Heat transfer enhancement by metal screens and metal spheres in phase change energy storage systems

This study focuses on heat transfer enhancement in double pipe energy storage system. Enhancement is achieved by use of metal screens/spheres placed inside the phase change material (PCM), which is paraffin wax and results in increasing the effective thermal conductivity of the combined media of PCM and metal screens/spheres. The experiments are conducted as a function of the diameter and number of spheres inserted in the phase change material. Also, the experiments investigate the effect of increasing the temperature of the heat transfer fluid (HTF). Results are presented in terms of variations in the PCM Nusselt number and the melting Fourier number. Results indicate three-fold decrease in the Fourier number and similar increase in the Nusselt number. Replacing 2-volume percentage of the wax material by the metal spheres results in this large enhancement.     

INFORMATION INFRASTRUCTURE MANAGEMENT

Corporate survival in an information economy requires that IS managers assume the new role of information infrastructure management, an architecture-focused approach that results in an integrated IS and business organization with an integrated strategic plan. The approach enables IS managers to anticipate future organizational demands and stimulate innovative redesign of business processes to continuously improve performance.     

Synthesis of S-dithiocarbonates with polymer-supported xanthates

Summary Polymer-supported ammonium salts of methyl and ethyl xanthates react with alkyl halides to yield S-dithiocarbonates.     

Blind frame synchronization for error correcting codes having a sparse parity check matrix

We present in this letter a blind frame synchronization method based on a Maximum A Posteriori probability (MAP) approach. Applied to coded communication systems, this method is based on the calculation of the Log-likelihood Ratios (LLR) of the syndrome obtained according to the parity check matrix of the code. After presenting the proposed method, we compare it to an existing blind synchronization method previously introduced. Simulation results show that the proposed method outperforms the existing one and presents good performance when applied to codes having a sparse parity check matrix such as Low Density Parity Check (LDPC) codes and convolutional codes.     

A temporal modal defeasible logic for formalizing social commitments in dialogue and argumentation models

In this paper, we extend a temporal defeasible logic with a modal operator Committed to formalize commitments that agents undertake as a consequence of communicative actions (speech acts) during dialogues. We represent commitments as modal sentences. The defeasible dual of the modal operator Committed is a modal operator called Exempted. The logical setting makes the social-commitment based semantics of speech acts verifiable and practical; it is possible to detect if, and when, a commitment is violated and/or complied with. One of the main advantages of the proposed system is that it allows for capturing the nonmonotonic behavior of the commitments induced by the relevant speech acts.     

A solar still augmented with a flat-plate collector

A single-stage, basin-type solar still and a conventional flat-plate collector were connected together in order to studythe effect of augmentation on the still under local conditions. The still inlet was connected to a locally made, fin-tube collector such that its outlet was fed to the still basin instead of the common storage tank. Measurements of various temperatures, solar intensities and distilled water productions were taken for several days at various operating conditions. Several modes of operation were studied: still connected to collector for a 24-h period; still connected only during sunlight hours from 8 am to 5 pm, and still operating alone for a 24-h period. These tests were performed using tap water and saline water as a feed. It was found that the mass of distilled water production using augmentation was increased by 231% in the case of tap water as a feed and by 52% in the case of salt water as a feed.     

Diclofenac-bismuth complex: synthesis, physicochemical, and biological evaluation

Diclofenac-bismuth complexation was attempted by mixing diclofenac sodium (Na) and bismuth-subcitrate aqueous solutions at diclofenac:bismuth molar ratio of 3:1. A solid precipitate was obtained and isolated. The precipitate was characterized for stoichiometric ratio of diclofenac-bismuth complexation using capillary electrophoresis, which showed 1:1 complexation. In addition, nuclear magnetic resonance and Fourier transform infrared analysis were performed for the isolated solid complex and indicated that bismuth was in coordinate bond formation with the carboxylate group of diclofenac. In comparison with diclofenac Na powder, the complex was evaluated as an aqueous suspension for in vitro drug dissolution. The complex exhibited a faster dissolution rate than and similar dissolution extent as diclofenac Na. In comparison with an aqueous solution of diclofenac Na and an aqueous suspension of physical mixture of diclofenac acid (suspended) and bismuth-subcitrate (dissolved), the aqueous complex suspension was evaluated for ulcerogenic effect in rats upon oral administration. The complex led to more gastric ulceration than diclofenac Na, which was not in accordance with the antiulcer properties of bismuth. This antiulcer effect was shown as the physical mixture administration was accompanied with lower gastric ulceration than diclofenac Na administration. These gastric ulceration results were explained in terms of the difference in particle size between solid diclofenac acid formed as a result of the complex breakdown in an acidic medium (0.1 M HCl to simulate the gastric fluid) and that formed as a result of diclofenac Na neutralization. Diclofenac acid particles formed from the complex breakdown were of average size, three times smaller of those formed as a result of diclofenac Na protonation. This difference in particle size was correlated with the higher gastric ulceration associated with the complex than with diclofenac Na in terms of higher coverage of the gastric mucosa with diclofenac, and consequently, higher local ulceration.     

A parallel data assimilation model for oceanographic observations

In this paper we describe the development of a program that aims at achieving the optimal integration of observed data in an oceanographic model describing the water transport phenomena in the Agulhas area at the tip of South Africa. Two parallel implementations, MPI and OpenMP, are described and experiments with respect to speed and scalability on a Compaq AlphaServer SC and an SGI Origin3000 are reported. Copyright © 2003 John Wiley & Sons, Ltd.     

Effect of the Extent of Conversion and Retrogradation on the Digestibility of Potato Starch

The effect of starch conversion on the susceptibility of potato granules to α‐amylase was studied by direct sampling at different pasting times corresponding to different points on the RVA profile of a 6.4% (w/w) suspension of starch in distilled water. Native granules showed high resistance to α‐amylase with 8.6 ± 0.4% digestibility for a 6 h incubation period with the enzyme. When the suspension was heated to 60 °C, the digestibility increased to 53.5 ± 0.7% although, at this temperature, there was still no noticeable increase in the measured viscosity (≤0.040 Pa · s). The material sampled after a pasting time corresponding to the RVA peak viscosity showed a digestibility of 88.4 ± 0.5%. This suggested, owing to the expected retrogradation of amylose on cooling, the quasi‐total susceptibility of amylopectin to enzymatic digestion at this pasting stage. The effect of ions on the swelling of potato starch was used to assess whether the decrease of the swelling of the granules in the presence of NaCl was paralleled by an increase in resistance to α‐amylase. A small (∼6.1%) but significant decrease in the digestibility of pasted starch was observed in the presence of salt. Finally, the effect of the retrogradation of the amylopectin fraction on its digestibility was assessed in extruded potato starch ribbons containing 35% (w/w) water and stored at different temperatures. After 14 days of storage, the digestibility decreased from 77.0 ± 0.9% in the freshly extruded samples to between 28.0 ± 1.7% and 42.1 ± 0.3%, depending on the storage temperature. This suggested a measurable difference in the α‐amylase susceptibility between the A and B polymorphs of retrograded amylopectin.