Influences of iron, manganese, and dissolved organic carbon on the hypolimnetic cycling of amended mercury

The biogeochemical cycling of iron, manganese, sulfide, and dissolved organic carbon were investigated to provide information on the transport and removal processes that control the bioavailability of isotopic mercury amended to a lake. Lake profiles showed a similar trend of hypolimnetic enrichment of Fe, Mn, DOC, sulfide, and the lake spike ((202)Hg, purity 90.8%) and ambient of pools of total mercury (HgT) and methylmercury (MeHg). Hypolimnetic enrichment of Fe and Mn indicated that reductive mobilization occurred primarily at the sediment-water interface and that Fe and Mn oxides were abundant within the sediments prior to the onset of anoxia. A strong relationship (r(2)=0.986, n=15, p<0.001) between filterable Fe and Mn indicated that reduction of Fe and Mn hydrous oxides in the sediments is a common in-lake source of Fe(II) and Mn(II) to the hypolimnion and that a consistent Mn:Fe mass ratio of 0.05 exists in the lake. A strong linear relationship of both the filterable [Fe] (r(2)=0.966, n=15, p<0.001) and [Mn] (r(2)=0.964, n=15, p<0.001) to [DOC] indicated a close linkage of the cycles of Fe and Mn to DOC. Persistence of iron oxides in anoxic environments suggested that DOC was being co-precipitated with Fe oxide and released into solution by the reductive dissolution of the oxide. The relationship between ambient and lake spike HgT (r(2)=0.920, n=27, p<0.001) and MeHg (r(2)=0.967, n=23, p<0.001) indicated that similar biogeochemical processes control the temporal and spatial distribution in the water column. The larger fraction of MeHg in the lake spike compared to the ambient pool in the hypolimnion suggests that lake spike may be more available for methylation. A linear relationship of DOC to both filterable ambient HgT (r(2)=0.406, n=27, p<0.001) and lake spike HgT (r(2)=0.314, n=15, p=0.002) suggest a role of organic matter in Hg transport and cycling. However, a weak relationship between the ambient and lake spike pools of MeHg to DOC indicated that other processes have a major role in controlling the abundance and distribution of MeHg. Our results suggest that Fe and Mn play important roles in the transport and cycling of ambient and spike HgT and MeHg in the hypolimnion, in part through processes linked to the formation and dissolution of organic matter-containing Fe and Mn hydrous oxides particles.     

Analysis of the Response of Smoke Detectors to Smoldering Fires and Nuisance Sources

Since the initial smoke detector was developed, research has been ongoing to reduce the response times to fire sources and improve the ability of detectors to ignore nuisance sources. Research has been conducted to analyze the signatures from cooking activities, ranging from normal cooking to the flaming ignition of food products with the intent of identifying the precursors to flaming ignition. In particular, the goal of the research is to provide an alarm sufficiently prior to flaming ignition to allow homeowners to take corrective actions to prevent a fire. For the 11 experiments analyzed, the optical density measured in the range hood was the most accurate precursor signal, having the greatest ability to predict the imminent transition to a flaming fire with a minimum of false positives. Though plagued by false positives, the temperature of the heating element and response of an ionization detector provided a faster response than the optical density measure. Given that this research only included 11 experiments, further research should be conducted on a broader range of cooking styles and items being cooked.     

Microstructure-Based Estimation of Strength and Ductility Distributions for $$\alpha +\beta $$ Titanium Alloys

Titanium alloys are processed to develop a wide range of microstructure configurations and therefore material properties. While these properties are typically measured experimentally, a framework for property prediction could greatly enhance alloy design and manufacturing. Here a microstructure-sensitive framework is presented for the prediction of strength and ductility as well as estimates of the bounds in variability for these properties. The framework explicitly considers distributions of microstructure via new approaches for instantiation of structure in synthetic samples. The parametric evaluation strategy, including the finite element simulation package FEpX, is used to create and test virtual polycrystalline samples to evaluate the variability bounds of mechanical properties in Ti-6Al-4V. Critical parameters for the property evaluation framework are provided by measurements of single crystal properties and advanced characterization of microstructure and slip system strengths in 2D and 3D. Property distributions for yield strength and ductility are presented, along with the validation and verification steps undertaken. Comparisons between strain localization and slip activity in virtual samples and in experimental grain-scale strain measurements are also discussed.

     

Developing a procurement path determination chart SEM-based approach

The choice of an appropriate procurement system is crucial to construction project success. Procurement selection is largely based on path determination charts, with at least eight key criteria needing to be weighted by decision-makers. Including certain criteria whilst ignoring client-borne transaction costs (TCs) resulting from environmental uncertainties simplifies this process. TCs are ‘unseen’ costs associated with pre- and post-contract work. The effects of uncertainties in the transaction environment and procurement systems on TCs are investigated, comparing the traditional and design-build procurement systems. A cross-sectional sample approach was deployed, involving survey questionnaire and results verification through ‘real-world’ cases. Data was sought from construction professionals in management, design and operation of construction projects. The research participants evaluate their time spent on procurement activities using a five-point Likert scale. Hypotheses of the relations between environmental uncertainties, procurement systems, and pre- and post-contract TCs are tested using a structural equation modelling (SEM) approach. The study found that TCs account for about 46.75% and 42.88% of the daily time spent by project managers in traditional and design-build procurement systems in New Zealand respectively. The study concludes that the TC concept is a useful framework for determining objective instead of subjective opinions for procurement decisions.     

The Case of The Case Study in City Planning and Municipal Management

Abstract

PLAN FOR REZONING THE CITY OF NEW YORK. A Report by Harrison, Ballard &; Allen. City Planning Commission. New York. 1950. 290 pp. maps, illustrations. $2.00.

CONTROLLED ACCESS EXPRESSWAYS IN URBAN AREAS—A symposium. Highway Research Board Bulletin No. 25. Washington, D. C., 1950. 45 pages, illustrated. 60 cents.

SOCIAL PRESSURES IN INFORMAL GROUPS. By Leon Festinger, Stanley Schachter and Kurt Back. Harper Bros., New York, 1950. x-930 pp. $3.00.

PRODUCTION OF NEW HOUSING. A Research Monograph on Efficiency in Production. By Leo Grebler. Social Science Research Council. New York 1950. ix+ 186 pp. $1.75.     

Frustrations of National Planning: Reality and Theory in Colombia

Realities of national planning in Colombia are used as background for an examination of theory and models of national planning. Colombia is a democratic and relatively prosperous developing country of Latin America which has had a few periods of violent crises. National planning is highly centralized in Colombia along the lines suggested by several theorists in the United States. Yet the national planning function has been rife with frustrations and dubious successes. Such conditions merit examination of the theory of national planning in general.     

Feasibility of Using Titanium Machine Turnings in Powder Metallurgy Processes

JOM - The use of titanium machine turnings has been identified as a possible ultralow-cost method to produce titanium powder. However, very little data are available on the viability of this...     

Structural and compositional analysis of (InGa) (AsSb)/GaAs/GaP Stranski–Krastanov quantum dots

We investigated metal-organic vapor phase epitaxy grown (InGa)(AsSb)/GaAs/GaP Stranski–Krastanov quantum dots (QDs) with potential applications in QD-Flash memo...     

Generation of Functional Immortalized Human Corneal Stromal Stem Cells

In addition to their therapeutic potential in regenerative medicine, human corneal stromal stem cells (CSSCs) could serve as a powerful tool for drug discovery and development. Variations from different donors, their isolation method, and their limited life span in culture hinder the utility of primary human CSSCs. To address these limitations, this study aims to establish and characterize immortalized CSSC lines (imCSSC) generated from primary human CSSCs. Primary CSSCs (pCSSC), isolated from human adult corneoscleral tissue, were transduced with ectopic expression of hTERT, c-MYC, or the large T antigen of the Simian virus 40 (SV40T) to generate imCSSC. Cellular morphology, proliferation capacity, and expression of CSSCs specific surface markers were investigated in all cell lines, including TNFAIP6 gene expression levels in vitro, a known biomarker of in vivo anti-inflammatory efficacy. SV40T-overexpressing imCSSC successfully extended the lifespan of pCSSC while retaining a similar morphology, proliferative capacity, multilineage differentiation potential, and anti-inflammatory properties. The current study serves as a proof-of-concept that immortalization of CSSCs could enable a large-scale source of CSSC for use in regenerative medicine.