Total mercury,methylmercury and selenium in mercury polluted areas in the province Guizhou,China

The province of Guizhou in Southwestern China is currently one of the world's most important mercury production areas. Emissions of mercury from the province to the global atmosphere have been estimated to be approximately 12% of the world total anthropogenic emissions. The main objective of this study was to assess the level of contamination with Hg in two geographical areas of Guizhou province. Mercury pollution in the areas concerned originates from mercury mining and ore processing in the area of Wanshan, while in the area of Quingzhen mercury pollution originates from the chemical industry discharging Hg through wastewaters and emissions to the atmosphere due to coal burning for electricity production. The results of this study confirmed high contamination with Hg in soil, sediments and rice in the Hg mining area in Wanshan. High levels of Hg in soil and rice were also found in the vicinity of the chemical plant in Quingzhen. The concentrations of Hg decreased with distance from the main sources of pollution considerably. The general conclusion is that Hg contamination in Wanshan is geographically more widespread, due to deposition and scavenging of Hg from contaminated air and deposition on land. In Quingzhen Hg contamination of soil is very high close to the chemical plant but the levels reach background concentrations at a distance of several km. Even though the major source of Hg in both areas is inorganic Hg, it was observed that active transformation of inorganic Hg to organic Hg species (MeHg) takes place in water, sediments and soils. The concentration of Hg in rice grains can reach up to 569 microg/kg of total Hg of which 145 microg/kg was in MeHg form. The percentage of Hg as MeHg varied from 5 to 83%. The concentrations of selenium can reach up to 16 mg/kg in soil and up to 1 mg/g in rice. A correlation exists between the concentration of Se in soil and rice, indicating that a portion of Se is bioavailable to plants. No correlation between Hg and Se in rice was found. Exposure of the local population to Hg may occur due to inhalation of Hg present in air (in particular in Hg mining area) and consumption of Hg contaminated food (in particular rice and fish) and water. Comparison of intake through these different routes showed that the values of Hg considerably exceed the USA EPA Reference Concentration (RfC) for chronic Hg exposure (RfC is 0.0004 mg/m(3)) close to the emission sources. Intake of Hg through food consumption, particularly rice and fish, is also an important route of Hg exposure in study area. In general, it can be concluded that the population mostly at risk is located in the vicinity of smelting facilities, mining activities and close to the waste disposal sites in the wider area of Wanshan. In order to assess the real level of contamination in the local population, it is recommended that biomonitoring should be performed, including Hg and MeHg measurements in hair, blood and urine samples.     

Environmental and economic feasibility of palm oil biodiesel in the Mexican transportation sector

This study analyses the environmental and economic feasibility of producing palm oil-based biodiesel in Mexico in order to substitute of diesel fuel consumption using B5 until 2015 and B10 from 2016 to 2031 in the transportation sector. Two scenarios were created by projecting demand and costs for biodiesel as well as greenhouse gases emissions reduction over the next 26 years. In the environmental section, avoided emissions of Particulate matter, Total Hydrocarbons, Carbon Monoxide, Sulphur Dioxide, and Carbon Dioxide as well as the increase in Nitrous Oxide emissions were estimated for each scenario. In the economic section, a cost–benefit analysis of biodiesel substitution was implemented, and mitigation costs of Carbon Dioxide were estimated. Our results show that the feasibility of palm oil biodiesel use is directly related to the implementation of fiscal incentives, such as the exemption from tax (Special Tax on Production and Services).     

Using SMS text messaging to assess moderators of smoking reduction: Validating a new tool for ecological measurement of health behaviors.

Objective: Understanding the psychological processes that contribute to smoking reduction will yield population health benefits. Negative mood may moderate smoking lapse during cessation, but this relationship has been difficult to measure in ongoing daily experience. We used a novel form of ecological momentary assessment to test a self-control model of negative mood and craving leading to smoking lapse. Design: We validated short message service (SMS) text as a user-friendly and low-cost option for ecologically measuring real-time health behaviors. We sent text messages to cigarette smokers attempting to quit eight times daily for the first 21 days of cessation (N-obs = 3,811). Main outcome measures: Approximately every two hours, we assessed cigarette count, mood, and cravings, and examined between- and within-day patterns and time-lagged relationships among these variables. Exhaled carbon monoxide was assessed pre- and posttreatment. Results: Negative mood and craving predicted smoking two hours later, but craving mediated the mood–smoking relationship. Also, this mediation relationship predicted smoking over the next two, but not four, hours. Conclusion: Results clarify conflicting previous findings on the relation between affect and smoking, validate a new low-cost and user-friendly method for collecting fine-grained health behavior assessments, and emphasize the importance of rapid, real-time measurement of smoking moderators. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Preferred color gamut boundaries for wide‐gamut and multiprimary displays

Preferred chroma enhancement and its dependence on hue are studied in a two‐part experiment using a wide‐gamut multiprimary display. Earlier research showed a clear dependence on hue but was limited by the gamut of the display it employed; the present work builds on this while easing the gamut constraints. In the first part of the present experiment, a tuning task was used to refine the preference for chroma boost starting with standard‐gamut (Rec. 709) images. The overall median preferred boost is roughly 20%, but it is not uniform over hues: the preferred boost for orange, yellow, green, and cyan colors is greater than that for blue, magenta, and red colors. Dependence on image content and observer is noted, though a content‐independent chroma boost created by aggregating preference over many images performs well. An adjustment parameter for overall chroma, which incorporates the hue dependence averaged over image content, should be sufficient to handle the vast majority of interobserver variance in preference. In the second part of the experiment, various chroma boost algorithms were evaluated through a paired comparison task. The prescribed hue‐dependent chroma boost is preferred over all other variations, and all hue‐preserving chroma boost variations are preferred over both colorimetrically accurate and na??ve same‐drive‐signal renderings. The results may be applied in display design to select gamut boundaries that maximize satisfaction over the observer population. © 2012 Wiley Periodicals, Inc. Col Res Appl, 39, 169–178, 2014     

NAFLA – Ein Simulationswerkzeug zur analytischen Abschätzung von Schadstofffahnenlängen

Groundwater pollution with organic contaminants remains a world-wide problem. Before selection of any remediation technique, it is important to pre-assess contaminated sites with respect to their hazard. For this, several analytical and numerical approaches have been used and an initial assessment of contaminated sites the MS-Excel^© tool “NAFLA” was developed. “NAFLA” allows a quick and straightforward calculation and comparison of some analytical approaches for the estimation of maximum plume length under steady-state conditions. These approaches differ from each other in source geometry, model domain orientation, and in the consideration of (bio)chemical reaction within the domain. In this communication, we provide details about the development of “NAFLA”, its possible usage and information for users. The tool is especially designed for application in student education, by authorities and consultants.     

Trans isomeric octadecenoic acids are related inversely to arachidonic acid and DHA and positively related to mead acid in umbilical vessel wall lipids

Long-chain PUFA play an important role in early human neurodevelopment. Significant inverse correlations were reported between values of trans isomeric and long-chain PUFA in plasma lipids of preterm infants and children aged 1–15 yr as well as in venous cord blood lipids of full-term infants. Here we report FA compositional data of cord blood vessel wall lipids in 308 healthy, full-term infants (gestational age: 39.7±1.2 wk, birth weight: 3528±429 g, mean±SD). The median (interquartile range) of the sum of 18-carbon trans FA was 0.22 (0.13)% w/w in umbilical artery and 0.16 (0.10)% w/w in umbilical vein lipids. Nonparametric correlation analysis showed significant inverse correlations between the sum of 18-carbon trans FA and both arachidonic acid and DHA in artery (r=−0.38, P<0.01, and r=−0.20, P<0.01) and vein (r=−0.36, P<0.01, and −0.17, P<0.01) wall lipids. In addition, the sum of 18-carbon trans FA was significantly positively correlated to Mead acid, a general indicator of EFA deficiency, in both artery (r=+0.35, P<0.01) and vein (r=+0.31, P<0.01) wall lipids. The present results obtained in a large group of full-term infants suggest that maternal trans FA intake is inversely associated with long-chain PUFA status of the infant at birth.     

The European project trust—reconfigurable terminals and supporting networks

To date, research into reconfigurable mobile communications has predominantly focussed on the software radio concept, and specifically on the hardware technologies required to move physical layer processing into a programmable environment [1, 2, 3]. Although an interesting and necessary challenge, this only represents a fraction of the overall support and technology required to realise the potential of the concept. Other necessary developments include network/terminal cooperation for seamless inter-standard handoff, QoS management for software download and reconfiguration, a secure software download mechanism, terminal software and mobile radio network architecture supporting terminal reconfiguration, management for software downloads, configuration management, capability negotiation, radio resource management and spectrum allocation policies etc… This paper describes results from the EuropeanIst Trust (Transparently Reconfigurable UbiquitouS Terminal) [4] project concerning user and operator requirements, the proposed overall system environment, security issues, concerted radio resource management, and expected time frame for the development of reconfigurable terminals.     

Self-contained microelectrochemical immunoassay for small volumes using mouse IgG as a model system

A self-contained, microelectrochemical immunoassay on the smallest volumes reported to date (1 microL for the antigen, 1 microL for the secondary antibody-enzyme conjugate, and 200 nL for the electrochemically detected species) has been developed using mouse IgG as a model system in a sandwich-type enzyme-linked immunosorbant assay, which takes less than 30 min to both complete the assembly of immunoassay components onto the antibody-modified surface and detect enzymatically generated species (excluding time for electrochemical cleaning of electrodes). These studies demonstrate the advantage of the close proximity of electrodes to modified surfaces and their application in the analysis of small volumes. Using a 50 microm diameter x 8 microm deep cavity with individually addressable electrodes on a microfabricated chip, the primary antibody was selectively and covalently attached at a gold, recessed microdisk (RMD) at the bottom of the microcavity to the free end of SAMs of either 11-mercaptoundecanoic acid or 11-mercapto-1-undecanol using 1-ethyl-3-[3-(dimethylamino)propyl]carbodiimide hydrochloride. Nonspecific adsorption to the surrounding material, polyimide, of the microcavity device was eliminated. Electrochemical desorption was used to confine the immunoassay activity at the RMD. Enzymatic conversion of the substrate p-aminophenyl phosphate top-aminophenol is detectable in less than 30 s using cyclic voltammetry at a gold, tubular nanoband electrode, which is on the wall of the microcavity and immediately adjacent to the modified RMD. A third electrode, also within the region of the microcavity, served as the pseudoreference/auxiliary electrode. Calibration curves obtained for 1-microL solutions of 5-100 ng/mL of IgG and for 200 nL-solutions of 5 microM to 4 mM of PAPR gave detection limits of 4.4 nM (6.4 ng/mL) or 880 fmol (129 pg) for PAPR and 56 fM (9 pg/mL) or 56 zmol (9 fg) for IgG. It is expected that the device may be suitable for analysis with volumes down to tens of picoliters.     

Virtual Private Ad Hoc Networking

The fact that a lot of applications require secure communication to take place only between a dynamic subset of distributed devices sharing a common context, is, from a network point of view, very challenging and demanding. Existing technologies such as VPN, P2P overlays or VLANs can only partially respond to these requirements. This observation is the key factor that has driven the proposal of the virtual private ad hoc network concept. Virtual private ad hoc networks (VPAN) are secure and self-organizing overlay networks on top of existing IP infrastructure that use ad hoc networking techniques to enable network connectivity. The underlying IP infrastructure can be the Internet, cellular networks, ad hoc networks, mesh networks … or combinations thereof. A virtual private ad hoc overlay network creates a transparent, shielded and trusted environment for the applications and services running on the participants' devices. The overlay uses internal addressing and ad hoc routing, thereby forming a virtual network on top of the physical infrastructure. In addition, the overlay must be self-organizing and self-maintaining upon member mobility or membership changes. This paper gives an overview of the potential applications, a high-level network architecture and the network challenges emerging from the novel concept of virtual private ad hoc networking. Jeroen Hoebeke was born in Ghent, Belgium in 1979. In 2002 he received the Masters degree in engineering (Computer Science) from the University of Ghent. In August 2002, he joined the Broadband Communications Networks Group. His PhD research includes the development of adaptive routing protocol techniques for mobile ad hoc networks. His main research interests are in ad hoc wireless communications and, more generally, in broadband wireless communications. Within the European MAGNET project, he is actively involved in the development of a network architecture and demonstrator for Personal Networks, with a prime focus on routing and connectivity. Gerry Holderbeke was born in Zottegem, Belgium in 1982. He graduated in Informatics at the University of Ghent in 2004. In August 2004 he joined the Broadband Communications Networks Group where he is currently working as a project developer. His research currently includes the development of an emulator for mobile ad hoc networks. His main research interests are in ad hoc networks and broadband wireless communications and involve routing, addressing and more generally, communication within mobile ad hoc networks and infrastructured networks. Within the European MAGNET project, he is actively involved in the development of a network architecture for Personal Networks, with a prime focus on the implementation of the routing architecture. Ingrid Moerman was born in Gent, Belgium in 1965. She received the degree in Electro-technical Engineering and the Ph.D degree from the Ghent University, Gent, Belgium in 1987 and 1992, respectively. Since 1987, she has been with the Interuniversity Micro-Electronics Centre (IMEC) at the Department of Information Technology (INTEC) of the Ghent University, where she conducted research in the field of optoelectronics. In 1997, she became a permanent member of the Research Staff at IMEC. Since 2000 she is part-time professor at the Ghent University. Since 2001 she has switched her research domain to broadband communication networks. She is currently involved in the research and education on broadband mobile & wireless communication networks and on multimedia over IP. The main research topics related to mobile & wireless communication networks are: wireless access to vehicles (high bandwidth & driving speed), adaptive QoS routing in wireless ad hoc networks, body area networks, protocol boosting on wireless links, design of fixed access/metro part, traffic engineering and QoS support in the wireless access network. Ingrid Moerman is author or co-author of more than 300 publications in the field of optoelectronics and communication networks. Bart Dhoedt received a degree in Engineering from the Ghent University in 1990. In September 1990, he joined the Department of Information Technology of the Faculty of Applied Sciences, University of Ghent. His research, addressing the use of micro-optics to realize parallel free space optical interconnects, resulted in a PhD degree in 1995. After a 2 year post-doc in opto-electronics, he became professor at the Faculty of Applied Sciences, Department of Information Technology. Since then, he is responsible for several courses on algorithms, programming and software development. His research interests are software engineering and mobile & wireless communications. Bart Dhoedt is author or co-author of approximately 70 papers published in international journals or in the proceedings of international conferences. His current research addresses software technologies for communication networks, peer-to-peer networks, mobile networks and active networks. Piet Demeester received the Masters degree in Electro-technical engineering and the Ph.D degree from the Ghent University, Gent, Belgium in 1984 and 1988, respectively. In 1992 he started a new research activity on broadband communication networks resulting in the IBCN-group (INTEC Broadband communications network research group). Since 1993 he became professor at the Ghent University where he is responsible for the research and education on communication networks. The research activities cover various communication networks (IP, ATM, SDH, WDM, access, active, mobile), including network planning, network and service management, telecom software, internetworking, network protocols for QoS support, etc. Piet Demeester is author of more than 300 publications in the area of network design, optimization and management. He is member of the editorial board of several international journals and has been member of several technical program committees (ECOC, OFC, DRCN, ICCCN, IZS, &).