C／C复合材料Mo-Si-N抗氧化涂层的制备

在C／C复合材料表面采用熔浆法制备Mo—Si系涂层的烧结过程中通入氮气，开发了Si3N4．MoSi2／Si—SiC（Mo-Si-N系）多层抗氧化涂层，并初步考察了涂层的抗氧化性能。结果表明，多层涂层的致密性主要受制于起始氮化温度。只有在Si熔点以上通入氮气，才能获得致密无缺陷的涂层。多层涂层的底层为SiC，外层为Si3N4，中间层为MoSi2／Si。这种多层涂层的抗氧化性能与涂层中MoSi2的含量有关；MoSi2含量为30％（体积分数，下同）和40％时，与真空中合成的Mo-Si涂层相比，高温抗氧化性能显著改善，抗氧化温度提高到1400℃～1450℃。     

Unsteady aerodynamic loads on high speed trains passing by each other

In order to study unsteady aerodynamic loads on high speed trains passing by each other 350km/h, three-dimensional flow fields around trains during the crossing event are numerically simulated using three-dimensional Euler equations. Roe’s FDS with MUSCL interpolation is employed to simulate wave phenomena. An efficient moving grid system based on domain decomposition techniques is developed to analyze the unsteady flow field induced by the restricted motion of a train on a rail. Numerical simulations of the strain passing by on the double-track are carried out to study the effect of the train nose-shape, length and the existence of a tunnel on the crossing event. Unsteady aerodynamic loads-a side force and a drag force-acting on the train during the crossing are numerically predicted and analyzed. The side force mainly depends on the nose-shape, and the drag force depends on tunnel existence. Also. a push-pull (i.e. impluse force) force successively acts on each car and acts in different directions between the neighborhood cars. The maximum change of the impulsive force reaches about 3 tons. These aerodynamic force data are absolutely necessary to evaluate the stability of high speed multi-car trains. The results also indicate the effectiveness of the present numerical method for simulating the unsteady flow fields induced by bodies in relative motion.     

Structural Displacement Measurement Using an Unmanned Aerial System

Vibration‐based Structural Health Monitoring (SHM) is one of the most popular solutions to assess the safety of civil infrastructure. SHM applications all begin with measuring the dynamic response of structures, but displacement measurement has been limited by the difficulty in requiring a fixed reference point, high cost, and/or low accuracy. Recently, researchers have conducted studies on vision‐based structural health monitoring, which provides noncontact and efficient measurement. However, these approaches have been limited to stationary cameras, which have the challenge of finding a location to deploy the cameras with appropriate line‐of‐sight, especially to monitor critical civil infrastructures such as bridges. The Unmanned Aerial System (UAS) can potentially overcome the limitation of finding optimal locations to deploy the camera, but existing vision‐based displacement measurement methods rely on the assumption that the camera is stationary. The displacements obtained by such methods will be a relative displacement of a structure to the camera motion, not an absolute displacement. Therefore, this article presents a framework to achieve absolute displacement of a structure from a video taken from an UAS using the following phased approach. First, a target‐free method is implemented to extract the relative structural displacement from the video. Next, the 6 degree‐of‐freedom camera motion (three translations and three rotations) is estimated by tracking the background feature points. Finally, the absolute structural displacement is recovered by combining the relative structural displacement and the camera motion. The performance of the proposed system has been validated in the laboratory using a commercial UAS. Displacement of a pinned‐connected railroad truss bridge in Rockford, IL subjected to revenue‐service traffic loading was reproduced on a hydraulic simulator, while the UAS was flown from a distance of 4.6 m (simulating the track clearance required by the Federal Railroad Administration), resulting in estimated displacements with an RMS error of 2.14 mm.     

A roll-to-roll microwave plasma chemical vapor deposition process for the production of 294 mm width graphene films at low temperature

Roll-to-roll microwave plasma chemical vapor deposition (CVD) has been used for the continuous deposition of graphene films for industrial mass production. Using surface wave plasma, a pair of roll-to-roll winder and unwinder system has been built into a CVD apparatus, which has a deposition area of 294 mm × 480 mm. A graphene film was deposited onto the Cu film with 294 mm width under CH₄/Ar/H₂ plasma below 400 °C. It was found from cross-sectional transmission electron microscopy that few layer graphene, had been produced which consists of flakes with a nanometer size. After transferring the film onto a polyethylene terephthalate film, a uniform graphene film with high optical transmittance was confirmed.     

Fast Concurrent Growth of Ni3Sn4 and Voids During Solid-State Reaction Between Sn-Rich Solder and Ni Substrates

To simulate the growth of Ni₃Sn₄ phase layers in Sn-based solder joints with Ni substrates during solid-state aging, Sn/(Cu_1−x Ni _x )₆Sn₅/Ni and Sn/Ni diffusion couples were aged isothermally at 180°C and 200°C, and the growth kinetics of the (Ni,Cu)₃Sn₄ and Ni₃Sn₄ layers in the respective couples were monitored during the isothermal aging. Once the (Ni,Cu)₃Sn₄ layer was formed at the (Cu,Ni)₆Sn₅/Ni interface, it grew unexpectedly fast with concurrent growth of voids formed in the Sn layer during prolonged aging at both temperatures. The results obtained from the various types of diffusion couples revealed that the voids formed in the Sn layer were Kirkendall voids, due to the (Ni,Cu)₃Sn₄ layer growing predominantly at the (Ni,Cu)₃Sn₄/Ni interface by fast diffusion of Sn across the (Ni,Cu)₃Sn₄ layer. It is proposed that the accelerated growth of the (Ni,Cu)₃Sn₄ and Ni₃Sn₄ layers after the formation of voids in the Sn layer is due to the relaxation of vacancy oversaturation and the enhanced annihilation rate of incoming vacancies in the presence of the voids in the Sn layer.     

All-Impurities Scavenging,Safe Separators with Functional Metal-Organic-Frameworks for High-Energy-Density Li-Ion Battery

Li-ion batteries (LIBs) have wide applications owing to their high-energy density and stable cycle characteristics. Nevertheless, with the rapid expansion of electric vehicle market, issues such as explosion of LIBs and the need to secure a longer driving distance have emerged. In this work, functional metal–organic frameworks (MOFs) are introduced as a separator in LIBs, in which a highly heat-resistant polymer separator is fabricated through electrospinning. The MOFs can scavenge impurities (including gas, water, and hydrofluoric acid) that positively affect battery performance and safety. The multi-functional separator suppresses salt decomposition when a nickel-rich cathode is operated at high voltage and high temperature through it. This delays the deterioration of the cathode interface and results in a superb cycle stability with 75% retention even in the presence of 500 ppm of water in the electrolytes. In addition, the pouch cell is manufactured by enlarging the separator, and the degree of electrode swelling due to gas generation and interface degradation in the pouch state is alleviated to 50% or less. These findings highlight the necessity of scavenging impurities to maintain excellent performance and provides the development direction of functional separators in LIBs.     

Engineered Lipid Nanoparticles for the Treatment of Pulmonary Fibrosis by Regulating Epithelial-Mesenchymal Transition in the Lungs

Pulmonary fibrosis is a chronic and irreversible lung disease with limited therapeutic regimens. Advances in elucidating the pathophysiological mechanism and discovering novel therapeutic interventions are still in urgent need. Here, the engineered lipid nanoparticles (LNPs) are developed for delivering RNA therapeutics to the lungs. Three different types of LNPs (native, cationic, and ligand incorporated) are optimized to facilitate the pulmonary delivery of RNAs. Among them, the mannose incorporated LNPs (Mannose LNPs) outperform the others and show efficient delivery of siRNAs down-regulating the epithelial-mesenchymal transition (EMT) associated protein, G2 and S phase-expressed protein 1 (GTSE1). Treatment with the mannose LNPs confirms a significant decrease in collagen accumulation and EMT-related proteins in the fibrosis animal models and provides functional recovery from pulmonary fibrosis. This approach demonstrates that engineered LNPs can facilitate the delivery of RNA therapeutics to the lungs and potentially open a new regimen of treatment for pulmonary fibrosis.