DIVA: Recognition of typical situations for turbine generator diagnosis

DIVA is an expert system for turbine generator diagnosis. Its aim is to help a plant operator interpret vibration evolution to diagnose developing faults. Interpretation of vibration evolution is primarily a recognition process which is achieved by a particular model of heuristic classification. DIVA tries to recognize the observed situation among a hierarchy of typical situations.The purpose of this paper is to present the model we used for heuristic classification, based on prototypes. Prototypes represent typical problem situations and may also be seen as experts with special knowledge of what to do in such situations. We argue that this model presents significant advantages to deal with complex problems such as vibration surveillance.     

Two C60O Structures and Their Relative Stabilities: AM1 Computations

C₆₀O is studied by means of the AM1 quantum-chemical method. Full geometry optimization of its C_s and C_2v structures, and harmonic vibrational analysis, are employed in the evaluation of the temperature dependence of their relative stabilities. The C_2v structure remains a minor component of the equilibrium gas-phase mixture even at high temperatures.     

Species-specific composition of free amino acids on the leaf surface of fourSenecio species

The specificity of the chemical composition of the leaf surface of fourSenecio species was studied in order to understand the host selection ofTyria jacobaeae, a monophagous moth that hasSenecio jacobaea as its principal host plant. Pyrrolizidine alkaloids characteristic forSenecio species were not detected in water and sulfuric acid extracts of the leaf surface ofSenecio jacobaea. Water extracts of the leaf surfaces ofS. jacobaea, S. vulgaris, S. viscosus, andS. sylvaticus contained low concentrations of free amino acids. The proportions of these amino acids were very different from those inside the leaf tissues. In a discriminant analysis, the four species could be completely separated on the basis of the relative proportions of amino acids on the leaf surface.     

Periodes et repetitions des mots du monoide libre

We study the relationship between the global periodicity of a word and its (local) repetitions, that is to say its successive equal factors.Our main result generalizes the theorem of Cesari Vincent according to which the period of a word is the maximum of the minimal repetitions. Our generalization is twofold, it does not take account of any sides to define repetitions (the above result does) and calculates the maximum only on a special set of points. It allows a sharpened version of the solution to a problem settled by Schützenberger in which the theorem of Cesari Vincent originates.     

Autoirradiation d'un alliage cubique centre uranium-plutonium-molybdene

Measurements have been made of the length changes due to self-irradiation damage at 4.2 K for over 1300 h in a U-Pu-Mo bcc alloy (containing 20 at% plutonium and 15 at% molybdenum) stabilized by quenching. These are the first measurements of this type carried out on a bcc alloy. The initial rate of increase of δl/l was $\text{2,3 × 10}{}^{\mathrm{?7}}\text{h}{}^{\mathrm{?1}}$ If it is assumed that each α desintegration forms 1800 Frenkel pairs, it is found that Frenkel pairs have a formation volume equal to 0.5 atomic volume.     

Polymorphisme de l'hydrure de magnesium sous haute pression

The structural relationships in magnesium hydride have been studied under P-T conditions up to 80 kbar and 900°C. α-MgH₂ of rutile structure in normal conditions transforms into two new phases under high pressures : β-MgH₂ and γ-MgH₂ respectively with a hexagonal (pseudocubic) and an orthorhombic unit-cell structure·β-MgH₂ maybe related to a fluorite type form (with an eight-coordination for Mg) transforming when releasing pressure into γ-MgH₂ of α-PbO₂ type (with a six-coordination for Mg). The density of α-MgH₂ and γ-MgH₂ are very similar but the density of the β-MgH₂ fluorite form is some 25 % greater than that of the rutile type. Thus MgH₂ seems to exhibit under high pressure conditions the typical behavior of number of rutile type compounds MX₂ such as fluorides or oxides.     

Influence de la pression partielle d'oxygene sur la nature des defauts ponctuels dans Ca2LaFe3O8+x

The type of point defects in non-stoichiometric Ca₂LaFe₃O_8+x ferrite has been studied by measuring the variation of electrical conductivity with oxygen partial pressure at various temperatures. Several ordering possibilities occur. The oxygen atoms inserted, mostly 1-charged, have a strong tendency to couple at sufficient oxygen pressure and at low temperature. Interstitial oxygen atoms in the lattice vacancies induce structural evolution as non-stoichiometry becomes significant enough.     

Characterization of toxins within crude venoms by combined use of Fourier transform mass spectrometry and cloning

The standard analytical procedure for screening the proteomic profile of a venom often relies on an appropriate combination of sample extraction, electrophoresis, reversed-phase high-performance liquid chromatography, mass spectrometry, and Edman degradation. We present in this study a new approach for venom screening based on Fourier transform mass spectrometry (FTMS) analysis directly on the crude venom. The venom chosen is a unique sample from Atractaspis irregularis, a species never studied at the molecular level previously. This snake belongs to the Atractaspidae family that is known to produce highly toxic venoms containing endothelin-like peptides called sarafotoxins (SRTXs). Nanoelectrospray-FTMS spectrum of the crude venom allowed the identification of 60 distinct compounds with molecular masses from 600 to 14,000 Da, which would have been impossible without the resolution of this kind of instrument. De novo sequencing within the entire venom confirmed the sequences of two new families of sarafotoxins, whose precursors had been cloned, and allowed the characterization of a third one. One particularly interesting point was that the propolypeptides appeared processed not in one unique compound, but rather in different length molecules ranging from 15 for the shorter to 30 amino acids for the longer. Moreover, our results clearly establish that in the case of A. irregularis only one copy of mature sarafotoxin emerges from each precursor, which is a totally different organization in comparison of other precursors of SRTXs.