High-temperature oxidation of pure titanium in CO2 and Ar-10%CO2 atmospheres

The oxidation behavior of pure titanium has been investigated in the temperature range of 1000 K to 1300 K in CO₂ or Ar-10%CO₂. Optical microscopy, electron probe microanalyses, and X-ray measurements on the oxide scales formed during oxidation indicate that their structures are nearly independent of temperature and the corrosion atmosphere. The scales consisted of two layers, an external one and an internal one, having a rutile (TiO₂) structure. The parabolic rate law was confirmed for growth of the external scale and the permeation depth of oxygen in titanium with apparent activation energies of 266 and 226 kJ/mol, respectively. The rate-determining diffusion species in the oxidation processes are discussed.     

Expectation-maximization algorithms for inference in Dirichlet processes mixture

Mixture models are ubiquitous in applied science. In many real-world applications, the number of mixture components needs to be estimated from the data. A popular approach consists of using information criteria to perform model selection. Another approach which has become very popular over the past few years consists of using Dirichlet processes mixture (DPM) models. Both approaches are computationally intensive. The use of information criteria requires computing the maximum likelihood parameter estimates for each candidate model whereas DPM are usually trained using Markov chain Monte Carlo (MCMC) or variational Bayes (VB) methods. We propose here original batch and recursive expectation-maximization algorithms to estimate the parameters of DPM. The performance of our algorithms is demonstrated on several applications including image segmentation and image classification tasks. Our algorithms are computationally much more efficient than MCMC and VB and outperform VB on an example.     

High-aspect-ratio through-hole array microfabricated in a PMMA plate for monodisperse emulsion production

Microchannel (MC) emulsification is a promising technique for producing monodisperse emulsions consisting of highly uniform droplets. The authors developed a high-aspect-ratio microstructure (HARMST) made of poly(methyl methacrylate) (PMMA) as a new MC emulsification device. A PMMA straight-through MC array plate consisting of 31,250 through-holes with a 7.3 × 22.9-μm oblong section and a 200-μm depth was fabricated by a process of synchrotron radiation (SR) lithography and etching. Oblong MCs fabricated in a PMMA straight-through MC array were highly uniform with a coefficient of variation of less than 2%. The fabricated PMMA straight-through MC array plate was used to produce water-in-oil (W/O) emulsions. Monodisperse W/O emulsions with average droplet diameters of approximately 25 μm and a minimum coefficient of variation of 3.2% were produced via a hydrophobic PMMA straight-through MC array. The PMMA straight-through MC array plate also produced monodisperse W/O emulsions at droplet production rates of up to 1.7 × 10⁴/s. The PMMA straight-through MC array plates developed in this work are expected to expand the application field of emulsification using straight-through MC array plates, which have previously been made of single-crystal silicon.     

Analysis of electro‐optical properties of polymer‐stabilized OCB and the application to TFT‐LCDs

Abstract— A 9‐in. full‐color polymer‐stabilized OCB TFT‐LCD with stable bend alignment in the absence of an electric field was developed. The condition of the polymer stabilization, the characteristics of UV‐curable monomers, and their influence on the configurations of the polymer network in the cell were studied. Possible models of the configuration were proposed and their relationship to the electro‐optical properties was analyzed using a novel simulation method considering the distribution of anchoring effects from both alignment surfaces and the polymer network. It was suggested that a good performance such as high contrast ratio and fast response could be expected in the polymer network originating from newly developed monomers composed of multifunctional LC acrylates due to a relatively weak‐anchoring effect and presumably its localization near the alignment surfaces. By using the newly developed monomers under the optimized polymer‐stabilizing process, a high contrast ratio of 250:1 and fast response nearly equal to that of a conventional OCB cell were achieved.     

Production of monodisperse water-in-oil emulsions consisting of highly uniform droplets using asymmetric straight-through microchannel arrays

This paper reports the production of monodisperse water-in-oil (W/O) emulsions using new microchannel emulsification (MCE) devices, asymmetric straight-through MC arrays that were hydrophobically modified. The silicon asymmetric straight-through MC arrays consisted of numerous pairs of microslots and circular microholes whose cross-sectional sizes were 10 μm. This paper primarily focused on investigating the effect of the osmotic pressure of a dispersed phase (Π_d) on MCE. This paper also investigated the effects of the type of continuous-phase oils and the dispersed-phase flux (J _d) on MCE. The dispersed phases were Milli-Q water and Milli-Q water solutions containing sodium chloride. The continuous phases were decane (as control), hexane, medium chain triacylglyceride (MCT), and refined soybean oil (RSO) solutions containing tetraglycerin monolaurate condensed ricinoleic acid ester (TGCR) as a surfactant. At Π_d of exceeding threshold, highly uniform aqueous droplets with coefficients of variation of less than 3% were stably generated via hydrophobic asymmetric straight-through MCs. Monodisperse W/O emulsions with average droplet diameters between 32 and 45 μm were produced using the alkane–oil and triglyceride–oil solutions as the continuous phase. This work also demonstrated that the hydrophobic asymmetric straight-through MC array had remarkable ability to produce highly uniform aqueous droplets at very high J _d of up to 1,200 L m⁻² h⁻¹.     

Magnetic order and evolution of the electronic state aroundx=0.12 in La2?xBaxCuO4 and La2?xSrxCuO4

Muon spin rotation ( ⁺SR) measurement provides clear evidence of the antiferromagnetic order of Cu moments below 35 K for La_2–x Ba _x CuO₄ and below 15 K for La_2–x Sr _x CuO₄ in the narrow range ofx where the high-T _c superconductivity (SC) is suppressed remarkably. The results suggest that the change of the electronic state coupled with the lattice instability is relevant to the local suppression of SC and freezing of spin fluctuations of the Cu moment.     

Generation of uniform drops via through-hole arrays micromachined in stainless-steel plates

This study investigated the generation of oil drops using new symmetric and asymmetric through-hole-array devices made of stainless steel. The through-hole-array devices were built by piling up six stainless-steel plates, each having circular micro-holes with a diameter of 300 or 500 μm or micro-slots with a shorter line of 300 or 500 μm. Drops were generated by injecting a dispersed phase (refined soybean oil) via the through-hole array into a compartment filled with a continuous phase (Milli-Q water solution containing one of two emulsifiers). The drop detachment from symmetric and asymmetric through holes was observed in real time and analyzed. Uniform oil drops with average diameters of 1.0–4.1 mm and coefficients of variation of typically less than 6% were generated using symmetric and asymmetric through-hole-array devices. The resultant drop diameters for asymmetric through-hole arrays were significantly smaller than those for symmetric through-hole arrays. This paper also discusses experimental results regarding the effects of the microstructure, the dimensions of the through holes, and the type of emulsifier on drop generation and the resultant drop diameter.     

Straight-through microchannel devices for generating monodisperse emulsion droplets several microns in size

The authors recently proposed a promising technique for producing monodisperse emulsions using a straight-through microchannel (MC) device composed of an array of microfabricated oblong holes. This research developed new straight-through MC devices with tens of thousands of oblong channels of several microns in size on a silicon-on-insulator plate, and investigated the emulsification characteristics using the microfabricated straight-through MC devices. Monodisperse oil-in-water (O/W) and W/O emulsions with average droplet diameters of 4.4–9.8 μm and coefficients of variation of less than 6% were stably produced using surface-treated straight-through MC devices that included uniformly sized oblong channels with equivalent diameters of 1.7–5.4 μm. The droplet size of the resultant emulsions depended greatly on the size of the preceding oblong channels. The emulsification process using the straight-through MC devices developed in this research had very high apparent energy efficiencies of 47–60%, defined as (actual energy input applied to droplet generation/theoretical minimum energy input necessary for making droplets) × 100. Straight-through MC devices with numerous oblong microfluidic channels also have great potential for increasing the productivity of monodisperse fine emulsions.     

Site-specific electronic structure analysis by channeling EELS and first-principles calculations

Site-specific electronic structures were investigated by electron energy loss spectroscopy (EELS) under electron channeling conditions. The Al-K and Mn-L(2,3) electron energy loss near-edge structure (ELNES) of, respectively, NiAl2O4 and Mn3O4 were measured. Deconvolution of the raw spectra with the instrumental resolution function restored the blunt and hidden fine features, which allowed us to interpret the experimental spectral features by comparing with theoretical spectra obtained by first-principles calculations. The present method successfully revealed the electronic structures specific to the differently coordinated cationic sites.     

Shock response analysis on thermal stick–slip phenomenon in hard disk drive

We measured and calculated shock responses due to the thermal stick–slip phenomenon in hard disk drives. We first measured the stress wave propagation and found that a stress wave travels over the entire top cover of the drive in 30?μs at two velocities: 4.66 and 2.97?km/s. These are the velocities of longitudinal and distortional waves in a plate, respectively. The position error signal responded in 55?μs after the thermal stick–slip phenomenon happened. We then conducted a numerical analysis of wave propagation. The resultant stress wave propagation and the position error corresponded well to the measured ones. We found that the propagation path which leads overwriting on adjacent tracks is through the actuator to the head, not through the spindle motor to the disk. We concluded that stress waves can be detected with a shock sensor before they arrive at the head if the sensor is located at the pivot bearing or the actuator, which are on the propagation path.