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排序方式: 共有4483条查询结果,搜索用时 15 毫秒
81.
Yeshu Tan Jianrui Feng Haobo Dong Longxiang Liu Siyu Zhao Feili Lai Tianxi Liu Ying Bai Ivan P. Parkin Guanjie He 《Advanced functional materials》2023,33(4):2209967
Platinum (Pt) is regarded as a promising electrocatalyst for hydrogen evolution reaction (HER). However, its application in an alkaline medium is limited by the activation energy of water dissociation, diffusion of H+, and desorption of H*. Moreover, the formation of effective structures with a low Pt usage amount is still a challenge. Herein, guided by the simulation discovery that the edge effect can boost local electric field (LEF) of the electrocatalysts for faster proton diffusion, platinum nanocrystals on the edge of transition metal phosphide nanosheets are fabricated. The unique heterostructure with ultralow Pt amount delivered an outstanding HER performance in an alkaline medium with a small overpotential of 44.5 mV and excellent stability for 80 h at the current density of −10 mA cm−2. The mass activity of as-prepared electrocatalyst is 2.77 A mg−1Pt, which is 15 times higher than that of commercial Pt/C electrocatalysts (0.18 A mg−1Pt). The density function theory calculation revealed the efficient water dissociation, fast adsorption, and desorption of protons with hybrid structure. The study provides an innovative strategy to design unique nanostructures for boosting HER performances via achieving both synergistic effects from hybrid components and enhanced LEF from the structural edge effect. 相似文献
82.
Klara Suchan Justus Just Pascal Beblo Carolin Rehermann Aboma Merdasa Roland Mainz Ivan G. Scheblykin Eva Unger 《Advanced functional materials》2023,33(3):2206047
Photo- and charge-carrier-induced ion migration is a major challenge when utilizing metal halide perovskite semiconductors for optoelectronic applications. For mixed iodide/bromide perovskites, the compositional instability due to light- or electrical bias induced phase-segregation restricts the exploitation of the entire bandgap range. Previous experimental and theoretical work suggests that excited states or charge carriers trigger the process, but the exact mechanism is still under debate. To identify the mechanism and cause of light-induced phase-segregation phenomena, the full compositional range of methylammonium lead bromide/iodide samples are investigated, MAPb(BrxI1-x)3 with x = 0…1, by simultaneous in situ X-ray diffraction (XRD) and photoluminescence (PL) spectroscopy during illumination. The quantitative comparison of composition-dependent in situ XRD and PL shows that at excitation densities of 1 sun, only the initial stage of photo-segregation is rationalized with the previously established thermodynamic models. However, a progression of the phase segregation is observed that is rationalized by considering long-lived accumulative photo-induced material alterations. It is suggested that (additional) photo-induced defects, possibly halide vacancies and interstitials, need to be considered to fully rationalize light-induced phase segregation and anticipate the findings to provide crucial insight for the development of more sophisticated models. 相似文献
83.
Lee Connie M. S. Fong Kenneth N. K. Mok Maggie M. Y. Lam M. K. Kung Y. Chan Paven P. W. Ma Maggie K. M. Lui S. L. Kwan Lorraine P. Y. Chu W. L. Hui P. C. Yau Christina S. F. Kwan Ivan W. L. Chan Kelsey Y. M. Chan T. M. 《Virtual Reality》2023,27(3):1571-1583
Virtual Reality - Cognitive impairment is not uncommon in patients with end-stage renal disease and can make it more difficult for these patients to carry out peritoneal dialysis (PD) on their own.... 相似文献
84.
Compagnucci Ivan Corradini Flavio Fornari Fabrizio Polini Andrea Re Barbara Tiezzi Francesco 《Software and Systems Modeling》2023,22(3):969-1004
Software and Systems Modeling - The Internet of things has been adopted in several sectors both influencing how people work and enhancing organizations’ business processes. This resulted in... 相似文献
85.
Farrugia Russell Portelli Barnaby Grech Ivan Camilleri Duncan Casha Owen Micallef Joseph Gatt Edward 《Microsystem Technologies》2022,28(6):1451-1465
Microsystem Technologies - The maximum scan angle amplitude of resonating micro-mirrors, intended for micro-projection display applications is limited by air damping. Three-dimensional transient... 相似文献
86.
Stratified concrete poses a promising alternative for construction. Its fresh and hardened properties have been studied at the material level; however, structural behavior in steel reinforced specimens has not been studied. This paper focuses on the flexural behavior of eight stratified reinforced concrete (SRC) specimens representing slices from a slab or non-bearing wall. Specimens with two stratified concrete designs and three steel ratios were tested and compared to estimates from a fiber element numerical model and rectangular stress-block design methods from ACI 318 and Eurocode 2. The results suggest that SRC has similar damage modes as ordinary reinforced concrete (ORC). The fiber element model accurately estimated the measured behavior, while ACI 318 and Eurocode 2 differed from the experimental results by <25%. These prediction accuracies are similar to those for ORC. Therefore, the flexural design of SRC can be done using both fiber element and rectangular stress-block approaches. 相似文献
87.
Biodegradable Microparticles for Simultaneous Detection of Counterfeit and Deteriorated Edible Products 下载免费PDF全文
Ivan Rehor Sophie van Vreeswijk Tina Vermonden Wim E. Hennink Willem K. Kegel Huseyin Burak Eral 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(39)
In an era of globalized trade relations where food and pharmaceutical products cross borders effortlessly, consumers face counterfeit and deteriorated products at elevated rates. This paper presents multifunctional, biodegradable hydrogel microparticles that can provide information on the authenticity and the potential deterioration of the tagged food or pharmaceutical formulations. These microparticles integrate spatially patterned authenticity code with two sensors—the first one detects possible presence of pathogenic microbes through monitoring pH while the second one identifies products stored above optimal temperatures via optical monitoring of the microparticle degradation. Particles are synthesized from a biocompatible polymer and a photoinitiator, dextran modified with 2‐hydroxyethylmethacrylate and riboflavin, respectively, using a continuous, high throughput method stop‐flow lithography. The proposed synthesis approach also enables crosslinking with visible light bringing about additional flexibility to flow lithography. Model liquid and solid food and pharmaceutical products are successfully labeled with microparticles and the functionality of the sensors in aqueous solutions is demonstrated. 相似文献
88.
José Augusto de Oliveira Diogo Aparecido Lopes Silva Mariana Guardia Lillian do Nascimento Gambi Otávio José de Oliveira Aldo Roberto Ometto 《Clean Technologies and Environmental Policy》2017,19(6):1761-1774
The companies’ needs to adopt changes in their way of production to maximize the environmental performance required by their stakeholders, and at the same time, to maximize their economic and market performance, have made them seek for environmental strategies and certifications. In this sense, the Cleaner Production and the Environmental Management System based on ISO 14001 have been, respectively, presented, since the main objective of this research is to identify and analyze Cleaner Production contributions to comply with ISO 14001 requirements. For such, a survey research has been carried out in Brazilian industrial companies certified by ISO 14001. We have identified the main performance factors by leading practices and variables of Cleaner Production that contribute to the compliance with the standard requirements by companies. Thus, it has been noted that Cleaner Production is an important strategy for the preparation of companies for certification as well as for improving their environmental performance. 相似文献
89.
High Conductivity in Molecularly p‐Doped Diketopyrrolopyrrole‐Based Polymer: The Impact of a High Dopant Strength and Good Structural Order 下载免费PDF全文
Yevhen Karpov Tim Erdmann Ivan Raguzin Mahmoud Al‐Hussein Marcus Binner Uwe Lappan Manfred Stamm Kirill L. Gerasimov Tetyana Beryozkina Vasiliy Bakulev Denis V. Anokhin Dimitri A. Ivanov Florian Günther Sibylle Gemming Gotthard Seifert Brigitte Voit Riccardo Di Pietro Anton Kiriy 《Advanced materials (Deerfield Beach, Fla.)》2016,28(28):6003-6010
90.
Insight into In Situ Amphiphilic Functionalization of Few‐Layered Transition Metal Dichalcogenide Nanosheets 下载免费PDF全文