一种基于产生式的流程模型分析方法*

在深入分析业务流程模型和合理的抽象业务活动基础上,提出了一种基于产生式的流程模型形式化分析方法,并提供了一种从一般流程描述到该模型的转换方法;在此基础上,推导了一系列行之有效的流程属性验证规则,并通过应用实际例子证明了所提出方法的有效性。     

门限多代理多签名方案*

将门限签名体制引入到多代理多签名方案中,首次提出了一个门限多代理多签名方案。新方案不仅能实现多个原始签名人将签名权委托给多个代理签名人,还能将每个代理人的密钥进行分享,实现一定数量的原始签名人就能授权,一定数量的代理签名人就能产生有效的代理签名。另外,新方案还可以控制代理签名的有效时间和回收代理签名权。     

基于库存论的模型库建立与实现*

以库存论为理论基础,在SQL Server 2000与Visual Studio.NET环境下设计实现了一个模型库;模型库按功能进行了分类介绍,并对每一类中的功能和算法进行阐述,给出了实现的方法。     

Mechanical nondiscoloring and antistretching photonic crystal films based on Zn2+ coordination and hydroxypropyl methylcellulose

Mechanical nondiscoloring and antistretching photonic crystal (PC) films, especially those with stable structure colors during deformation, have great potential applications in wearable display devices, decoration, and packaging. Here, PC films with antistretching and invariant structural colors during deformation were prepared, by combining Zn²⁺ coordinated elastic material and hydroxypropyl methylcellulose (HPMC) with polystyrene@silica (PS@SiO₂) colloidal crystals. The PC films release energy by forming local fractures at a microscopic level during the straining process but the lattice spacing and effective refractive index of the local array do not change. According to the Bragg law, the structure color remains unchanged. The introduction of HPMC gave the PC films excellent tensile properties, and the maximum tensile strength reached 10 MPa. And after 100 times of stretching, bending and compression cycles, the structural color remained unchanged.     

Synthesis and characterization of poly(hexamethylene terephthalate/hexamethylene oxamide) alternating copolyamide (alt-PA6T/62)

As a representative polyoxamide, poly(hexamethylene oxamide) (PA62) has good comprehensive performance. However, the high T_m (330°C) creates an obstacle for processing. To improve the processability of PA62, poly(hexamethylene terephthalate/hexamethylene oxamide) alternating copolyamide (alt-PA6T/62) was synthesized by hexamethylene diamine-terminated 6T6-diamine and dibutyl oxalate via solution/solid state polycondensation. Random copolyamide (ran-PA6T/62) was also synthesized for comparison. The structure and properties of the copolymer were analyzed by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR) spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Wide-angle X-ray diffraction (WAXD) and the saturated water absorption test. The NMR results confirm the alternating structure of alt-PA6T/62. The DSC and TGA results demonstrate that the novel alternating copolyamide alt-PA6T/62 (T_m = 321°C, T₅ = 420°C) exhibited better thermal properties than those of ran-PA6T/62 (T_m = 294°C, T₅ = 412°C). The saturated water absorption of alt-PA6T/62 was found to be 3.2 wt%. These results revealed that the novel alt-PA6T/62 had an alternating sequence distribution, showed a high melting point as well as good processability and thermal stability, and possessed low saturated water absorption and excellent dimensional stability.     

Low surface energy self-polishing polymer grafted MWNTs for antibacterial coating and controlled-release property of Cu2O

Marine biofouling had been a headache when engaging in marine activities. The most effective and convenient method for dealing with this problem was to apply antifouling coatings. But now a single anti-fouling system was hard to satisfy the requirement of anti-fouling simultaneously. Therefore, it was particularly important to develop novel multi-system anti-fouling technology. In the work, a novel polymer coatings with polydimethylsiloxane (PDMS) segments in the main chain and hydrolysable side chain was designed and synthesized which showed low surface energy and self-polishing performance, and then we creatively covalently immobilized the polyurethane on the surface of multi-carbon nanotubes (MWNTs) to form multisystem antifouling coating. The results showed that the polymer coating would produce hydrolysable regions in the hydrophobic PDMS segment to endure the polymer coating hydrophobic and hydrolysis properties when contacted with water. In addition, the self-polishing rate and the surface energy could be regulated by varying its copolymerization, and the addition of MWNTs could kill the microorganisms and endowed the polymer coating itself enhanced antibacterial effect. Furthermore, considering the high specific surface area and physicochemical characteristics of MWNTs, it could be combined with antifoulant Cu₂O through a polar or non-polar combination as a carrier to control the release rate of Cu₂O in coatings.     

Systematic investigation on the effect of crosslinking agent type and dosage on the performance of TPU/MVQ based thermoplastic vulcanizates

Dynamic vulcanized thermoplastic polyurethane (TPU)/methyl vinyl silicone rubber (MVQ) thermoplastic vulcanizates (TPVs) were prepared in torque rheometer. The influence of the type and amount of peroxide crosslinking agent on the mechanical properties, thermal stability, micromorphology and melt flowability was systematically investigated. The results showed that the mechanical properties of the TPVs vulcanized by 2,5-dimethyl-2,5-di (tert-butyl peroxy) hexane (DBPH) first increased and then decreased with increasing the peroxide amount, while for dicumyl peroxide (DCP) vulcanizing system the mechanical properties slowly increased. Besides, the comprehensive mechanical properties vulcanized by DBPH were better than those of DCP group. The results of the thermogravimetric analysis showed that the TPVs vulcanized by DBPH had better heat stability, corresponding to the excellent thermo-oxidative aging performance and the 38% increase in tensile strength after aging. In addition, the MVQ rubber particles showed better dispersing performance for DBPH vulcanizing system. The melt flow rate of the TPVs showed a linear relationship with increasing DBPH dosage and became worse after the amount of crosslinking agent exceeded 1.5 phr. By comprehensive comparison, the TPVs have better performance when use peroxide DBPH as the crosslinking agent and the dosage is 1.5 phr.     

Effects of the molecular structure from pitch fractions on the properties of pitch-based electrospun nanofibers

Mesophase pitch was separated into different pitch fractions to investigate the effect of pitch fractions on the properties of their nanofibers prepared by electrospinning. The evolution of different pitch fractions-derived nanofibers during stabilization and carbonization were explored, and the properties of the resultant carbon nanofibers (CNFs) as electrode materials for supercapacitor were compared. Results indicated that the hexane insoluble-toluene soluble (HI-TS) and toluene insoluble-tetrahydrofuran (THF) soluble (TI-THFS) fractions had good spinnability due to their narrow molecular weight distribution. Moreover, compared with HI-TS and THF insoluble (THFI), TI-THFS consisted of appropriate aromaticity and branched alkyl groups which promoted the stabilization and carbonization behaviors of its nanofibers, resulting in maintaining ideal fiber morphology of TI-THFS-derived nanofiber due to the mitigation of their exothermic reactions. Meanwhile, the TI-THFS-derived CNFs presented the highest surface area of 543 m² g⁻¹ and exhibited an excellent specific capacitance of 167 F g⁻¹ at 0.5 A g⁻¹ in 6 M KOH electrolyte.     

利用转子动能的风机辅助频率控制最优策略

风机增加辅助频率控制模块是解决新能源取代同步机导致的电力系统频率安全问题的一种方案,其中利用转子动能的调频模式可以使风机运行在最大功率点,经济性比功率备用模式更好。已有研究主要让风机通过虚拟惯量和频率下垂控制模拟同步机,却未充分利用风机控制灵活、可塑性强的优点,且未考虑风机转子动能限制及系统频率二次跌落。论文跳出虚拟惯量加频率下垂控制的传统框架,提出利用转子动能的风机辅助频率控制最优策略。首先将风机输出功率曲线作为决策变量,通过优化得到最优功率曲线,然后设计对应的辅助频率控制策略,实现最优输出功率曲线。仿真结果验证所提策略的效果,并说明风机辅助频率控制不应局限于模拟同步机,而是有更优的策略。     

直流变换器的电流控制性能对比与数字实现

基于DSP数字控制的DC/DC变换器,其电流环路的控制一般采用平均电流模式.峰值电流控制一般由模拟芯片实现,且存在稳定问题,需要设计斜坡补偿电路.此处以Buck变换器为例,对两种电流控制进行小信号建模,并仿真对比了动态和稳态性能,结果表明峰值电流控制具有更快的动态响应速度;为了追求高动态性能,利用DSP特有的AD比较功能实现了峰值电流的数字控制,并提出和分析了一种数字斜坡补偿方法,研制的500 W样机实验验证了所提方法的正确性和有效性.