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排序方式: 共有458条查询结果,搜索用时 15 毫秒
31.
Lubricant films containing colloidal overbased calcium salts have particular effects on detergency and on the wear process. The mechanical properties of such boundary films are very dependent on the process conditions, and are essentially a result of physico-chemical transformations of the colloid. Three types of films were compared: a film obtained by the drying of the base solvent, a film due to the compaction of the colloid between two steel surfaces, and a friction film obtained with this type of lubricant. Adsorption, compaction, and shear transformations induce a solid film. The pressure effect on the frictional behaviour of these colloidal films has been investigated using a surface force apparatus for low contact pressure (104 to 106 Pa), and using tribometers supporting heavy loads for the analysis of the high pressure domain. Above a critical pressure, evaluated at 106 Pa, the colloidal film does not flow, but forms a compacted mattress sliding on the surface plane and squeezing a molecular layer of lubricant. 相似文献
32.
In the field of research for Severe Accidents of PWRs, calculation results are needed to estimate when corium achieves basemat melt-through. In this framework, knowledge of the heat transfer coefficient as well as the temperature at the interface between the melt and the solid are key issues. It has been previously emphasized that physico-chemistry of the melt (composition) affects the temperature. However, the effect of gas sparging and liquid concrete release on the mechanical stability of the solid layer and on the interface temperature has not been analysed in detail. ARTEMIS 1D tests were launched to analyse the phenomenology at the interface. A general conclusion for all these tests is that a solid medium enriched in refractory species exists at the interface between the pool and the concrete.Tests 2 and 6, which are close to reactor representative conditions, could be well described with the assumption Tinterface = Tliquidus. The analysis of tests 3 and 4 revealed that the interfacial medium is thicker by a factor of 4-5 times than calculated with the assumption of pure conduction heat transfer. Detailed analysis leads to the conclusion that the interfacial medium is made of a porous layer of refractory particles embedded in a liquid phase. The liquid density difference, between the porous medium and chimneys, results in recirculation of the liquid in the porous layer. This recirculation is responsible for a convective contribution to heat transfer through the porous layer. The convective heat flux is partly linked to cooling of the recirculating liquid, but also to its partial solidification. The solidification results in gradual plugging and enrichment of the porous layer in refractory species and in the increase of the resistance to heat transfer. The phenomena have been modelled and ARTEMIS tests 3 and 4 are well reproduced. The complete plugging of the porous medium, associated with thermodynamic equilibrium at the interface between the solid medium and the pool leads naturally to the solid crust model implemented in TOLBIAC-ICB. The latter model appears, thus, as a simplification of the porous medium approach described here.Thick interfacial layers, which have composition between refractory and corium mixture, have been observed in ACE and MACE tests with LCS (Limestone-Common Sand) or Limestone concrete and can be explained with the proposed model approach. For siliceous concrete, convection within a porous medium is not possible due to the large viscosity. 相似文献
33.
Gorce JM Friboulet D Dydenko I D'hooge J Bijnens BH Magnin IE 《IEEE transactions on ultrasonics, ferroelectrics, and frequency control》2002,49(12):1704-1719
Spectral estimation is a major component in studies aiming at characterizing biological tissues through the analysis of backscattered radio frequency (RF) ultrasonic signals and images. However, conventional spectral estimation techniques yield a well-known trade-off between spatial resolution and variance. The backscattered signals are stochastic by nature, so short-term local analysis results in a high variance of the estimates, which cannot efficiently be reduced through conventional spatial averaging. We address this issue by describing a spectral estimation technique that reduces the variance of the estimates (by smoothing the local estimates in spectrally homogeneous regions) while preserving spectral discontinuities (i.e., the smoothing is not performed across regions with different spectral contents). The proposed approach is set in a Bayesian framework and is based on local autoregressive (AR) estimation, constrained by smoothness priors. These smoothness priors are introduced through a Markov random field in which the associated potential functions are nonquadratic, allowing thereby to preserve discontinuity. The method is validated on simulated RF images and tested on echocardiographic images acquired in vivo. The results are compared to the estimates provided by the conventional Burg technique. These results clearly demonstrate the ability of the proposed approach to improve spectral estimation in terms of variance reduction and discontinuity detection. 相似文献
34.
Monfette Marie-Eve; Grimard Fran?ois; Ivers Hans; Blais Marie-Claude; Lavoie Vicky; Boisvert Jean-Marie 《Canadian Metallurgical Quarterly》2006,38(3):261
The popularity of the Fear of Negative Evaluation scale (FNE; Watson & Friend, 1969) stems from the centrality of this construct in personality, social and clinical psychology. In order to meet the needs of the Francophone researchers community, Kéroack, Boisvert, and Prévost (1987) traduced the short version of this instrument. Since social anxiety is most salient in adolescence, there is a need for normative and psychometric data for this population. This research aims at documenting the psychometric properties and norms for Francophone adolescents. Five hundred and seventy-eight participants aged from 14 to 19 years completed the French versions of the short FNE and the Social Avoidance and Distress scale. The factorial structure, the internal consistency and the convergent validity analyses confirm the traduction's quality and the questionnaire's validity. Norms are presented separately for females and males. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
35.
Francis Gohin Sophie Loyer Michel Lunven Claire Labry Jean-Marie Froidefond Daniel Delmas Martin Huret Alain Herbland 《Remote sensing of environment》2005,95(1):29-46
In biological modelling of the coastal phytoplankton dynamics, the light attenuation coefficient is often expressed as a function of the concentrations of chlorophyll and mineral suspended particulate matter (SPM). In order to estimate the relationship between these parameters over the continental shelf of the northern Bay of Biscay, a set of in situ data has been gathered for the period 1998-2003 when SeaWiFS imagery is available. These data comprise surface measurements of the concentrations of total SPM, chlorophyll, and irradiance profiles from which is derived the attenuation coefficient of the photosynthetically available radiation, KPAR. The performance of the IFREMER look-up table used to retrieve the chlorophyll concentration from the SeaWiFS radiance is evaluated on this new set of data. The quality of the estimated chlorophyll concentration is assessed from a comparison of the variograms of the in situ and satellite-derived chlorophyll concentrations. Once the chlorophyll concentration is determined, the non living SPM, which is defined as the SPM not related to the dead or alive endogenous phytoplankton, is estimated from the radiance at 555 nm by inverting a semi-analytic model. This method provides realistic estimations of concentrations of chlorophyll and SPM over the continental shelf all over the year. Finally, a relationship, based on non living SPM and chlorophyll, is proposed to estimate KPAR on the continental shelf of the Bay of Biscay. The same formula is applied to non living SPM and chlorophyll concentrations, observed in situ or derived from SeaWiFS radiance. 相似文献
36.
Jean-Marie Bourjolly Ozgur Gurtuna Aleksander Lyngvi 《International Transactions in Operational Research》2006,13(5):461-481
The robotic capability of maintaining and repairing space assets, on‐orbit servicing (OOS), has the potential to change the way spacecraft are designed, manufactured and operated. The most common OOS mission concept envisions an orbital “depot”, where consumables and spare parts for spacecraft will be stored. A “servicing platform”, based at this depot, will be used to service a number of client spacecraft and then return to the depot for resupply. We model OOS as a time‐dependent, moving‐target traveling salesman problem and present an algorithm for minimizing the total amount of energy or time required for OOS operations. 相似文献
37.
Chuang Dong Li-Ming Zhang Qing-Gang Zhou Hui-Chen Zhang Jean-Marie Dubois Qiu-Hua Zhang Yao-Chun Fu Fei-Zhou He Fei Ge 《Bulletin of Materials Science》1999,22(3):465-472
The present paper is concerned with a special group of approximants with B2 superstructures. In the first part, recent work
on structural features of the B2 superstructure approximants is summarized. Experimental results obtained in Al-Cu-Mn and
Al-Cu systems are presented, where a series of B2-based approximants are observed. These phases all have similar valence electron
concentrations, in full support of thee/a-constant definition of approximants. Special emphasis is laid on the chemical twinning modes of the B2 basic structure in
relation to the Al-Cu approximants. It is revealed that the B2 twinning mode responsible for the formation of local pentagonal
atomic arrangements is of 180°/[111] type. This is also the origin of 5-fold twinning of the B2 phase on quasicrystal surfaces.
Crystallographic features of phases B2, τ2, τ3,γ, and other newly discovered phases are also discussed. In all these phases, local pentagonal configurations are revealed.
In the second part, dry tribological properties of some AlCuFe samples containing the B2-type phases are presented. The results
indicated that the B2 phase having their valence ratio near that of the quasicrystal possesses low friction coefficient under
various loads, comparable with the annealed quasicrystalline ingot. Such a result indicates that the B2-type phase withe/a near that of quasicrystal is indeed an approximant, which is in full support of the valence electron criterion for approximants. 相似文献
38.
Jean-Marie Piot Didier Guillochon Danielle Leconte Daniel Thomas 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1988,42(2):147-156
Many uses of protein hydrolysates have been developed and applied to areas such as nutritional therapy, culture media, and the isolation of biologically active peptides. All these applications need carefully controlled and characterized hydrolysates. In order to produce such a type of hydrolysate, it is possible to use haemoglobin which is a very well defined and constant protein source. Enzymic hydrolysis of haemoglobin by pepsin was carried out at pilot-plant scale in an ultrafiltration reactor with mineral membranes. The object was to obtain a reproducible, decolorized, salt-free enzymic hydrolysate. Two types of membranes were tested having 10000 dalton (M5 type) and 20000 dalton (M4 type) cut-offs. Little significant difference was observed in the final products when both types of membranes were used. Reproducibility of hydrolysates was verified by amino acid analysis and gel filtration chromatography. The haemoglobin hydrolysates produced contained more than 90% protein and are especially suitable for fine applications. 相似文献
39.
This paper investigates the different approaches that best retrieve band shape parameters and kinetic time constants from series of protein Fourier transform infrared (FT-IR) spectra recorded in the course of 1H/2H exchange. In this first approach, synthetic spectra were used. It is shown that 1H/2H exchange kinetic measurements can help resolve spectral features otherwise hidden because of the overlap of various spectral contributions. We evaluated the efficiency of Fourier self-deconvolution, synchronous/asynchronous correlation, difference spectroscopy, principal component analysis, inverse Laplace transform, and determination of the underlying spectra by global analysis assuming first-order kinetics with either known or unknown time constants. It is demonstrated that some strategies allow the extraction of both the time dependence and the spectral shape of the underlying contributions. 相似文献
40.
The biodegradability of water samples is usually estimated with bioassays under oxic conditions. In order to overcome some of the drawbacks linked to the incubation of the samples in aerobic batches, a new protocol is proposed and tested, which is based on an organic carbon (OC) balance after a 45 days incubation under anoxic conditions with excess nitrate. The biodegradable fractions of organic matter obtained with the anoxic protocol are slightly lower than those obtained under oxic conditions. Several possible reasons for a systematic underestimation of the biodegradable organic matter under anoxic conditions are evaluated and discussed: a reduced microbial metabolic potential, significantly reduced degradation rates for the slowly biodegradable organic matter, an additional production of refractory organic compounds during the incubation, or the inhibition of the recycling of the organic matter stored in bacterial biomass. Nevertheless, the 7% difference observed on the biodegradable total OC estimations keeps low enough so that the anoxic protocol can be proposed as a convenient alternative to the oxic one. 相似文献