Pumping stations for today's steel degassing requirements

This article focuses on the vacuum equipment used in vacuum degassing (VD) and vacuum oxygen decarburization (VOD) processes. Despite harsh process conditions caused by outgassing and the process gases themselves, there are various pumping principles and designs of vacuum pumps that can be used. Through clever pump selection there is an opportunity to realize substantial energy and operating resource savings on the vacuum pumping side. Last but not least, a new pump series will be presented that further contributes to cost reduction through higher efficiency.     

A Facile Molecular Approach to Amorphous Nickel Pnictides and Their Reconstruction to Crystalline Potassium-Intercalated γ-NiOOHx Enabling High-Performance Electrocatalytic Water Oxidation and Selective Oxidation of 5-Hydroxymethylfurfural

The low-temperature molecular precursor approach can be beneficial to conventional solid-state methods, which require high temperatures and lead to relatively large crystalline particles. Herein, a novel, single-step, room-temperature preparation of amorphous nickel pnictide (NiE; EP, As) nanomaterials is reported, starting from NaOCE(dioxane)_n and NiBr₂(thf)_1.5. During application for the oxygen evolution reaction (OER), the pnictide anions leach, and both materials fully reconstruct into nickel(III/IV) oxide phases (similar to γ-NiOOH) comprising edge-sharing (NiO₆) layers with intercalated potassium ions and a d-spacing of 7.27 Å. Remarkably, the intercalated γ-NiOOH_x phases are nanocrystalline, unlike the amorphous nickel pnictide precatalysts. This unconventional reconstruction is fast and complete, which is ascribed to the amorphous nature of the nanostructured NiE precatalysts. The obtained γ-NiOOH_x can effectively catalyse the OER for 100 h at a high current density (400 mA cm⁻²) and achieves outstandingly high current densities (>600 mA cm⁻²) for the selective, value-added oxidation of 5-hydroxymethylfurfural (HMF). The NiP-derived γ-NiOOH_x shows a higher activity for both processes due to more available active sites. It is anticipated that the herein developed, effective, room-temperature molecular synthesis of amorphous nickel pnictide nanomaterials can be applied to other functional transition-metal pnictides.     

Neue Regelungen für den Grund‐ und Tunnelbau im Bundesfernstraßenbereich – Teil II: Tunnelbau

New guidelines for foundation and tunnel engineering in the field of German Federal Highways, part II – tunnel engineering. A general overview about the structure of the regulations for civil engineering works on the federal highways (ZTV‐ING) and the new regulations for foundation works was already given in the issue 12/2007 of Bautechnik [8]. The modified and new developed regulations for road tunnel constructions in Germany are presented in this issue. Special focus will be laid on the new regulations for mechanised shield excavation methods and on tunnel sealing systems.     

An Intriguing Array of Extrudate Patterns in Long-Chain Branched Polymers During Extrusion

The present study highlights a range of surface and volume extrudate patterns that can be detected during the extrusion flow of long-chain branched polymers. Thus, four linear low-density polyethylenes (LDPEs) have been extruded using a single-screw extruder coupled to an inline optical imaging system. The selected LDPEs are selected to outline the influence of molecular weight and long-chain branching on the types of melt flow extrusion instabilities (MFEI). Through the inline imaging system, space–time diagrams are constructed and analyzed via Fourier-transformation using a custom moving window procedure. Based on the number of characteristic frequencies, peak broadness, and whether they are surface or volume distortions, three main MFEI types, distinct from those typically observed in linear and short-chain branched polymers, are identified. The higher molecular weight, low long-chain branching LDPEs exhibited all three instability types, including a special type volume instability. Independently of the molecular weight, higher long-chain branching appeared to have a stabilizing effect on the transition sequences by suppressing volume extrudate distortions or limiting surface patters to a form of weak intensity type.     

Nanoscale Control of the Surface Functionality of Polymeric 2D Materials

Typically, 2D nanosheets have a homogeneous surface, making them a major challenge to structure. This study proposes a novel concept of 2D organic nanosheets with a heterogeneously functionalized surface. This work achieves this by consecutively crystallizing two precisely synthesized polymers with different functional groups in the polymer backbone in a two-step process. First, the core platelet is formed and then the second polymer is crystallized around it. As a result, the central area of the platelets has a different surface functionality than the periphery. This concept offers two advantages: the resulting polymeric 2D platelets are stable in dispersion, which simplifies further processing and makes both crystal surfaces accessible for subsequent functionalization. Additionally, a wide variety of polymers can be used, making the process and the choice of surface functionalization very flexible.     

Long-Term Stability,Biocompatibility, and Magnetization of Suspensions of Isolated Bacterial Magnetosomes

Magnetosomes are magnetic nanoparticles biosynthesized by magnetotactic bacteria. Due to a genetically strictly controlled biomineralization process, the ensuing magnetosomes have been envisioned as agents for biomedical and clinical applications. In the present work, different stability parameters of magnetosomes isolated from Magnetospirillum gryphiswaldense upon storage in suspension (HEPES buffer, 4 °C, nitrogen atmosphere) for one year in the absence of antibiotics are examined. The magnetic potency, measured by the saturation magnetization of the particle suspension, drops to one-third of its starting value within this year—about ten times slower than at ambient air and room temperature. The particle size distribution, the integrity of the surrounding magnetosome membrane, the colloidal stability, and the biocompatibility turn out to be not severely affected by long-term storage.     

In Situ Reconstruction of Helical Iron Borophosphate Precatalyst toward Durable Industrial Alkaline Water Electrolysis and Selective Oxidation of Alcohols

Iron-based (pre)catalysts have attracted enormous attention for various electrooxidation reactions due to the low cost, high abundance, and multiple accessible redox states of iron. Herein, a well-defined helical iron borophosphate (LiFeBPO) is developed as an electro(pre)catalyst for the oxygen evolution reaction (OER) and selective alcohol oxidation. When deposited on nickel foam (NF), LiFeBPO exhibits an exceptional OER performance at ambient conditions attaining a current density of 100 mA cm⁻² at ≈276 mV overpotential in 1 m KOH. Notably, this anode sustains durable alkaline water electrolysis at 500 mA cm⁻² for over 330 h under industrial conditions (6 m KOH and 85 °C). In –situ and ex situ investigations reveal a deep reconstruction of LiFeBPO during OER, which transforms into a 3D open porous skeleton assembled by ultrasmall, low-crystalline α-FeOOH nanoparticles (interfacing with NiOOH of NF). This structure contributes to exposing accessible surface active sites, as well as accelerating mass transport and bubble detachment. Moreover, this electrode also catalyzes the electrooxidation of alcohols (methanol, ethylene glycol, and glycerol) to formic acid (FA) with high selectivity and full conversion. This study provides promising solutions for designing suitable anodes for the simultaneous production of green hydrogen fuel and value–added FA from electrooxidation reactions.     

Using transient energy release measurements for the in-line characterization of non-Newtonian fluids and fluid state in pipe flow

Alberini et al. have developed a new technology based on a passive acoustic emission (AE) sensing system that uses only a single sensor, with the goal of providing live and in-situ measurement of rheology. For this study, three different types of fluids were selected to represent common rheological behaviours: Newtonian behaviour, non-Newtonian behaviour with power law, and non-Newtonian behaviour with Herschel–Bulkley relationship. By analyzing the transient energy released during the interaction between the probe and the fluid, distinct acoustic fingerprints were identified in the frequency domain. These acoustic fingerprints were found to be characteristic of the different fluids and their rheology, and were validated in triplicate. Furthermore, the results showed that the intensity of the acoustic emissions increased with higher flow rates (30 to 50 L/min). To test the correlation between flow rate and acoustic response, a neural network regression test was conducted, which demonstrated a direct correlation between AE peaks and flow rate. The neural network used was nonlinear autoregressive network with exogenous inputs (NARX), and the test involved a stepwise regression with 70% training and 30% network validation. The study also introduced the Rheology-AE quotient, which maps fluid constituents against the acoustic signal. Results showed that this was a reliable means of deriving live rheology from a fluid's frequency domain. Finally, the results obtained from this study were validated using an offline rotational rheometer.     

Low-temperature rheology of engine lubricants subjected to mechanical shear: Viscosity modifier effects

It is well known^1–5 that the viscosity of crankcase lubricants decreases in the early stages of use due to shearing of the viscosity modifier (VM) and, depending upon the type of service, fuel dilution. This paper examines the effects of VM chemistry on the shearing process, and particularly how both high-temperature and low-temperature viscosities can change as a result of mechanical shear in the Kurt Orbahn injector test and during a passenger car fleet test. Commercial olefin copolymer, styrene/butadiene, styrene/isoprene, and radial isoprene polymers were included in this study, as a way of representing the major VM chemistries used in motor oils throughout the world. The rate of change of kinematic and high-temperature, high-shear-rate viscosity with time, as well as low-temperature cranking and pumping viscosity changes, were found to be characteristic of particular VM chemistries.