Ion beam sputtering coatings on large substrates: toward an improvement of the mechanical and optical performances

Large mirrors (?350 mm) having extremely low optical loss (absorption, scattering, wavefront) were coated for the VIRGO interferometer. The new generation of mirrors needs to have a better wavefront and lower mechanical loss. To improve the component wavefront, the corrective coating technique was used. By doping the tantalum pentoxide layers, we improved, for the first time to our knowledge, the multilayer mechanical loss. The first results are discussed.     

Peptides released from acid goat whey by a yeast-lactobacillus association isolated from cheese microflora

Seven lactobacilli and a variety of microflora extracted from twenty five commercial cheeses were grown on unsupplemented acid goat whey and screened for their capacity to hydrolyse whey proteins [alpha-lactalbumin (alpha-la) and beta-lactoglobulin (beta-lg)] and to generate peptides. Fermentations were performed aerobically or anaerobically at 37 degrees C using crude or pre-heated whey (10 min at 65, 75 or 85 degrees C). Under aerobic conditions, growth of lactobacilli was poor and protein hydrolysis did not occur. Anaerobic conditions slightly increased lactobacilli growth but neither beta-lg hydrolysis nor peptide generation were observed. More than 50% of alpha-la was digested into a truncated form of alpha-la (+/- 12 kDa) in crude whey and whey pre-heated at 65 degrees C. Twenty-five microflora extracted from raw milk cheeses were screened for their proteolytic activities on acid goat whey under the conditions previously described. Eight of them were able to hydrolyse up to 50% of alpha-la mainly during aerobic growth on crude or pre-heated whey. The corresponding hydrolysates were enriched in peptides. The hydrolysate involving microflora extracted from Comté cheese after or at 18 months ripening was the only one to exhibit hydrolysis of both alpha-la and beta-lg. Microbiological analysis showed that microorganisms originating from Comté cheese and capable of growth on unsupplemented whey consisted of Candida parapsilosis and Lactobacillus paracasei. Fermentation kinetic profiles suggested that peptides were released from alpha-la hydrolysis. The co-culture of both microorganisms was required for alpha-la hydrolysis that occurred concomitantly with the pH decrease. During whey fermentation, Cand. parapsilosis excrete at least one protease responsible for alpha-la hydrolysis, and Lb. paracasei is responsible for medium acidification that is required for protease activation.     

A space-exact beam element for time-dependent analysis of composite members with discrete shear connection

This paper presents a space-exact, time-discretized solution for the time-dependent analysis of composite beams with partial interaction. The time effects considered in this model are creep and shrinkage of the concrete slab. The constitutive model adopted to describe the time effects is linear viscoelasticity with time-dependent coefficients to account for ageing. By using the time-discretized form of the constitutive relations, the equilibrium equations in terms of the displacements at a generic instant are analytically solved. Based on the analytical expressions (exact in space) of the displacements and the internal forces, the space-exact stiffness matrix is deduced for a generic composite beam element. This stiffness matrix can be used in a displacement-based procedure for the time-analysis of continuous composite steel-concrete beams with arbitrary support and loading conditions. The present formulation requires a minimum number of elements depending on the support and loading conditions. The proposed hybrid analytical-numerical method is used to investigate both the short-term and the long-term deflections of simply supported composite beams in order to assess the calculation method proposed in Eurocode EN 1994-1-1 [21]. The effects of creep, shrinkage and degree of shear connection on the deflection of simply supported composite beams are also analyzed. The long-term deflection calculated with the analytical model based on the rules given in EN 1994-1-1 [21] is compared against the one predicted by the proposed model. It is found that EN 1994-1-1 [21] slightly underestimate the long-term deflection. It was also observed that the contribution of shrinkage to the deflection is more significant than suggested in EN 1994-1-1 [21].     

The Seine system: introduction to a multidisciplinary approach of the functioning of a regional river system

The Seine basin (France) is dominated by the megalopolis of Paris (10 millions inhabitants), surrounded by intensive agricultural areas: it represents an important example of regional territory strongly affected by anthropogenic activity. In the scope of the PIREN-Seine program, an interdisciplinary study of this basin was conducted. This paper introduces a special issue of the Science of the Total Environment devoted to the results of this program. It summarizes the main features of the Seine river system, the physical characteristics of its drainage network and its watershed, and the nature and spatial distribution of human activities. The scientific approaches used for the study of the system are described, emphasizing the role of material budgeting, mathematical modeling and historical reconstruction. Some functional characteristics of the Seine watershed and drainage network are summarized, showing that the system is now essentially controlled by anthropogenic constraints.     

Tensile and water barrier properties of cassava starch composite films reinforced by synthetic zeolite and beidellite

Composites films were prepared by the casting method using native cassava starch plasticized with glycerol and 3D or 2D synthetic fillers i.e. Beta zeolite and Na-beidellite type 2:1 phyllosilicate. Special attention was paid to the effect of the filler contents and type on the mechanical and barrier properties. It was shown that films reinforced with lyophilized Beta zeolite presented both high water solubility (WS) and water vapor permeability (WVP) values than the pristine starch whereas an improvement on the WVP was found for composites prepared from Na-beidellite or from non lyophilized Beta zeolite. For the two types of fillers, a drastic increase of the mechanical properties (especially in the Young’s modulus) was observed.