Catalytic characteristics of MnO2 nanostructures for the O2 reduction process

Nanorods with an α type MnO(2) structure and a diameter ranging from 25 to 40 nm, along with tipped needles with a β MnO(2) structure and a diameter of 100 nm were obtained. The 25 nm diameter α MnO(2) nanorods showed the best catalytic activity for dissociation of HO(2)(-) formed during oxygen reduction in a KOH solution. The MnO(2) nanostructures preferably followed a two-electron oxygen reduction mechanism in a LiOH solution. The size of the catalyst also affected the specific capacities of the non-aqueous Li/O(2) batteries fabricated using the MnO(2) based air electrode. The highest specific capacity of 1917 mA h g(-1) was obtained for an α MnO(2) nanorod catalyst having a diameter of 25 nm. The cation present in the MnO(2) nanostructures appears to determine the catalytic activity of MnO(2).     

Control of domain wall pinning in ferromagnetic nanowires by magnetic stray fields

We have found that the depinning field of domain walls (DWs) in permalloy (Ni(81)Fe(19)) nanowires can be experimentally controlled by interactions between magnetic stray fields and artificial constrictions. A pinning geometry that consists of a notch and a nanobar is considered, where a DW traveling in the nanowire is pinned by the notch with a nanobar vertical to it. We have found that the direction of magnetization of the nanobar affects the shape and local energy minimum of the potential landscape experienced by the DW; therefore, the pinning strength strongly depends on the interaction of the magnetic stray field from the nanobar with the external pinning force of the notch. The mechanism of this pinning behavior is applied for the instant and flexible control of the pinning strength with respect to various DW motions in DW-mediated magnetic memory devices.     

The economic impact of strengthening fuel quality regulation—reducing sulfur content in diesel fuel

This paper investigates the impact of strengthening vehicle emission regulation on economic activities. The government attempts to use three regulation measures to protect air quality from transportation emission. The measures include the aggregate limit (bubbles), the vehicle emission standard, and the fuel quality standard. Especially, we focus on the economic impact of reducing sulfur content in diesel fuel quality standard. Sulfur content in diesel fuel is one of the main factors in worsening local air quality. The emission from diesel vehicle accounts for 51.8% of total vehicle emission in Korea. If sulfur content reduction regulation is implemented, then the petroleum industry should build more facility to produce low sulfur content diesel, leading to additional production costs and increasing prices and decreasing outputs. We use computable general equilibrium model to analyze how the sulfur reduction regulation affects economic activities and trace out local emission reduction cost and GDP loss. And we suggest the tax-recycling mechanism to mitigate the negative economic costs due to the sulfur reduction regulation.     

Performance of amplify-and-forward cooperative networks with differential unitary space time coding

In wireless communications, multi-input multi-output technology has been appreciated for its high transmission rate and diversity gain. These can also be exploited in cooperative networks by using network nodes as virtual antenna arrays. In this paper, we analyze the performance of cooperative networks with differential unitary space-time modulation under high signal-to-noise ratio. Relaying protocol is based on amplify-and-forward. The effect of relay location and energy allocation as well as the comparison with a conventional cooperative network is also addressed.     

Sub‐Nanometer Level Size Tuning of a Monodisperse Nanoparticle Array Via Block Copolymer Lithography

The fabrication and catalytic application of a size‐tunable monodisperse nanoparticle array enabled by block copolymer lithography is demonstrated. Highly uniform vertical cylinder nanodomains are achieved in poly(styrene‐block‐4‐vinylpyridine) (PS‐b‐P4VP) diblock copolymer thin‐films by solvent annealing. The prominent diffusion of the anionic metal complexes into the protonated P4VP cylinder nanodomains occurs through specific electrostatic interactions in a weakly acidic aqueous solution. This well‐defined diffusion with nanoscale confinement enables preparation of the laterally ordered monodisperse nanoparticle array with sub‐nanometer level precise size tuning. The controlled growth of monodisperse nanoparticle arrays is proven by their catalytic use for vertical carbon nanotube (CNT) growth via plasma enhanced chemical vapor deposition (PECVD). Since the size of the catalyst particles is the decisive parameter for the diameters and wall‐numbers of CNTs, the highly selective growth of double‐walled or triple‐walled CNTs could be accomplished using monodisperse nanoparticle arrays.     

Poly(diketopyrrolopyrrole‐benzothiadiazole) with Ambipolarity Approaching 100% Equivalency

As a characteristic feature of conventional conjugated polymers, it has been generally agreed that conjugated polymers exhibit either high hole transport property (p‐type) or high electron transport property (n‐type). Although ambipolar properties have been demonstrated from specially designed conjugated polymers, only a few examples have exhibited ambipolar transport properties under limited conditions. Furthermore, there is, as yet, no example with ‘equivalent’ hole and electron transport properties. We describe the realization of an equivalent ambipolar organic field‐effect transistor (FET) by using a single‐component visible–near infrared absorbing diketopyrrolopyrrole (DPP)‐benzothiadiazole (BTZ) copolymer, namely poly[3,6‐dithiene‐2‐yl‐2,5‐di(2‐decyltetradecyl)‐pyrrolo[3,4‐c]pyrrole‐1,4‐dione‐5’,5’’‐diyl‐alt‐benzo‐2,1, 3‐thiadiazol‐4,7‐diyl] ( PDTDPP‐alt‐BTZ ). PDTDPP‐alt‐BTZ shows not only ideally balanced charge carrier mobilities for both electrons (?_e = 0.09 cm²V^?1s^?1) and holes (?_h = 0.1 cm²V^?1s^?1) but also its inverter constructed with the combination of two identical ambipolar FETs exhibits a gain of ～35 that is much higher than usually obtained values for unipolar logic.     

Memory Access Optimized Implementation of Cyclic and Quasi-Cyclic LDPC Codes on a GPGPU

Software based decoding of low-density parity-check (LDPC) codes frequently takes very long time, thus the general purpose graphics processing units (GPGPUs) that support massively parallel processing can be very useful for speeding up the simulation. In LDPC decoding, the parity-check matrix H needs to be accessed at every node updating process, and the size of the matrix is often larger than that of GPU on-chip memory especially when the code length is long or the weight is high. In this work, the parity-check matrix of cyclic or quasi-cyclic (QC) LDPC codes is greatly compressed by exploiting the periodic property of the matrix. Also, vacant elements are eliminated from the sparse message arrays to utilize the coalesced access of global memory supported by GPGPUs. Regular projective geometry (PG) and irregular QC LDPC codes are used for sum-product algorithm based decoding with the GTX-285 NVIDIA graphics processing unit (GPU), and considerable speed-up results are obtained.     

Smooth, 3D Ge transistor channels by heteroepitaxial growth

Crystalline germanium (Ge) is a prime candidate as a material for high-performance transistors due to its higher electron and hole mobility with respect to those of silicon. In this study, we present a novel method of fabricating epitaxial Ge structures of high crystalline and morphological quality directly onto Si substrates, in which 3D Ge structures are grown by selective epitaxy then annealed in a hydrogen ambient at 850 °C. Under such annealing, the surface of the Ge structures deform by surface diffusion to form smooth, rounded shapes for which the surface energy is at a local minima. The apparent smoothness of the surface, along with the decreased defect density expected to exist in these heteroepitaxial Ge structures, suggest they are adequate for use as transistor channels.     

Thin-Film Thermoelectric Module for Power Generator Applications Using a Screen-Printing Method

A new process for fabricating a low-cost thermoelectric module using a screen-printing method has been developed. Thermoelectric properties of screen-printed ZnSb films were investigated in an effort to develop a thermoelectric module with low cost per watt. The screen-printed Zn _x Sb_1−x films showed a low carrier concentration and high Seebeck coefficient when x was in the range of 0.5 to 0.57 and the annealing temperature was kept below 550°C. When the annealing temperature was higher than 550°C, the carrier concentration of the Zn _x Sb_1−x films reached that of a metal, leading to a decrease of the Seebeck coefficient. In the present experiment, the optimized carrier concentration of screen-printed ZnSb was 7 × 10¹⁸/cm³. The output voltage and power density of the ZnSb film were 10 mV and 0.17 mW/cm², respectively, at ΔT = 50 K. A thermoelectric module was produced using the proposed screen-printing approach with ZnSb and CoSb₃ as p-type and n-type thermoelectric materials, respectively, and copper as the pad metal.     

Improving aptamer selection efficiency through volume dilution, magnetic concentration, and continuous washing in microfluidic channels

The generation of nucleic acid aptamers with high affinity typically entails a time-consuming, iterative process of binding, separation, and amplification. It would therefore be beneficial to develop an efficient selection strategy that can generate these high-quality aptamers rapidly, economically, and reproducibly. Toward this goal, we have developed a method that efficiently generates DNA aptamers with slow off-rates. This methodology, called VDC-MSELEX, pairs the volume dilution challenge process with microfluidic separation for magnetic bead-assisted aptamer selection. This method offers improved aptamer selection efficiencies through the application of highly stringent selection conditions: it retrieves a small number (<10(6)) of magnetic beads suspended in a large volume (>50 mL) and concentrates them into a microfluidic chamber (8 μL) with minimal loss for continuous washing. We performed three rounds of the VDC-MSELEX using streptavidin (SA) as the target and obtained new DNA aptamer sequences with low nanomolar affinity that specifically bind to the SA proteins.