Fast in situ 3D nanoimaging: a new tool for dynamic characterization in materials science

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Photocatalytic activity of a new composite material of Fe (III) oxide nanoparticles wrapped by a matrix of polymeric carbon nitride and amorphous carbon

Polymeric carbon nitride was synthesized from urea and doped with Cu and Fe to act as co-catalysts. The material doped with Fe was a new composite material composed of Fe(III) oxides (acting as a co-catalyst) wrapped by the polymer layers and amorphous carbon. Furthermore, the copper doped material was described in a previous report. The photocatalytic degradation of the azo dye direct blue 1 (DB) was studied using as photocatalysts: pure carbon nitride (CN), carbon nitride doped with Cu (CN-Cu) and carbon nitride doped with Fe (CN-Fe). The catalysts were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), by X-ray photoelectron spectroscopy (XPS) and Brunauer–Emmett–Teller method (BET), etc. The adsorption phenomenon was studied using the Langmuir and Freundlich models. For the kinetic study, a solution of 500 mg L^?1 of DB1 was treated with each catalyst, visible light and H₂O₂. The dye concentration was measured by spectrophotometry at the wavelength of 565 nm, and the removal of the total organic content (TOC) was quantified. BET analysis yielded surface areas of 60.029, 20.116 and 70.662 m²g^?1 for CN, CN-Cu and CN-Fe, respectively. The kinetics of degradation were pseudo-first order, whose constants were 0.093, 0.039 and 0.110 min^?1 for CN, CN-Cu and CN-Fe, respectively. The total organic carbon (TOC) removal reached the highest value of 14.46% with CN-Fe.     

Utilizing Iron's Attractive Chemical and Magnetic Properties in Microrocket Design,Extended Motion,and Unique Performance

All‐in‐one material for microrocket propulsion featuring acid‐based bubble generation and magnetic guidance is presented. Electrochemically deposited iron serves as both a propellant, toward highly efficient self‐propulsion in acidic environments, and as a magnetic component enabling complete motion control. The new microrockets display longer lifetime and higher propulsion efficiency compared to previously reported active metal zinc‐based microrockets due to the chemical properties of iron and the unique structure of the microrockets. These iron‐based microrockets also demonstrate unique and attractive cargo towing and autonomous release capabilities. The latter is realized upon loss of the magnetic properties due to acid‐driven iron dissolution. More interestingly, these bubble‐propelled microrockets assemble via magnetic interactions into a variety of complex configurations and train structures, which enrich the behavior of micromachines. Modeling of the magnetic forces during the microrocket assembly and cargo capture confirms these unique experimentally observed assembly and cargo‐towing behaviors. These findings provide a new concept of blending propellant and magnetic components into one, toward simplifying the design and fabrication of artificial micro/nanomachines, realizing new functions and capabilities for a variety of future applications.     

Use of 3D printing for biofuel production: efficient catalyst for sustainable biodiesel production from wastes

This work deals with the sustainable biodiesel production from low-cost renewable feedstock (waste and non-edible oils) using a heterogeneous catalyst constituted by potassium loaded on an amorphous aluminum silicate naturally occurring as volcanic material (pumice). The main challenge to biodiesel production from low-quality oils (used oils and greases) is the high percentage of free fatty acids (FFAs) and water in the feedstock that causes undesirable side reactions. The catalytic materials studied were tested in the transesterification reaction when using low-quality oils containing a high proportion of free fatty acids (FFAs) and water. Results indicated that the amount of acid and basic sites on the catalytic surface increases upon increasing potassium loading in the catalyst, displaying better performance for biodiesel production. Indeed, the modification of the aluminum silicate substrate upon potassium incorporation results in a catalytic material containing both acidic and basic sites, which are responsible for both triglycerides transesterification and FFA esterification reactions. The studied catalyst not only showed good performance in the biodiesel production reaction but also good tolerance to FFA and water contained in the feedstock for biodiesel production. The catalytic material was microstructured by 3D printing in order to design a catalytic stirring system with high mechanical strength, efficient and reusable. The use of 3D printing in biofuel production is a novelty that brings good solutions for catalyst production.     

Technologies and logistics for phosphorus recovery from livestock waste

Phosphorus (P) runoff from livestock waste can trigger algal blooms that adversely affect aquatic life and human health. One strategy to mitigate this problem is to install nutrient recovery technologies that concentrate and mobilize nutrients from nutrient-rich regions to nutrient-deficient ones. We present supply chain design formulations to identify optimal types and locations for P recovery technologies. The formulations capture trade-offs in transportation costs, technology efficiency, investment/operational costs, revenue collected from different recovered products (struvite and nutrient cakes), and environmental impact. Our computational framework is used to analyze the impact of different scenarios for market prices of recovered products, recovery yields, and remediation costs. We find that transportation of waste alone (without any processing) can achieve significant reductions in environmental impact at low cost, but cannot achieve economic sustainability in the long run due to the lack of direct revenue streams. Mechanical separation technologies that recover P in the form of nutrient cakes are low-cost solutions that can achieve high environmental benefits and reduced transportation costs, but revenues are also limited due to low values of the cakes. Struvite crystallization in fluidized beds is found to be a highly attractive option under current struvite prices, but economic sustainability is strongly dependent on yield recoveries (which are currently highly uncertain).     

Metamaterial-based graphene thermal emitter

A thermal emitter composed of a frequency-selective surface metamaterial layer and a hexagonal boron nitride-encapsulated graphene filament is demonstrated. The broadband thermal emission of the metamaterial (consisting of ring resonators) was tailored into two discrete bands, and the measured reflection and emission spectra agreed well with the simulation results. The high modulation frequencies that can be obtained in these devices, coupled with their operation in air, confirm their feasibility for use in applications such as gas sensing.

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Effects of a startling acoustic stimulus on reaction time in different parkinsonian syndromes

BACKGROUND: The functional assessment of the startle circuit is usually done by analyzing the acoustic startle response (ASR). However, a startling acoustic stimulus (SAS) also induces changes in the excitability of neural structures that can be demonstrated by studying the SAS-induced change in the behavior of certain neurophysiologic responses. OBJECTIVE: To examine the effects induced by an SAS on voluntary reaction time in patients with parkinsonian syndromes (StartReact effect) and to compare the results with those obtained in a group of age-matched healthy volunteers. METHODS: Twelve patients with idiopathic PD (IPD), seven patients with progressive supranuclear palsy (PSP), seven patients with multisystem atrophy (MSA), and seven healthy age-matched control volunteers performed a simple visual reaction time task and received SAS together with the "go" signal in random trials. RESULTS: Baseline reaction time was significantly slower in PSP patients than in control subjects and MSA patients. The SAS induced a significant shortening of the reaction time in control subjects and in patients with IPD and MSA, but not in patients with PSP. The percentage of reaction time shortening with regard to the baseline values also differed significantly between PSP patients and the other groups of subjects. The StartReact effect was consistent throughout the experiment and showed reduced habituation with repeated testing. CONCLUSIONS: The results are consistent with an abnormal function of the startle circuit in patients with PSP and agree with previous studies using the ASR. The reduced habituation of the StartReact effect favors its clinical applicability in the assessment of differences between patients with parkinsonian syndromes.     

Design of product as source of variance in composition of meat-based infant beikosts

The influence of both the design of the product (formulated raw ingredients) and type of product (on the meat type formulated base) on the mineral composition, crude protein (CP), protein digestibility (PD), total dietary fiber (TDF) and phytic acid (FA) contents of meat-based infant beikosts was studied. The product design was the main factor determining the CP, TDF, Ca, Na and K contents, while the type of product was the main factor determining the PD, FA, Zn, Fe and Mn contents. High K and Mn levels were related to high TDF contents. CP and Zn showed a significant relationship but the CP Fe relationship was not significant.