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991.
1H and 13C nuclear magnetic resonance (n.m.r.) spectroscopies have been used to study the changes in composition of a hydrogenated anthracene oil solvent that occur during extraction of a UK bituminous coal. It has been shown that the principal hydrogen donor groups in the solvent are hydroaromatic and naphthenic rings in hydroaromatic species. Good agreement was achieved between the concentration of donatable hydrogen estimated from n.m.r., and the amount of hydrogen transferred from the solvent during exhaustive extraction. 相似文献
992.
Thomas Janette A.; Arnold John R.P.; Basran Jaswir; Andrews Julie; Roberts Gordon C.K.; Birdsall Berry; Feeney James 《Protein engineering, design & selection : PEDS》1994,7(6):783-792
A mutant of Lactobacillus casei dihydrofolate reductase hasbeen constructed in which Thr63, a residue which interacts withthe 2'-phosphate group of the bound coenzyme, is replaced byalanine. This substitution does not affect kcat, but producesan 800-fold increase in the Km for NADPH, which reflects dissociationof NADPH from the enzyme-NADPH-tetrahydrofolate complex, anda 625-fold increase (corresponding to 3.8 kcal/mol) in the dissociationconstant for the enzyme-NADPH complex. The difference in magnitudeof these effects indicates a small effect of the substitutionon the negative cooperativity between NADPH and tetrahydrofolate.Stopped-flow studies of the kinetics of NADPH binding show thatthe weaker binding arises predominantly from a decrease in theassociation rate constant. NMR spectroscopy was used to comparethe structures of the mutant and wild-type enzymes in solution,in their complexes with methotrexate and with methotrexate andNADPH. This showed that only minimal structural changes resultfrom the mutation; a total of 47 residues were monitored fromtheir resolved 1H resonances, and of these nine in the binarycomplex and six in the ternary differed in chemical shift betweenmutant and wild-type enzyme. These affected residues are confinedto the immediate vicinity of residue 63. There is a substantialdifference in the 31P chemical shift of the 2'-phosphate ofthe bound coenzyme, reflecting the loss of the interaction withthe side chain of Thr63. The only changes in nuclear Overhausereffects (NOEs) observed were decreases in the intensity of NOEsbetween protons of the adenine ring of the bound coenzyme andthe nearby residues Leu62 and Ile102, showing that the substitutionof Thr63 does cause a change in the position or orientationof the adenine ring in its binding site. 相似文献
993.
Viscosity rise and extent of reaction were followed during the step growth polymerization of linear and branched urethanes in bulk and in solution. Results indicate that intra-molecular reaction may exist in both linear and branched systems. Adding solvent increases the extent of intra-molecular reaction. The system viscosity was found to correlate with CgMw, where C is polymer concentration, g is the ratio of branched to linear polymer radii of gyration, and Mw is the weight-average molecular weight. 相似文献
994.
Iron-ascorbate stimulated lipid peroxidation in rat liver microsomes can be inhibited by glutathione (GSH). The role of protein
thiols and vitamin E in this process was studied in liver microsomes isolated from rats fed diets either sufficient or deficient
in vitamin E and incubated at 37°C unde 100% O2. Lipid peroxidation was induced by adding 400 μM adenosine 5′-triphosphate, 2.5 to 20 μM FeCl3, and 450 μM ascorbic acid. One mL of the incubation mixture was removed at defined intervals for the measurement of thiobarbituric
acid reactive substances (TBARS), protein thiols and vitamin E. In vitamin E sufficient microsomes, the addition of GSH enhanced
the lag time prior to the onset of maximal TBARS accumulation and inhibited the loss of vitamin E. Treatment of these microsomes
with the protein thiol oxidant diamide resulted in a 56% loss of protein thiols, but did not significantly change vitamin
E levels. However, diamide treatment abolished the GSH-mediated protection against TBARS formation and loss of vitamin E during
ascorbate-induced peroxidation. Liver microsomes isolated from rats fed a vitamin E deficient diet contained 40-fold less
vitamin E and generated levels of TBARS similar to vitamin E sufficient microsomes at a 4-fold lower concentration of iron.
GSH did not affect the lag time prior to the onset of maximal TBARS formation in vitamin E deficient microsomes although total
TBARS accumulation was inhibited. Similar to what was previously found in vitamin E sufficient microsomes [Palamanda and Kehrer,
(1992)Arch. Biochem. Biophys. 293, 103–109], GSH prevented the loss of protein thiols in vitamin E deficient microsomes. However, GSH did not protect efficiently
against the loss of residual vitamin E in deficient microsomes. These data provide support for the concept that GSH protects
against microsomal lipid peroxidation by maintaining protein thiols, and consequently vitamin E, in the reduced state. The
lack of protection in vitamin E deficient microsomes may be related to the inability of such low levels of vitamin E to inhibit
peroxidation. 相似文献
995.
Fred J. Eller Robert J. Bartelt Baruch S. Shasha David J. Schuster David G. Riley Philip A. Stansly Thomas F. Mueller Kenneth D. Shuler Bruce Johnson James H. Davis Carol A. Sutherland 《Journal of chemical ecology》1994,20(7):1537-1555
This study describes the identification of an aggregation pheromone for the pepper weevil,Anthonomus eugenii and field trials of a synthetic pheromone blend. Volatile collections and gas chromatography revealed the presence of six male-specific compounds. These compounds were identified using chromatographic and spectral techniques as: (Z)-2-(3,3-dimethylcyclohexylidene)ethanol, (E)-2-(3,3-dimethylcyclohexylidene)ethanol, (Z)-(3,3-dimethylcyclohexylidene)acetaldehyde, (E)-(3,3-dimethylcyclohexylidene)acetaldehyde, (E)-3,7-dimethyl-2,6-octadienoic acid (geranic acid), and (E)-3,7-dimethyl-2,6-octadien-1-ol (geraniol). The emission rates of these compounds from feeding males were determined to be about: 7.2, 4.8, 0.45, 0.30, 2.0, and 0.30µg/male/day, respectively. Sticky traps baited with a synthetic blend of these compounds captured more pepper weevils (both sexes) than did unbaited control traps or pheromone-baited boll weevil traps. Commercial and laboratory formulations of the synthetic pheromone were both attractive. However, the commercial formulation did not release geranic acid properly, and geranic acid is necessary for full activity. The pheromones of the pepper weevil and the boll weevil are compared. Improvements for increasing trap efficiency and possible uses for the pepper weevil pheromone are discussed. A convenient method for purifying geranic acid is also described.The mention of firm names or trade products does not imply endorsement or recommendation by the U.S. Department of Agriculture over other firms or similar products not mentioned. All programs and services of the U.S. Department of Agriculture are offered on a nondiscriminatory basis without regard to race, color, national origin, religion, sex, age, marital status or handicap. 相似文献
996.
Widely different hydrogen adsorption capacities have been reported for a variety of carbon materials which have attracted attention for hydrogen storage. This has led to doubts as to the validity of some of the claims and it has been suggested that one possible reason for the disparate hydrogen sorption capacities may lie in the inaccurate measurement of the hydrogen adsorbed. The aim of the work described in this paper was to make a contribution to this debate by developing a means and method of producing repeatable, accurate measurements of hydrogen sorption capacity in carbon materials. The apparatus developed is a volumetric differential pressure set-up operating at up to 10 MPa and the method has a conservative limit of detection of 0.1 wt% and an accuracy of ±0.05 wt%, using 1.0-2.5 g samples of the carbon materials studied. These included a carbon nanofiber sample and a series of activated carbons, the latter displaying a direct correlation between the BET effective surface area and the hydrogen sorption capacity of the materials. The amount of hydrogen adsorbed was less than 1 wt% for all the carbons examined. 相似文献
997.
James G. Kohl Andrew G. Kohl Angel Licea-Claverie Arturo Zizumbo-Lopez Randika Jayasinghe Mascareneous Ashokcline 《Polymer-Plastics Technology and Engineering》2020,59(13):1463-1472
ABSTRACT Waste can be considered a crisis across the world, especially in the Global South where landfills are collapsing and vector-borne illnesses are increasing. Due to the increase in the amount of waste plastic in the environment, different uses of recycled plastics are being investigated. One such use is roofing tiles. This has been put in place in Sri Lanka through the Waste for Life organization. Here, recycled polyethylene is filled with rice husk particles. Due to the hydrophilic nature of the rice husk, the strength of the polyethylene composites decreased with increasing rice husk filler. Since the roofing tiles do not need to support a large load, the loss in strength should not be too detrimental. However, the creep behavior was improved with 10% and 20% filler. This is important in that the temperature on the roof can reach high temperatures. 相似文献
998.
The changes in structure and mechanical properties of melt spun polypropylene filaments were determined as the filaments were successively (i) drawn, (ii) twisted, (iii) annealed, and (iv) untwisted. Filaments spun to two different melt draw down levels were studied. The effects of draw temperature and draw ratio, extent of twist, annealing temperature, and the extent of untwisting were examined. Melt spun and twisted filaments (draw ratio of 1) were also considered. Structural characterization techniques used in this study include wide angle (WAXS) and small angle (SAXS) diffraction, scanning electron microscopy (SEM), birefringence and density measurement. Drawing increased crystalline orientation and at low temperatures disrupted the monoclinic unit. cell existing in the melt spun fibers. The drawing produced considerable fibrillation under all conditions even when carried out at 120°C. The fibrillation quid void formation due to low temperature drawing was more pronounced. The variation of WAXS patterns and mechanical properties of twisted drawn filaments was interpreted by presuming that the fibrils act in a manner analogous to that of the filaments in a continuous filament twisted yarn. In the case of incompletely drawn filaments the effect of additional drawing occurring during twistin must be considered. Twisted fibers annealed at 150°C sowed a drastic reduction in tensile properties, while those annealed at 125°C did not set the twist and caused the fibers to tend to untwist. Annealing at 140°C appeared to give satisfactory heat setting. Annealing of cold drawn and cold drawn and twisted fibers increased the density, removed many defects and reformed a well defined monoclinic crystal structure and a lamellar morphology. Untwisting of heat set filaments tended to give back the properties of hot drawn fibers. In some cases, however, the opening of cracks was noted. 相似文献
999.
Flash pyrolysis of Loy Yang brown coal, and Liddell and Millmerran bituminous coals has been studied using a fluidized-bed reactor with a nominal throughput of 20 kg h?1. The apparatus and its performance are described. The yields of tar and hydrocarbon gases are reported for each coal in relation to pyrolysis temperature, as also are analytical data on the pyrolysis products. The peak tar yields for the dry, ash-free Loy Yang and Millmerran coals were respectively 23% wt/wt (at ≈ 580 °C) and 35% wt/wt (at 600 °C). The tar yield from Liddell coal was 31% wt/wt at ≈ 580 °C. Hydro-carbon gases were produced in notable quantities during flash pyrolysis; e.g. Millmerran coal at 810 °C gave 6% wt/wt (daf) methane, 0.9% wt/wt ethane, 6% wt/wt ethylene, and 2.5% wt/wt propylene. The atomic ratios and the absolute levels of hydrogen in product tars and chars decreased steadily with increasing pyrolysis temperature. 相似文献
1000.
A series of experiments has been carried out to study the way in which preparation conditions of coal digests influence filtration rate. It was shown that a relation exists between cake resistivity and digestion temperature and time, and therefore good control over digestion conditions is important for rapid filtration. Particular attention must be paid to the design of the reactor to ensure that all the material is given the same heat-treatment. The optimum residence time occurs when repolymerization of the dissolved coal commences. 相似文献