The influence of the legal and economical environment and the profile of activities on the optimal design features of a natural-gas-fired combined heat and power plant

The paper deals with the effect of some selected quantities occurring in the legal and economical environment on the optimal values of some selected design quantities of a natural-gas-fired CHP plant. This trend of investigations results from the newly observed legal changes in the legislation concerning new forms of mechanisms supporting the combined production of electricity and heat. Special stress was exerted on changes resulting from the formulation of two directives, viz. 2003/7/EC and 2004/8/EC.For the purpose of realising this task, a reference structure of a CHP plant was selected. For the steam-water part of the plant thirteen quantities were selected, determining the design features of the most essential components of this part of the system. These quantities served as decision variables in processes of optimisation. As the objective function the break-even price of electricity was assumed.The second part of the paper presents the results of sensitivity analyses of the fundamental indices of the energy and economical effectiveness to failures in the adherence of the optimal values of the respective design quantities, as well as the results of investigations on the effect of the operation time of the plant in the course of one year.     

ZnO Nanoplatelets with Controlled Thickness: Atomic Insight into Facet-Specific Bimodal Ligand Binding Using DNP NMR

Colloidal nanoplatelets (NPLs) and nanosheets with controlled thickness have recently emerged as an exciting new class of quantum-sized nanomaterials with substantially distinct optical properties compared to 0D quantum dots. Zn-based NPLs are an attractive heavy-metal-free alternative to the so far most widespread cadmium chalcogenide colloidal 2D semiconductor nanostructures, but their synthesis remains challenging to achieve. The authors describe herein, to the best of their knowledge, the first synthesis of highly stable ZnO NPLs with the atomically precise thickness, which for the smallest NPLs is 3.2 nm (corresponding to 12 ZnO layers). Furthermore, by means of dynamic nuclear polarization-enhanced solid-state ¹⁵N NMR, the original role of the benzamidine ligands in stabilizing the surface of these nanomaterials is revealed, which can bind to both the polar and non-polar ZnO facets, acting either as X- or L-type ligands, respectively. This bimodal stabilization allows obtaining hexagonal NPLs for which the surface energy of the facets is modulated by the presence of the ligands. Thus, in-depth study of the interactions at the organic–inorganic interfaces provides a deeper understanding of the ligand–surface interface and should facilitate the future chemistry of stable-by-design nano-objects.     

Interactions of Amyloid-β with Membrane Proteins

In developing and developed countries, an increasing elderly population is observed. This affects the growing percentage of people struggling with neurodegenerative diseases, including Alzheimer’s disease. Nevertheless, the pathomechanism of this disease is still unknown. This contributes to problems with early diagnosis of the disease as well as with treatment. One of the most popular hypotheses of Alzheimer’s disease is related to the pathological deposition of amyloid-β (Aβ) in the brain of ill people. In this paper, we discuss issues related to Aβ and its relationship in the development of Alzheimer’s disease. The structure of Aβ and its interaction with the cell membrane are discussed. Not only do the extracellular plaques affect nerve cells, but other forms of this peptide as well.     

The impact of a sewage treatment plant's effluent on sediment quality in a small bay in Lake Geneva (Switzerland–France). Part 2: Temporal evolution of heavy metals

The Bay of Vidy is the most contaminated area of Lake Geneva, Switzerland, as a result of the release of treated and untreated waste water from the municipal sewage treatment plant of the city of Lausanne and its surroundings. The reconstruction of the historical deposition of heavy metals in the sediment of the bay has been performed by the analysis of several dated (radiocaesium) sediment cores. The presence of sewage‐derived contaminants in the Bay of Vidy since the beginning of the sewage treatment plant's operations in 1964 is clearly observed, when a sharp increase in heavy metal contents is recorded, with maximum concentrations of cadmium, copper, zinc and lead occurring between the late 1960s and early 1970s. Despite considerable improvement in recent times, the present concentrations of the investigated heavy metals in sediments of the Bay of Vidy are still higher than concentrations measured at the centre of the lake, the latter close to Lake Geneva's natural background values. It is concluded that the quantity of heavy metals deposited in the bay is considerable and, because of sediment instability, will constitute a potential hazard for biota.     

Direct determination of benzodiazepines in biological fluids by restricted-access solid-phase microextraction

A biocompatible solid-phase microextraction (SPME) fiber was prepared using an alkyl-diol-silica (ADS) restricted-access material as the SPME coating. The ADS-SPME fiber was able to simultaneously fractionate the protein component from a biological sample, while directly extracting several benzodiazepines, overcoming the present disadvantages of direct sampling in biological matrixes by SPME. The fiber was interfaced with an HPLC-UV system, and an isocratic mobile phase was used to desorb, separate, and quantify the extracted compounds. The calculated clonazepam, oxazepam, temazepam, nordazepam, and diazepam detection limits were 600, 750, 333, 100, and 46 ng/mL in urine, respectively. The method was confirmed to be linear over the range of 500-50000 ng/mL with an average linear coefficient (R2) value of 0.9918. The injection repeatability and intraassay precision of the method were evaluated over 10 injections, resulting in a RSD of approximately 6%. The ADS-SPME fiber was robust and simple to use, providing many direct extractions and subsequent determination of benzodiazepines in biological fluids.     

Lecane tenuiseta rotifers improves activated sludge settleability in laboratory scale SBR system at 13°C and 20°C

Two experiments at different temperatures were conducted in five laboratory‐scale bioreactors with enhanced nutrient removal simulating the work of sequencing batch reactors (SBRs). The process was operated in three 8‐hour cycles. The oxygen concentration, pH and temperature were controlled and maintained at 1 mg of O₂/L, 7 and 13°C, respectively, throughout the first two weeks and at 20°C for the next 10 days. The introduction of Lecane tenuiseta improved the settling properties of the activated sludge dominated by Microthrix parvicella at both temperatures tested. L. tenuiseta rotifers led to a reduction in filamentous bacteria abundance and did not negatively affect the chemical parameters of the effluent. For each temperature, there were no differences in COD, N_tot, N‐NH₄ or P‐PO₄ values between the treatment and control bioreactors. The results have shown that the application of L. tenuiseta is a promising biological tool for bulking prevention especially in a cold season.     

Selected elements of rock burst state assessment in case studies from the Silesian hard coal mines

Exploitation of coal seams in the Upper Silesian Coal Basin is conducted in complex and difficult conditions. These difficulties are connected with the occurrence of many natural mining hazards and limitations resulting from the existing in this area surface infrastructure. One of the most important problems of Polish mining is the rock burst hazard and reliable evaluation of its condition. During long-years' mining practice in Poland a comprehensive system of evaluation and control of this hazard was de-veloped. In the paper the main aspects of rock burst hazard state evaluation will be presented, comprising: 1) rock mass inclination for rock bursts, I.e., rock strength properties investigation, comprehensive parametric evaluation of rock mass inclination for rock bursts, prognosis of seismic events induced by mining operations, methods of computer-aided modelling of stress and rock mass deformation parameters distribution, strategic rock mass classification under rock burst degrees; 2) immediate seismic and rock burst hazard state evaluation, I.e., low diameter test drilling method, seismologic and seismoacoustic method, comprehensive method of rock burst hazard state evaluation, non-standard methods of evaluation; 3) legal aspects of rock burst hazard state evaluation. Selected elements of the hazard state evaluation system are illustrated with specific practical examples of their applica-tion.     

Surface morphology of steel and titanium induced by ion beam bombardment – Comprehensive analysis

It is well known that ion bombardment of solid surface modifies its physical and chemical properties, among others, surface morphology. In this paper we try to concentrate on four aspects of ion beam induced surface morphology, i.e.: (a) surface topography, (b) surface roughness, (c) rate of profile shape variability, and (d) surface morphology arrangement. Surface topographies (in micro- and nanometre range) were observed by means of scanning electron and near-field microscopes. High quality profilograph and atomic force microscope were utilised to measure surface roughness parameters. To do that, surface profiles must be well known. To detect any profile shape alteration during ion beam bombardment we used fractal analysis, and especially fractal dimension D that can give information about rate of profile shape variability. Surface morphology arrangement, i.e. a question whether it is random or determined, was studied with the use of frequency plots resulting from harmonic analysis of profiles.We studied surface topographies, selected roughness parameters, fractal dimensions and frequency plots relating to stainless steel and polycrystalline 99.5% titanium bombarded with perpendicular low energy (800 eV) broad argon ion beam as well as neutralized narrow argon or krypton ion beam (up to 6 keV).     

Unconventional fractional quantum Hall effect in monolayer and bilayer graphene

The commensurability condition is applied to determine the hierarchy of fractional fillings of Landau levels in monolayer and in bilayer graphene. The filling rates for fractional quantum Hall effect (FQHE) in graphene are found in the first three Landau levels in one-to-one agreement with the experimental data. The presence of even denominator filling fractions in the hierarchy for FQHE in bilayer graphene is explained. Experimentally observed hierarchy of FQHE in the first and second Landau levels in monolayer graphene and in the zeroth Landau level in bilayer graphene is beyond the conventional composite fermion interpretation but fits to the presented nonlocal topology commensurability condition.     

Hamiltonian direct differentiation and adjoint approaches for multibody system sensitivity analysis

The design of multibody systems involves high fidelity and reliable techniques and formulations that should help the analyst to make reasonable decisions. Given that constrained equations of motion for the simplest of multibody systems are highly nonlinear, determining the sensitivity terms is a computationally intensive and complex process that requires the application of special procedures. In this article, two novel Hamiltonian-based approaches are presented for efficient sensitivity analysis of general multibody systems. The developed direct differentiation and the adjoint methods are based on constrained Hamilton's canonical equations of motion. This formulation provides solutions, which are more stable as compared to the results of direct integration of equations of motion expressed in terms of accelerations due to a reduced differential index of the underlying system of differential-algebraic equations and explicit constraint imposition at the velocity level.The proposed Hamiltonian based methods are both capable of calculating the sensitivity derivatives and keeping the growth of constraint violation errors at a reasonable rate. The Hamiltonian-based procedures derived herein appear to be good alternatives to existing methods for sensitivity analysis of general multibody systems.