New rotary valves for pulse-tube refrigerators

In most used rotary valves in GM-type pulse-tube refrigerators the rotor makes heavy mechanical contact with the stator, so the valve is liable to wear, and large torques are needed. In this paper we will describe two types of valves, which have balanced forces on the rotor. In the first valve the rotor and the stator make no mechanical contact. The second type is a contact valve, like the classical valves, but the forces on the rotor are balanced in a different way. Therefore, these valves are less liable to wear, and the torques needed to rotate the valves are small.     

Application of autoregressive spectral analysis to missing data problems

Time series solutions for spectral analysis in missing data problems use reconstruction of the missing data, or a maximum likelihood approach that analyzes only the available measured data. Maximum likelihood estimation yields the most accurate spectra. An approximate maximum likelihood algorithm is presented that uses only previous observations falling in a finite interval to compute the likelihood, instead of all previous observations. The resulting nonlinear estimation algorithm requires no user-provided initial solution, is suited for order selection, and can give very accurate spectra even if less than 10% of the data remains.     

Finite sample properties of ARMA order selection

The cost of order selection is defined as the loss in model quality due to selection. It is the difference between the quality of the best of all available candidate models that have been estimated from a finite sample of N observations and the quality of the model that is actually selected. The order selection criterion itself has an influence on the cost because of the penalty factor for each additionally selected parameter. Also, the number of competitive candidate models for the selection is important. The number of candidates is, of itself, small for the nested and hierarchical autoregressive/moving average (ARMA) models. However, intentionally reducing the number of selection candidates can be beneficial in combined ARMA(p,q) models, where two separate model orders are involved: the AR order p and the MA order q. The selection cost can be diminished by creating a nested sequence of ARMA(r,r-1) models. Moreover, not evaluating every combination (p,q) of the orders considerably reduces the required computation time. The disadvantage may be that the true ARMA(p,q) model is no longer among the nested candidate models. However, in finite samples, this disadvantage is largely compensated for by the reduction in the cost of order selection by considering fewer candidates. Thus, the quality of the selected model remains acceptable with only hierarchically nested ARMA(r,r-1) models as candidates.     

Immunoelectron localization of mitochondrial F1 factor in cryosections of heart muscle cells

Immunocytochemistry was used to investigate the localization of F1 ATPase in mitochondria of cryosections of adult mouse heart muscle cells. The initial aldehyde fixation was the only denaturation step for antigens. The fine structure was preserved with contrast enhancement as the sections were maintained hydrated, with the advantage that the entire procedure is completed in one working day. The reaction was highly specific, and entire mitochondria were labeled with the Protein A-gold complex. A new analytical technique, electron spectroscopic imaging (ESI), contributed to a better visualization of the localization of the F1 factor.     

It takes two to mimic: Behavioral consequences of self-construals.

The present studies demonstrated the moderation of self-construal orientation on mimicry. Recent research has indicated that an interdependent self-construal is associated with assimilation of the other to the self whereas an independent self-construal is associated with minimizing the influence of others on the self (H. R. Markus & S. Kitayama, 1991; D. Stapel & W. Koomen, 2001). Therefore, the authors hypothesized that an interdependent self-construal would be associated with more mimicry than an independent self-construal. When self-construal orientations were experimentally primed. as in Studies 1 and 2, independent self-construals produced less nonconscious mimicry than interdependent self-construals. When self-construals were examined as cultural differences with either a chronically dominant independent (Americans) or interdependent (Japanese) construal of the self, these results were replicated. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Critical Shear Stress of Bimodal Sediment in Sand-Gravel Rivers

A new model for the critical shear stress and the transport of graded sediment is presented. The model is based on the size distribution of the bed surface and can be used to compute sediment transport rates in numerical simulations with an active layer model. This model makes a distinction between unimodal and bimodal sediments. It is assumed that all size fractions of unimodal sediments have the same critical shear stress while there is selective transport for the gravel fractions of bimodal sediments. A recently published laboratory transport data set is used to calibrate our model.     

Development of New Sulphonyl Resin from Modification of Commercial Resin

Summary This article deals with the handy synthesis of sulfonyl resins, which were produced by the treatment of a commercial sulfonic resin (Lewatit VPOC1812^® based at divinylbenzene (DVB) and styrene (STY). The preliminary chemical modification was based on the reaction of the Lewatit VPOC1812^® with thionyl chloride aiming to produce the sulfonyl chloride groups. The best conditions to obtain the sulfonyl chloride groups were: SOCl₂/SO₃H (molar ratio) =13 at 79 °C during 72 h. The resin chlorinated was afterward treated with urea, thiourea or guanidine. The functionalized resins with urea, thiourea or guanidine were produced with 56, 68 and 93% yield, respectively. The commercial and modified resins were characterized by apparent density, swelling degree, elemental analysis (CHNS), FTIR, optical microscopy (OM) and scanning electron microscopy (SEM).     

Comparison between photocatalytic ozonation and other oxidation processes for the removal of phenols from water

Photocatalytic ozonation (1O₃ + VUV + TiO₂), ozonation (O₃), catalytic ozonation (O₃ + TiO₂), ozone photolysis (O₃ + VUV), photocatalysis (TiO₂ + VUV) and photolysis (VUV) have been compared in terms of formation of intermediates, extent of, mineralization (TOC, COD, chloride, nitrate) and kinetics in the aqueous treatment of three phenols (phenol, p‐chlorophenol and p‐nitrophenol). In all cases, photocatalytic ozonation led to lower degradation times for chemical oxygen demand and total organic carbon removal. Intermediates formed were similar in the different oxidation systems with some exceptions. They can be classified into three different types: polyphenols (resorcinol, catechol, hydroquinone), unsaturated carboxylic acids (maleic and fumaric acids) and saturated carboxylic acids (glyoxylic, formic and oxalic acids). First order kinetic equations have been checked for the oxidation processes studied in the case of the parent compound. Rate constants of these systems have also been calculated. Copyright © 2005 Society of Chemical Industry