Synthesis and material and electronic properties of conjugated polymers

Conjugated polymers such as polyacetylene are semiconductors, and can be chemically doped to give very high values of conductivity (up to 150 000 S cm^–1). The semiconducting properties are due to delocalization of the electron system formed along the polymer chain, and this general class of materials shows many desirable semiconductor properties for electrical and optical applications. There are considerable challenges to find synthetic routes to allow processing of the polymer to the forms required for applications, and many of the recent important advances in the field are due to improvements in this area.     

Investigation of long term drift of an intraocular pressure sensor

Microsystem Technologies - “Zero drift” behavior of an optical intraocular pressure sensor is studied using an analytical model based on the deflection of a circular membrane. Results...     

Positive state‐bounding observer for positive interval continuous‐time systems with time delay

This paper is concerned with the problem of positive observer synthesis for positive systems with both interval parameter uncertainties and time delay. Conventional observers may no longer be applicable for such kind of systems due to the positivity constraint on the observers, and they only provide an estimate of the system state in an asymptotic way. A pair of positive observers with state‐bounding feature is proposed to estimate the state of positive systems at all times in this paper. A necessary and sufficient condition for the existence of desired observers is first established, and the observer matrices can be obtained easily through the solutions of a set of linear matrix inequalities (LMIs). Then, to reduce the error signal between the system state and its estimates, an iterative LMI algorithm is developed to compute the optimized state‐bounding observer matrices. Finally, a numerical example is presented to show the effectiveness and applicability of the theoretical results. Copyright © 2011 John Wiley & Sons, Ltd.     

Computer simulations of time-dependent suppression of EOF by polymer coatings

We use molecular dynamics simulations in order to investigate the time evolution of the effect of adsorbed polymer coatings on the electro-osmotic flow (EOF) in a capillary. Weakly adsorbed coatings show no time-dependent performance, but they do not strongly reduce the EOF. On the other hand, strongly adsorbed coatings made of longer polymer chains are often quenched in non-equilibrium conformations that can strongly reduce the EOF over extremely long periods of time. For intermediate adsorption strengths, we observe that the EOF increases as a function of time due to the relaxation of the coating layer. The concentration of polymers in solution and the length of the polymer chains also affect the time-dependence of the EOF. These results show that the quality of electrophoretic separations can depend on the waiting time between the formation of the coating and the beginning of the separation. We conclude by suggesting experimental tests of our predictions.     

Design optimization of supersonic jet pumps using high fidelity flow analysis

Supersonic jet pumps are simple devices with no moving parts, where a high velocity (primary) flow is used to pump a second fluid. In this paper, Computational Fluid Dynamics (CFD) is combined with an optimization framework in order to develop a tool for the rapid generation of jet pump designs. A key feature of the problem formulation is the transformation of the jet pump design parameters in terms of geometric ratios. This approach dramatically reduces the number of unrealistic designs covered by the Design of Experiments. Optimal Latin Hypercubes for surrogate model building and model validation points are constructed using a permutation genetic algorithm and design points are evaluated using CFD. Surrogate models of primary and entrained flow rates are built using a Moving Least Squares approach. A series of optimizations for various pump sizes are performed using a genetic algorithm and Sequential Quadratic Programming, with responses calculated from the surrogates. This approach results in a set of optimized designs, from which pumps for a wide range of flow rates can be interpolated.     

Synthesis of aromatic polyethers by Scholl reaction

This paper describes the synthesis and cation-radical polymerization of 1,5-bis(1-naphthoxy)-3-oxapentane. This monomer contains a flexible diethylene oxide unit between two 1-naphthalene rings. The FT-IR analysis of the resulted polymer indicates that it contains 1,4-disubstituted naphthalene structural units, i.e. 4,4-disubstituted-1,1-binaphthalene units. The polymer is crystalline with a melting point of 236 °C.Part IX: V. Percec and J. H. Wang: J. Mater. Chem., in press     

Where does the end begin? Problems in musico-cognitive modeling

Research with computer systems and musical grammars into improvisation as found in the tabla drumming system of North India has indicated that certain musical sentences comprise (a) variable prefixes, and (b) fixed suffixes (or cadences) identical with those of their original rhythmic themes. It was assumed that the cadence functioned as a kind of target in linear musical space, and yet experiments showed that defining what exactly constituted the cadence was problematic. This paper addresses the problem of the status of cadential patterns, and demonstrates the need for a better understanding and formalization of ambiguity in musico-cognitive processing. It would appear from the discussion that the cadence is not a discrete unit in itself, but just part of an ever-present underlying framework comprising the entire original rhythmic theme. Improvisations (variations), it is suggested, merely break away from and rejoin this framework at important structural points. This endorses the theory of simultaneity. However, the general cognitive implications are still unclear, and further research is required to explore musical ambiguity and the interaction of musical, linguistic, and spatio-motor grammars.     

The quantifier structure of sentences that characterize nondeterministic time complexity

For every nondeterministic Turing machineM of time complexityT(n), there is a second-order sentence of a very restricted form, whose set of finite models encodes the set of strings recognized byM. Specifically, has a relational symbol which is interpreted as addition restricted to finite segments of the natural numbers, and a prefix consisting of existentially quantified unary second-order variables followed by a universal-existential first-order part. Here, every input stringx is encoded by a model of sizeT(|x|). Using a closely related encoding of strings as models where the size of the model is the length of the string, a consequence is that ifT(n)=n ^d, then there is a sentence with a similar prefix but whose second-order variables ared-ary and whose finite models encode the strings accepted byM. Potential applications to low-level complexity are discussed.     

Curing characteristics of a composite matrix

The account describes investigations into the variations of specific volume and viscosity of a typical high-performance epoxy resin during various time-temperature cycles. The work was undertaken primarily to provide additional background information relating to the nature and causes of fibre kinking which has been observed in laminates comprising epoxy-carbon composite. The investigation has quantified certain characteristics of the resin which are presumed to be major contributory factors in the occurrence of fibre kinking. It is concluded that a simple solution to the general problem cannot be identified, although some possibilities are discussed for individual cases.