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91.
The reaction of bivalent ions (Cu, Co, Zn, Ni) with ethylene diamine bounded to homogeneous crosslinked terpolymer glycidyl methacrylate-styrene-divinylbenzene or macroporous copolymer glycidyl methacrylate-ethyleneglycole dimethacrylate has been studied. The capacity of polymer sorbent, exchange ability and the kinetic of the reaction has been studied. 相似文献
92.
Several important parameters for the operation of ion exchange resins in water treatment, such as breakthrough capacity, maximum flow rate, efficiency and reversibility of organic matter sorption and desorption, exhibit a close connection with the ion exchange rate. Therefore this value, expressed as the exchange half-time(l0,5) can be used as a criterion for a proper resin type choice and can also help to judge its use for obtaining treated water of required composition.The sorption and desorption rates of HCl, caproic acid and sulfosalicylic acid by styrene and acrylic weak base resins were estimated and the results obtained with particular resins were compared. Attention has been paid to the effect of gelular and macroporous matrix and solution concentration. Acrylic resins are preferable for sorption and desorption of HCl at low concentrations, at higher concentrations macroporous-styrene resins are better. Sorption of low-molecular organic acids is primarily controlled by selectivity and proceeds faster on acrylic resins at all concentrations. Desorption is governed by the concentration of the elution solution, rather than by selectivity and occurs faster on macroporous styrene resins. The macroporous matrix generally has a substantially smaller kinetic advantage for acrylic than for styrene weak base resins. 相似文献
93.
It was demonstrated that non-homopolymerizing derivatives of 6-caprolactam: 7-cyclohexyl-1-aza-2-cycloheptanone (I) and 7-isopropyl-5-methyl-1-aza-2-cycloheptanone (II) were polymerizing with 6-caprolactam under conditions of the socalled hydrolytic polymerization. With its increasing content in the initial reaction mixture the copolymerization rate, the equilibrium content of the copolymer, and the reduced viscosity decreased. Lactam (I) was a more reactive comonomer in comparison with lactam (II). 相似文献
94.
High resolution gel chromatography was applied to the analysis of phenolic antioxidants mixtures formed by an alkylation of 4,4'-isopropylidenebisphenol and used for the stabilisation of polyolefins and rubbers. The calibration by pure model substances provided values of relative zone rates on S-GEL-832 for a series of tert-butyl and tert-octyl derivatives of phenol and 4,4'-isopropylidenebisphenol. The chromatograms show in some cases a separation of isomers differing in size of their molecules in solution. 相似文献
95.
On the basis of standards of identification of substances in the additive system of polyethylene has been performed. Different methods for separation such as adsorption thin-layer chromatography, high-performance liquid chromatography with chemically bounded phases, and gas chromatography have been used. The fir al identification has been made with mass spectrometry. The substances have been extracted from polyethylene with hexane and chloroform. 相似文献
96.
97.
The work describes the suitability and applicability of the nanoindentation method for the determination of the micromechanical properties of a hen’s eggshell. The values of elastic modulus E were monitored in five different locations along the eggshell’s meridian line. Detailed maps of elastic moduli at particular eggshell cross-sections revealed high variations in local values of E-moduli at individual points, but not significant differences of their means at distant parts of the eggshell. Mean values of E-modulus in different meridian positions did not vary significantly and ranged from 47.4 to 53 GPa. Experimental histograms were created of all elastic moduli showing the frequency of their occurrence and these revealed a rather high variation in E-moduli throughout the cross-section. The probability density function can be characterised by a symmetrical shape and the distribution of E-moduli can be approximated with the Gauss distribution. The nanoindentation technique proved to be a suitable, easy-to-use, and powerful tool for assessing local variations of the mechanical properties of hen’s eggshells. 相似文献
98.
99.
Dutková Erika Sayagués María Jesús Fabián Martin Kováč Jaroslav Kováč Jaroslav Baláž Matej Stahorský Martin 《Journal of Materials Science: Materials in Electronics》2021,32(18):22898-22909
Journal of Materials Science: Materials in Electronics - In this work, the very rapid one-step mechanochemical synthesis of nanocrystalline ternary chalcogenide chalcostibite CuSbS2 prepared from... 相似文献
100.
Daniel Drdlik Martin Slama Hynek Hadraba Katarina Drdlikova Jaroslav Cihlar 《Ceramics International》2018,44(3):2884-2891
In the present work, the preparation of sintered lithium-doped tricalcium phosphates was studied, along with their physical, mechanical, and biological properties. Calcium phosphates were shaped via the use of electrophoretic deposition (EPD), using colloidally milled dispersions of hydroxyapatite (HAp) particles. The dispersions were stabilised with monochloroacetic acid. Lithium was incorporated into the structure via an addition of lithium chloride, which also served to optimise the deposition process. The dispersions were milled colloidally for periods of 0–48 h. The colloidal milling resulted in two effects: i) disintegration of the commercial HAp powder (10 µm) agglomerates, ii) unimodal distribution of the HAp particles (~ 170 nm). The fine particles of the milled HAp dispersions accelerated the deposition rate, and increased the mass of the deposit. The reduced size of the initial particles, owed to the milling, led to the superior arrangement of the particles during deposition and to reduced porosity after sintering (1050–1250 °C). The HAp decomposed into tricalcium phosphate phases during sintering. At a sintering temperature of 1250 °C, grain growth occurred, which consequently resulted in a slight degradation of the mechanical properties (reduction in hardness and Young's modulus). In contrast, the hardness and Young's modulus increased as the dispersion milling time increased (smaller grain size after sintering); however, the fracture toughness did not change. The results of the biological testing confirmed the bioactivity of the material through the growth of the apatite layer in the simulated body fluid (SBF), and the biodegradation of the prepared materials in the Tris-HCl solution. With regard to the preparation of compact lithium-doped tricalcium phosphates, the best results were obtained in the case of the sample that utilised the dispersion that was milled for 48 h, and was sintered at 1050 °C. 相似文献