In-plane rigid-body vibration mode characterization with a nanometer resolution by stroboscopic imaging of a microstructured pattern

This article introduces an improved approach for the characterization of in-plane rigid-body vibration, based on digital processing of stroboscopic images of the moving part. The method involves a sample preparation step, in order to pattern a periodic microstructure on the vibrating device, for instance, by focused ion beam milling. An image processing method has then been developed to perform the optimum reconstruction of this a priori known object feature. In-plane displacement and rotation are deduced simultaneously with a high resolution (10-2 pixel and 0.5 x 10(-3) rad, respectively). The measurement principle combines phase measurements-that provide the high resolution-with correlation-that unwraps the phase with the proper phase constants. The vibration modes of a tuning fork are used for demonstrating the capabilities of the method. For applications allowing the sample preparation, the proposed methodology is more convenient than common interference methods or image processing techniques for the characterization of the vibration modes, even for amplitudes in the nanometer range.     

In Situ TEM Observation of the Behavior of an Individual Fullerene-Like MoS<Subscript>2</Subscript> Nanoparticle in a Dynamic Contact

Inorganic fullerene-(IF)-like nanoparticles made of metal dichalcogenides (IF-MoS₂, IF-WS₂) have been known to be effective as anti-wear and friction modifier additives under boundary lubrication. The lubrication mechanism of these nanoparticles has been widely investigated in the past and even if the exfoliation and third body transfer of molecular sheets onto the asperities constitute the prevalent mechanism for the improved tribological behavior of IF nanoparticles, it has also been suggested that a rolling friction process could also play a role for well crystallized and spherical particles. In this study, in situ Transmission Electron Microscopy (TEM) observations of the behavior of single IF-MoS₂ nanoparticles were conducted using a sample holder that combines TEM and Atomic Force Microscopy (AFM) which simultaneously can apply normal and shear loads. It was shown that depending on the test conditions, either a rolling process or a sliding of the fullerenes could be possible. These in situ TEM observations are the first carried out with IF nanoparticles.     

Zinc Dialkyl Phosphate (<Emphasis Type=Bold>ZP</Emphasis>) as an Anti-Wear Additive: Comparison with <Emphasis Type=Bold>ZDDP</Emphasis>

In this study, we are interested in the anti-wear properties of zinc dialkyl phosphate additive (ZP) in comparison with ‘classical’ zinc dialkyldithiophosphate (ZDDP). Friction tests were performed on a reciprocating tribometer using both ball-on-flat and cylinder-on-flat configurations under a Hertzian contact pressure of 0.9 GPa. Experiments were carried out as a function of temperature (25 and 100 °C), sliding speed (25, 50 and 100 mm/s) and additives concentrations. Ball wear scar diameters as well as friction coefficient were measured. In order to better understand the anti-wear mechanisms of these additives, friction tests were followed by surface analyses such as AES (Auger Electron Spectroscopy) and XPS (X-Ray Photoelectron Spectroscopy). Transmission Electron Microscopy (TEM) observations of the ZDDP and ZP tribofilms were also carried out to visualise the generated layers. The anti-wear capability of ZP molecule is discussed.     

Searching for information in an online public access catalogue (OPAC): the impacts of information search expertise on the use of Boolean operators

Abstract Boolean systems still constitute most of the installed base of online public access catalogues (OPACs) in the French universities even if many studies have shown that Boolean operators are not frequently used by ‘non‐librarian’ users (by contrast with professional librarians). The first study examined the use of Boolean operators by French university students; In the second study, elaborated to evaluate the impact of information search expertise on this use, Boolean operators are explicitly presented and participants were explicitly invited to use them. We assumed that university students would not frequently use the operators in searching, and that even if they were explicitly invited to make use of them. Results obtained with the first study based on transaction logs analyses confirmed that French university students did not frequently use Boolean operators. The impact of information search expertise, analysed in the second study, compared three levels of expertise: Novice (university students), intermediate (future professional librarians), and expert (professional librarians). Results showed that, even if the three groups were invited to use Boolean operators, this use increased significantly with the level of information search expertise. University students, if they manage procedural functions of connectives in natural language, do not always manage the whole set of procedural functions carried by such connectives when used in the documentary language. So, the relevance of presenting explicit Boolean operators in the OPACs when users are ‘non‐librarians’ is questioned.     

Class D amplifier for a power piezoelectric load

We present a high efficiency inverter (>90%) that can drive an acoustic cavitation reactor with a 2 kW power between 10 and 100 kHz. This reactor is composed of numerous piezoelectric transducers and is particularly used to accelerate various industrial chemical reactions and destroy a variety of organic contaminants in water. The class-D amplifier or inverter is composed of power MOSFETs, type IRFP460, in a full bridge configuration driven by IR2110 circuits in bootstrap mode. The specific nature of the problem comes from the fact that, at frequencies slightly different from a resonant frequency frn, the load is mostly capacitive. The insertion of an appropriate low-pass filter in front of the load allowed an efficient solution to the problem due to the load being capacitive for harmonics. The realized system can provide nearly 2 kW to this type of piezoelectric load, with an efficiency of more than 95%     

Mass Spectrometry Based Metabolomics to Identify Potential Biomarkers for Resistance in Barley against Fusarium Head Blight (<Emphasis Type="Italic">Fusarium graminearum</Emphasis>)

Resistance in Triticeae to fusarium head blight (FHB) is quantitatively inherited. Metabolomics as a tool was used to better understand the mechanisms of resistance and to identify potential FHB resistance biomarker metabolites in barley. Five FHB-resistant two-row barley genotypes (CIho 4196, Zhedar-1, Zhedar-2, Fredrickson, and Harbin-2r) and one FHB-susceptible genotype (CH 9520–30) were each inoculated with either pathogen-suspension or mock-solution. Disease severity, quantified as the proportion of spikelets diseased, varied among genotypes, being the greatest in CH 9520–30. Spikelets were sampled, metabolites extracted with aqueous methanol, and analyzed using an LC-ESI-LTQ-Orbitrap system. A pair wise, resistant vs. susceptible, t-test identified 1774 significant treatment peaks. Canonical discriminant analysis of peak abundance allowed the genotypes to be sorted into three clusters: (i) CH9520-30, (ii) Harbin-2r, (iii) the remaining four genotypes. The t-test was further used to identify resistance-related (RR) and pathogenesis-related (PR) metabolites. The pathogen-produced virulence factor deoxynivalenol (DON), and its detoxification product, DON-3-O-glucoside (D3G) were designated as resistance indicator (RI) metabolites. Metabolites (RR, PR, or RI) occurring in at least two resistant genotypes, showing a two-fold or greater abundance in resistant vs. susceptible lines, and also known to have plant defense functions were selected as potential FHB resistance biomarker metabolites. These included phenylalanine, p-coumaric acid, jasmonate, linolenic acid, total DON produced (TDP), and the proportion of DON converted to D3G (PDC). Total DON was the lowest in CIho 4196, while PDC was the highest in Zhedar-2. The application of RR, PR, and RI metabolites as potential biomarkers to enhance resistance is discussed.     

Performance analyses of VHTR plants with direct and indirect closed Brayton cycles and different working fluids

This paper investigated the performance of Very High Temperature Reactor (VHTR) power plants with helium working fluid and direct and indirect Closed Brayton Cycles (CBCs), and with binary mixture working fluids of He–Xe and He–N₂ (molecular weight of 15 g/mole) and indirect CBCs. Also investigated are the effects of using low- and high-pressure compressors with intercooling, versus a single compressor, using bleed cooling the reactor pressure vessel in direct CBC helium plants, and varying the reactor exit temperature from 700 °C to 950 °C on the plant thermal efficiency, cycle pressure ratio and the size of and number of stages in the turbine and compressor. Analyses are performed for a shaft rotation speed of 3000 rpm, reactor thermal power of 600 MW and a temperature pinch of 50 °C in the intermediate heat exchanger (IHX) for the indirect CBCs.     

Web-conference supervision for advanced psychotherapy training: A practical guide.

The advent of readily accessible, inexpensive Web-conferencing applications has opened the door for distance psychotherapy supervision, using video recordings of treated clients. Although relatively new, this method of supervision is advantageous given the ease of use and low cost of various Internet applications. This method allows periodic supervision from point to point around the world, with no travel costs and no long gaps between direct training contacts. Web-conferencing permits face-to-face training so that the learner and supervisor can read each other's emotional responses while reviewing case material. It allows group learning from direct supervision to complement local peer-to-peer learning methods. In this article, we describe the relevant literature on this type of learning method, the practical points in its utilization, its limitations, and its benefits. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Effects of club size in the provision of public goods. Network and congestion effects in the case of the French municipalities

The article formalizes and measures the impact of club size on the quality of the public good provided to its members. Under a general framework we describe various functional forms that allow either network or crowding effects. Mechanisms of provision are that of a political process in which both the demand and the supply sides are considered. Estimations use the whole set of French municipalities. The supply model performs better than the demand model in the case of small municipalities, while for large cities the demand model has higher explanatory power. In so far as impact of city size on the quality of club goods is concerned, crowding does appear, but it does so in different patterns. For small towns marginal congestion first decreases then increases with population. Marginal congestion is decreasing for cities of intermediate size. For larger cities no significant effects are observed. Received: 27 June 2000 / Accepted: 20 August 2001 RID="*" ID="*" We have received particularly helpful comments from the editor-in-chief and two anonymous referees. We also thank Danièle Moret-Bailly for her friendly computational assistance.