GRAPHICAL SOLUTION OF MULTISTAGE FLUIDIZED BED HEAT EXCHANGER

The design of multistage fluidized beds for heat exchange necessitates the solution of the mass and energy balance equations combined with the equilibrium relations for each stage. This paper presents a novel way of applying well known methodology to a different technology, one where it has not been widely applied.

In the present work a McCabe-Thiele type of graphical approach is presented for both counter-current and cross-current contacting multiple fluidized beds. The necessary equations for a multistage calciner are developed and the application of the proposed method is demonstrated. Generalized fluidized bed efficiency for counter-current and cross-current multiple fluidized bed is presented.     

A PROCEDURE FOR EVALUATION OF COMMERCIAL FCC CATALYSTS

Based on the correlations between laboratory units and commercial plants, a procedure has been developed to guide commercial FCC (Fluid Catalytic Cracking) catalysts selection. Examining the operability of catalyst mixtures during catalyst transition period is emphasized. The testing procedure is simple and reliable. A commercially available catalyst and the catalyst currently in use have been compared to demonstrate the applicability of this procedure. The commercial testing has confirmed the reliability of laboratory results. The use of the catalyst evaluated led to a 30% saving in catalyst cost.     

Tissue culture of cocoa bean (Theobroma cacao L.): changes in lipids during maturation of beans and growth of cells and calli in culture

Callus cultures ofTheobroma cacao L., initiated from explants of immature cocoa bean cotyledons, contained 5.3%–6.4% lipids (dry wt basis). The major fatty acids were palmitic, oleic and linoleic acids. Cell suspensions contained 5.7–7.7% total lipids which had a higher polyunsaturated fatty acid content than total lipids of the calli. Phospholipids and glycolipids were the predominant lipid classes of calli and cell suspensions. Immature cocoa beans at early stages of development contained much higher polyunsaturated fatty acids, higher polar lipids and lower triglycerides than did mature ripe beans. Ripe cocoa beans contained 54% total lipids of which 96.8% where triglycerides. The fatty acid composition of total lipids of calli and cell suspensions were similar to those of the immature cocoa beans.     

多孔氧枪喷头轴线上速度分布特征的研究

本文基于湍流时流理论，对多孔氧格喷头几何轴线上的速度分布特征进行了理论和实验研究．结果表明，多孔氧论喷头轴线上速度最大值的临界枪位可由下式计算并由大型喷头的实测结果得到了验证     

Laser glazing of plasma-sprayed zirconia coatings

A CO₂ laser with cylindrical focal lens has been used to glaze the surface layer of plasma-sprayed ZrO₂-20wt% Y₂O₃/MCrAlY coatings. Both a continuous-wave laser and a pulsed laser were used in this study. Different parameter settings for power, travel speed, and pulse frequency were used, and their effects on the melting width, melting depth, coupling efficiency, microstructure, surface roughness, and process defects have been evaluated. Results show that the melting width of the glazed track was slightly smaller than the diameter of the raw beam. The melting depth increased with increasing energy density for both a continuous-wave laser and a pulsed laser. The coupling efficiency as about 40 to 65% for a continuous-wave laser, which increased with increasing laser travel speed, but decreased with an increase in energy density. The power density has no significant effect on coupling efficiency. Defects, such as bubbles or depressions, occur easily with a continuous wave laser. A high-quality glazed layer is successfully produced using a pulsed laser. The surface roughness of the plasma-sprayed ceramic coatings was significantly improved by laser glazing. Surface roughness decreased slightly as the pulse frequency increased for the glazed surface. Based on this study, proper processing parameters have been suggested.     

Effect of restrictive diffusion on hydrodesulfurization of heavy residue oils over CoMo/Al2O3

The effect of the ratio of reactant molecular diameter to catalyst pore diameter (λ) on the restrictive diffusion under hydrodesulfurization (HDS) reactions of heavy residue oils over CoMo/Al₂O₃ catalysts was investigated. A series of Al₂O₃ with various pore structures were used as supports of CoMo sulfide. The HDS reaction was carried out in a semi-batch Carberry type reactor at 648 K and 10.3 MPa. Two empirical correlations for restrictive diffusion under HDS reaction conditions were developed depending on the value of λ. The results showed that the restrictive diffusion effect under HDS reaction conditions is severe for the lower values of λ. However, this effect seems not prominent for higher values of λ. The order of the magnitude of the effective diffusivity was in the range of 10^?6-10^?7 cm²/s for the sulfur-containing compounds of residue oil in CoMo/Al₂O₃ catalysts at 648 K.     

On the examination of recycle on heat (and mass) transfer in concentric tubes

The effect of recycle on heat (and mass) transfer in concentric circular tubes has been investigated by finite difference methods. Theoretical results show that recycle can enhance the heat transfer rate for large Graetz numbers compared with that in an open tube (without an inner tube inserted and without recycle). Competition between a preheating effect and a residence-time effect can be used to explain the heat transfer behavior. The heat transfer rate can be further augmented, with nearly no increase in total pressure drop, by employing flow pattern B instead of flow pattern A.     

Determination of the long term corrosion behavior of coated steel with A.C. impedance measurements

A previous study of the a.c. impedance of thin polymer films on aluminum alloys, steel, and phosphated steel, determined over a wide frequency range, has resulted in a general model for the electrochemical impedance across the coated surfaces. According to this model, penetration of the coating by the electrolyte results in an impedance behavior which is typical of a dielectric film short-circuited by conducting electrolytic paths perpendicular and parallel to the polymer/metal interface. Comparison of the time dependence of the impedance of coated steel substrates with the impedance across a free film has demonstrated that the corrosion of the substrate enhances the development of parallel paths of ionic conduction in the coating. A.c. impedance measurements carried out on polybutadiene-coated steels pretreated by different procedures determine quantitatively the resistance R_p of the conducting paths. The time dependence of R_p for the coated substrates has been determined for exposure periods of up to three weeks. Visual observation of the corroded and delaminated areas according to ASTM D610 has been carried out simultaneously, and correlations have been established with R_p. The results are discussed in terms of the possibility to predict the corrosion behavior of a coated metal, based on the measurement of R_p.     

Using fast reactor component evaluation for pressurized water reactor life extension

An understanding of the effects of long-term, low-dose-rate radiation on core components is critical to light-water reactor plant life extension. Following reactor shutdown, materials that had experienced long exposures to low-dose-rate irradiation were retrieved from the EBR-II research reactor for analysis. These components are being analyzed to provide insight into pressurized water reactor life extension. In this work, three examples of EBR-II materials analyses are highlighted: radiation-induced segregation in 304 stainless steel, stress relaxation in Inconel X750, and swelling in 316 stainless steel. For more information, contact T.R. Allen, Argonne National Laboratory-West, P.O. Box 2528, Idaho Falls, Idaho 83403-2528;(208)533-7760; fax (208) 533-7863; e-mail todd.allen@anlw.anl.gov.