全文获取类型
收费全文 | 247592篇 |
免费 | 27334篇 |
国内免费 | 17402篇 |
专业分类
电工技术 | 21180篇 |
技术理论 | 4篇 |
综合类 | 23092篇 |
化学工业 | 32989篇 |
金属工艺 | 15656篇 |
机械仪表 | 17187篇 |
建筑科学 | 20417篇 |
矿业工程 | 8789篇 |
能源动力 | 7209篇 |
轻工业 | 22502篇 |
水利工程 | 6956篇 |
石油天然气 | 10967篇 |
武器工业 | 3109篇 |
无线电 | 28987篇 |
一般工业技术 | 23523篇 |
冶金工业 | 9873篇 |
原子能技术 | 3335篇 |
自动化技术 | 36553篇 |
出版年
2024年 | 1351篇 |
2023年 | 4024篇 |
2022年 | 8529篇 |
2021年 | 11434篇 |
2020年 | 8476篇 |
2019年 | 6333篇 |
2018年 | 7006篇 |
2017年 | 8295篇 |
2016年 | 7220篇 |
2015年 | 11104篇 |
2014年 | 13955篇 |
2013年 | 16492篇 |
2012年 | 19801篇 |
2011年 | 20594篇 |
2010年 | 19234篇 |
2009年 | 18410篇 |
2008年 | 18611篇 |
2007年 | 17801篇 |
2006年 | 15688篇 |
2005年 | 12442篇 |
2004年 | 8822篇 |
2003年 | 6943篇 |
2002年 | 6718篇 |
2001年 | 5969篇 |
2000年 | 4652篇 |
1999年 | 3027篇 |
1998年 | 1740篇 |
1997年 | 1443篇 |
1996年 | 1302篇 |
1995年 | 1120篇 |
1994年 | 916篇 |
1993年 | 591篇 |
1992年 | 478篇 |
1991年 | 345篇 |
1990年 | 285篇 |
1989年 | 256篇 |
1988年 | 180篇 |
1987年 | 125篇 |
1986年 | 113篇 |
1985年 | 52篇 |
1984年 | 44篇 |
1983年 | 37篇 |
1982年 | 37篇 |
1981年 | 58篇 |
1980年 | 80篇 |
1979年 | 36篇 |
1977年 | 9篇 |
1976年 | 10篇 |
1959年 | 18篇 |
1951年 | 32篇 |
排序方式: 共有10000条查询结果,搜索用时 265 毫秒
71.
Wei Lai Lihong Ge Huaming Li Yilin Deng Bin Xu Bo Ouyang Erjun Kan 《International Journal of Hydrogen Energy》2021,46(53):26861-26872
The electrochemical water splitting to produce H2 in high efficiency with earth-abundant-metal catalysts remains a challenge. Here, we describe a simple “cyclic voltammetry + ageing” protocol at room temperature to activate Ni electrode (AC-Ni/NF) for hydrogen evolution reaction (HER), by which Ni/Ni(OH)2 heterostructure is formed at the surface. In situ Raman spectroscopy reveals the gradual growth of Ni/Ni(OH)2 heterostructure during the first 30 min of the aging treatment and combined with polarization measurements, it suggests a positive relation between the Ni/Ni(OH)2 amount and HER performance of the electrode. The obtained AC-Ni/NF catalyst, with plentiful Ni–Ni(OH)2 interfaces, exhibits remarkable performance towards HER, with the low overpotential of only 30 mV at a H2-evolving current density of 10 mA/cm2 and 153 mV at 100 mA/cm2, as well as a small Tafel slope of 46.8 mV/dec in 1 M KOH electrolyte at ambient temperature. The excellent HER performance of the AC-Ni/NF could be maintained for at least 24 h without obvious decay. Ex situ experiments and in situ electrochemical-Raman spectroscopy along with density functional theory (DFT) calculations reveal that Ni/Ni(OH)2 heterostructure, although partially reduced, can still persist during HER catalysis and it is the Ni–Ni(OH)2 interface reducing the energy barrier of H1 adsorption thus promoting the HER performance. 相似文献
72.
73.
Among various carbon materials, diamond stands out due to excellent physical and chemical properties. In this work, we designed Dia@SiO2@Ag composites combining diamond micropowder and Ag nanoparticles by a simple chemical method and obtained stable substrate for surface enhanced Raman scattering (SERS) owing to its high surface-to-volume ratio, low density, as well as close bond between diamond and Ag. As-prepared Dia@SiO2@Ag presented high activity to detect crystal violet and rhodamine 6G molecules, which was demonstrated by significantly enhanced SERS spectra and high enhancement factor values (108-109). Moreover, Dia@SiO2@Ag also showed desired sensitivity, which was investigated by detection limit. Therefore, our study provided more theoretical support and broadened the functional applications of diamond, particularly in Raman detection. 相似文献
74.
Xiao-Ya Shangguan Bao-Lun Fang Chen-Xiao Xu Yuan Tan Yan-Gang Chen Zhi-Jun Xia Wei Chen 《Ceramics International》2021,47(5):6318-6328
A series of direct Z-scheme FeIn2S4/Bi2WO6 hierarchical heterostructures with intimate interface contacts were synthesized by in-situ growth route and characterized by systematical analyses. All as-prepared FeIn2S4/Bi2WO6 nanocomposites showed significantly enhanced photocatalytic activity towards photodegradation for the removal of tetracycline hydrochloride (TCH) in comparison with individual FeIn2S4 and Bi2WO6. Meanwhile, the highest photocatalytic degradation activity can be achieved by modulating adding amount of FeIn2S4 in FeIn2S4/Bi2WO6 nanocomposites and the optimized component ratio of FeIn2S4 to Bi2WO6 is determined to be 10 wt%. The enhanced photocatalytic activity could be ascribed to efficient separation between photogenerated holes and electrons based on the construction of direct Z-scheme system. The high photocatalytic stability of resultant 10 wt% FeIn2S4/Bi2WO6 nanocomposites was revealed through six successive recycling reactions. The main intermediate generated during TCH photodegradation was explored by HPLC-MS. Besides, the direct Z-scheme photocatalytic mechanism was confirmed by band position analysis, electron spin resonance (ESR) and active species capture experiment. 相似文献
75.
76.
在现有的时间银行系统中,时间币的发行功能和结算功能完全集中到一个中心节点上。这种极度中心化的功能结构,不仅存在容易发生中心节点单点失效、数据容易被篡改等信息安全问题,还存在着时间币的发行和流通缺乏透明度以及时间币的结算依赖中心化的结算机构等问题。针对这些问题,提出了一种基于区块链技术的解决方法。首先,将时间币的发行功能和结算功能从中心节点上分离出来;然后,利用具有分布式去中心化、集体维护和不可篡改等特性的区块链技术,将分离出来的发行功能逐步去中心化,将分离出来的结算功能去中心化,形成公益时间链(PWTB);最终,PWTB利用区块链技术以去中心化的方式将时间银行系统由单个节点维护账本变成由集体维护一个分布式的共享账本,使时间币的发行和流通公开透明,时间币的结算不依赖某个中心化的节点。安全分析表明所设计的PWTB能够实现安全的信息传输与存储,以及数据的共享。 相似文献
77.
针对基于容积脉搏波(PPG)提取运动心率时,传统心率提取算法由于运动噪声干扰使测量结果误差大、实时性不好的问题,提出一种抗运动干扰的实时心率提取方法。该方法通过实时小波去噪,同时结合三轴加速度信号(ACC)对运动进行分类训练,计算各运动状态心率增益,对实时心率值进行补偿。实验结果表明,通过与同时采集的ECG信号计算出的实时心率进行对比,绝对误差率仅为1.2%左右。相比传统心率提取算法,该算法具有抗干扰性强,实时准确的特点。 相似文献
78.
以转基因水稻中最常用的CaMV35S启动子、NOS终止子、Cry1Ab/Ac基因、HPT基因及SPS水稻内标基因为研究对象,利用5 种不同的荧光信号(FAM、HEX、Taxas Red、Cy5、Cy5.5)进行多重实时聚合酶链式反应(real-time polymerase chain reaction,real-time PCR)检测方法的研究。通过引物组合筛选、反应体系优化、特异性测试、灵敏度测试、适用性测试等一系列实验,建立了5 重real-time PCR方法,灵敏度可达0.032%。此方法具有灵敏度高、结果准确、通量大等优点,可实现水稻中转基因成分的快速、高效检测。 相似文献
79.
连续多跨的二层无粘结预应力混凝土框架结构按照改造需要拆成单跨框架结构,且增加一层。某一方向的预应力钢筋将全部切断。通过对多种改造加固方案的比选,最终确定了无粘结预应力钢绞线应力释放和重张拉法。通过与专业施工单位的共同配合,顺利完成了该工程预应力拆除改造关键技术,施工监测表明,通过施工监测表明整个拆改过程变形合理可控。本项目取得了较好的经济效应,且是改造项目中的绿色工程。 相似文献
80.
Wang Hay Kan Chenxi Wei Dongchang Chen Tao Bo Bao‐Tian Wang Yan Zhang Yangchao Tian Jun‐Sik Lee Yijin Liu Guoying Chen 《Advanced functional materials》2019,29(17)
Lithium‐rich disordered rock‐salt oxides have attracted great interest owing to their promising performance as Li‐ion battery cathodes. While experimental and theoretical efforts are critical in advancing this class of materials, a fundamental understanding of key property changes upon Li extraction is largely missing. In the present study, single‐crystal synthesis of a new disordered rock‐salt cathode material, Li1.3Ta0.3Mn0.4O2 (LTMO), and its use as a model compound to investigate Li concentration–driven evolution of local cationic ordering, charge compensation, and chemical distribution are reported. Through the combined use of 2D and 3D X‐ray nanotomography, it is shown that Li removal accompanied by oxygen oxidation is correlated with the development of morphological defects such as particle cracking. Chemical heterogeneity, quantified by subparticle level distribution of Mn valence state, is minimal during Mn redox, which drastically increases upon the formation of cracks during oxygen redox. Density functional theory and bond valence sum mismatch calculations reveal the presence of local short‐range ordering in the pristine oxide, which gradually disappears along with the extraction of Li. The study suggests that with cycling the transformation into true cation–disordered state can be expected, which likely impacts the voltage profile and obtainable energy density of the oxide cathodes. 相似文献