Bonding in cotton fiber from formaldehyde-free crosslinks

Cotton fabric was crosslinked with five agents, three of which were prepared form formaldehyde and two of which were formaldehyde-free. The formaldehyde-free agents produced less bonding between layers in the laminated microstructure of the cotton fiber. One agent, 4,5-dihydroxy-1,3-dimethyl-2-imidazolidinone, gave no evidence of any interlayer bonding. All five agents gave the same relationship between wrinkle recovery angle and molar substitution on the cotton up to moderate recovery angles, but only agents based on formaldehyde gave higher wrinkle recovery angles with additional reaction. Intralayer crosslinking did not reduce absorptivity, as shown by moisture regain and dye receptivity, but did restrict swelling in cupriethylenediamine hydroxide to the same extent as combined interlayer and intralayer crosslinking. The decrease in extensibility of treated fabric with increasing wrinkle recovery angle was the same with all agents. These results indicate the regions of the fiber that are important for each of these properties.     

New natural 2-acetoxy fatty acids using chemical ionization and electron impact mass spectrometry

The phospholipids of the spongePolymastia gleneni contain saturated long chain (C_22–30)-acetoxy fatty acids. Their structures were assigned based on chromatographic and spectrometric data as well as comparison with a synthetic sample. The use of capillary gas chromatography combined with chemical ionization and electron impact mass spectrometry was instrumental in the eludication of structures, since only a very small amount of crude lipids was available. Part 10 of “Phospholipids in Marine Organisms.” For Part 9 in this series, see reference 12.     

Generalisations of Heyman's and Foulkes' theorems using dual formulation

Existing duality principles in structural optimisation are briefly reviewed and then they are extended to structures with segment-wise constant cross-sections. All theories are discussed in the particular context of optimal plastic beam design with symmetric convex specific cost functions and are confirmed by independent calculations on illustrative examples. It is shown that the optimal solution is always associated with a displacement field in which the mean absolute curvature value for each segment equals the subgradient of the specific cost function, with respect to the maximum absolute moment value for that segment. Moreover, the dual problem consists of the maximisation of the difference of two terms: the first one is the integral of the product of load and deflection (external work), and the second is the sum of products of segment lengths and the mean complementary cost values (taken with respect to the mean absolute curvature for that segment). Finally, some tentative proposals for a class of non-convex optimisation problems are presented. For special cases, the proposed general statements reduce to theorems by Heyman, Foulkes and Hemp.     

Laboratory accreditation in the UK

Two complementary national laboratory accreditation schemes are run by the National Physical Laboratory (NPL) to provide official recognition of competent British laboratories and an assurance of quality to their customers. The first of these, the British Calibration Service (BCS), was set up in 1966 to accredit laboratories to calibrate instruments, gauges and reference materials. In 1981 the National Testing Laboratory Accreditation Scheme (NATLAS) was formed to extend the service to all kinds of testing. Both BCS and NATLAS form an integral part of the UK national measurement system and were combined to form the National Measurement Accreditation Service on 1 October 1985.     

Combining multiple knowledge bases

Combining knowledge present in multiple knowledge base systems into a single knowledge base is discussed. A knowledge based system can be considered an extension of a deductive database in that it permits function symbols as part of the theory. Alternative knowledge bases that deal with the same subject matter are considered. The authors define the concept of combining knowledge present in a set of knowledge bases and present algorithms to maximally combine them so that the combination is consistent with respect to the integrity constraints associated with the knowledge bases. For this, the authors define the concept of maximality and prove that the algorithms presented combine the knowledge bases to generate a maximal theory. The authors also discuss the relationships between combining multiple knowledge bases and the view update problem     

Finite-element grid improvement by minimization of stiffness matrix trace

A new and simple method of finite-element grid improvement is presented. The objective is to improve the accuracy of the analysis. The procedure is based on a minimization of the trace of the stiffness matrix. For a broad class of problems this minimization is seen to be equivalent to minimizing the potential energy. The method is illustrated with the classical tapered bar problem examined earlier by Prager and Masur. Identical results are obtained.     

Resonant neutron filters in elemental analysis and radiography

Translated from Atomnaya Énergiya, Vol. 67, No. 4, pp. 271–274, October, 1989.     

A mixed finite element model for the elastic contact problem

The static elastic contact problem is approached using Lagrange multipliers, leading to a mixed finite element problem. A non-linear friction law is introduced explicitly and the non-local character of the friction phenomena is implicitly assumed. In order to avoid stress oscillations near singular points, a perturbed Lagrangian functional is considered. The algorithms herein proposed do not impose nodal dependencies over the contact surfaces, allowing for the independent discretization of both bodies. The method is able to model simultaneous contact over different regions of any geometrical shape. Computer code, examples and results presented here are restricted to axisymmetrical and bidimensional cases.