Carbonyl‐precursor‐based W/Al2O3 and CoW/Al2O3 catalysts: characterization by temperature‐programmed methods

Carbonyl‐precursor‐based W/Al₂O₃ and bimetallic CoW/Al₂O₃ catalysts were prepared by gas‐phase adsorption in a fluidized‐bed reactor. The surface species formed during the gradual and controlled preparation process were studied by temperature‐programmed methods. Interactions on the surface were investigated as a function of metal loading by temperature‐programmed oxidation (TPO) and oxygen pulse chemisorption (PCO). A clear relationship was observed between decarbonylation treatment and the tungsten species formed. Total acidity of the samples was determined by temperature‐programmed desorption of ammonia (NH₃‐TPD). The NH₃‐TPD measurements, together with previous activity studies, suggest a relationship between total acidity and hydrotreating activity. The results of PCO and NH₃‐TPD measurements indicate that when the controlled gas‐phase preparation method is applied to zerovalent carbonyl precursor, the unfavourable formation of tungsten oxide can be minimized. This revised version was published online in July 2006 with corrections to the Cover Date.     

Scalable Parallel Memory Architectures for Video Coding

Current video compression standards, which process frames macroblock by macroblock, employ several processing functions to achieve the compression. These functions refer to data memory address space in different ways. E.g., performing motion estimation and motion compensation functions requires many times data accesses unaligned to word boundaries. On the other hand, Discrete Cosine Transformation (DCT) and inverse of it (IDCT) for 8 × 8 block can be performed first for rows and then for columns. Thus, transposition is needed between these two stages. Among other things, parallel memory architecture can provide a solution for these tasks. In our other paper, we shortly surveyed parallel memory architectures and proposed parallel memory architecture designs for different data path widths for video coding applications. In this paper, we construct video coding function examples by using the proposed parallel data memory efficiently. Furthermore, performance and implementation cost of the parallel memory architecture are estimated and compared to more conventional memory architectures. The examples are given for different data bus widths (16, 32, 64, and 128 bits). We show that the parallel memory can keep the data path fully utilized in many video coding function implementations. This ensures high-speed operation and full utilization of the processing resources.     

Toward Efficient Execution of RVC-CAL Dataflow Programs on Multicore Platforms

The increasing number of cores in System on Chips (SoC) has introduced challenges in software parallelization. As an answer to this, the dataflow programming model offers a concurrent and reusability promoting approach for describing applications. In this work, a runtime for executing Dataflow Process Networks (DPN) on multicore platforms is proposed. The main difference between this work and existing methods is letting the operating system perform Central processing unit (CPU) load-balancing freely, instead of limiting thread migration between processing cores through CPU affinity. The proposed runtime is benchmarked on desktop and server multicore platforms using five different applications from video coding and telecommunication domains. The results show that the proposed method offers significant improvements over the state-of-art, in terms of performance and reliability.     

On the power of L-systems in image generation

Image generation with DOL-systems is discussed. It is shown that, if either the vector or the turtle geometry interpretation is used, DOL-systems can produce step-by-step all images that can be generated by regular languages (or by equivalent Iterative Matrix Homomorphisms of Shallit and Stolfi). An extension of turtle geometry interpretation is introduced that enables L-systems to generate gray-tone images. It is shown that with our extension every Weighted Finite Automaton can be simulated step-by-step by a DOL-system.An abbreviated version of this paper was presented at the conference Developments in Formal Languages, Turku, July 1993.Research supported by the NSF Grant No. CCR-9202396This article was processed by the author using the LATEX style file pljourl from Springer-Verlag.     

Oxygen detection by non-Rutherford proton backscattering below 2.5 MeV

Oxygen detection by proton backscattering has been investigated. The oxygen detection sensitivity of 2.5 MeV proton backscattering is shown to exceed that of ⁴He backscattering by even a factor of about 15 depending on the matrix. The needed proton elastic scattering cross sections of oxygen for θ_lab = 170° have been measured in the energy range E_lab = 770–2480 keV relative to Ti and Sn elastic scattering cross sections using thin TiO₂ and SnO₂ samples. The angular dependence of the cross section was measured at energies E_lab = 1790, 1990, 2191, and 2382 keV for backscattering angles. The experimental cross sections were found to be 1.1–5.7 times the pure Coulomb cross section. Theoretical calculations for the scattering cross sections were performed and their inapplicability to experimental purposes is demonstrated. Fits to experimental data are given.     

Complexation of Ni(II) by Dimethylglyoxime for Rapid Removal and Monitoring of Ni(II) in Water

The complexation of Ni(II) with dimethylglyoxime (DMG) entrapped within a Nafion membrane and a DMG–sol–gel matrix was studied and compared for different solutions. First and pseudo-second order kinetic models, Elovich, intra-particle, and liquid film diffusion models were applied to evaluate sorption kinetics. Complexation of Ni(II) by DMG entrapped in the polymeric materials followed a pseudo-second order kinetic model; moreover, DMG in Nafion also allowed diffusion-controlled uptake. The pseudo-second order rate constant was significantly higher for the free ligand in solution than for Ni(II) accumulation in the surface-attached DMG-Nafion. The DMG–sol–gel removal ability of Ni(II) was tested using actual mine water. The presence of interferences only insignificantly decreased the removal percentage of Ni(II), thus confirming the high selectivity of DMG towards Ni(II). Also, an electrochemical sensor modified with DMG in Nafion was investigated further for direct electrochemical determination of Ni(II) in untreated mine water. Determination errors and interference effects were low. Thus, this approach represents an effective potential solution for selective Ni(II) removal from mine water as well as a rapid and cheap sensor for on-site monitoring of Ni(II) in mine and environmental waters.