different producers. These dyestuffs were Remacryl Blue (basic dye), Remazol Golden Orange (reactive dye), Solar Orange (direct dye), and Sandolan (acid dye). The percentage dye sorption by PVA was determined by spectroscopic analysis and color‐strength measurements of the PVA films after absorbing the different dyestuffs. The results showed that the concentration of dimethylbisacrylamide as a crosslinking agent has a great effect on the gel fraction and percentage swelling in water of the PVA polymer. In general, crosslinked PVA showed a low tendency to absorb the different dyestuffs under investigation at room temperature. This tendency was shown to increase with an increasing temperature of the dye solution from room temperature to 70°C. Meanwhile, the highest percentage of dye sorption was found in the case of the basic dye and the lowest one in the case of the reactive dye depending on the active groups on the dyes. Moreover, the percentage dye sorption by PVA was slightly higher in the acid medium rather than in the alkaline one. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 349–354, 2003     

New Type Anode for Calcium Ion Batteries Based on Silicon Carbide Monolayer

Silicon - A theoretical research study was conducted into the possibility of using a two-dimensional graphene-like material silicon carbide nano-sheet (2D-SiCNS) as an anode in rechargeable Ca-ion...     

Plasma surface modification of graphene oxide nanosheets for the synthesis of GO/PES nanocomposite ultrafiltration membrane for enhanced oily separation

In this study, two different monomers, namely hexafluorobutyl acrylate (HFBA) and diethylaminoethyl methacrylate (DEAEMA) were individually used to modify graphene oxide (GO) nanosheets via environmentally friendly plasma enhanced chemical vapor deposition (PECVD) method. The results from instrumental analyses confirmed the successful deposition of respective functional material onto the nanomaterials. Modified GOs were used as the nano-fillers to develop composite polyethersulfone (PES) ultrafiltration (UF) membrane with improved surface properties for oily solution treatment. All the developed membranes were characterized with a series of analytical instruments to support the findings of membrane filtration performance. The results indicated that the membrane incorporated with DEAEMA-GOs (coated with hydrophilic polymer) could achieve better results in terms of oil rejection, antifouling resistance and water recovery rate than the membrane incorporated with HFBA-GOs (coated with hydrophobic polymer). This is due to the reduced agglomeration between modified GOs as well as better interaction of hydrophilic-coated GOs with polymer membrane. Compared to the pure water flux of the membrane incorporated with unmodified GO, the membrane incorporated with DEAEMA-GO achieve approximately 85% higher value with oil removal rate remained almost unchanged (98.94% rejection).