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81.
82.
Maryse Demuynck Jean-Pierre Erauw Omer Van der Biest Francis Delannay Francis Cambier 《Journal of the European Ceramic Society》2012,32(9):1957-1964
In this study, the densification of alumina by spark plasma sintering (SPS) was investigated and compared to conventional hot pressing. It was shown that SPS is very effective in the sintering of alumina leading to higher densities and allows to work at lower temperatures and with shorter sintering cycles. The effect of the heating rate is dependent on the heating mode (SPS or HP). The identification of active sintering mechanisms was attempted by an isothermal and an anisothermal methods, showing that other mechanisms probably related to electrical effects enhance the densification. We suggest the higher contribution of surface diffusion mainly during the initial stage of sintering and an influence of the presence of impurities segregated at the grain boundaries. They could create conductive layers and also introduce ions with a lower valence than Al3+; defects are created in the surface layers and the diffusion of the species is increased. 相似文献
83.
Chrystelle Le Danvic Gaelle Guiraudie-Capraz Djamel Abderrahmani Jean-Pierre Zanetta Patricia Nagnan-Le Meillour 《Journal of chemical ecology》2009,35(7):741-751
Knowledge of endogenous ligands of olfactory binding proteins is a prerequisite for studying their role in odor and pheromone
transduction. Here, we report the extraction, derivatization, and characterization by gas chromatography-mass spectrometry
of the natural ligands of pig, Sus scrofa (L.), Von Ebner’s Gland protein (VEG) and odorant binding protein (OBP). We identified two isoforms (VEG1 and VEG2), which
differed only by the linkage of an O-N-acetylglucosamine (O-GlcNac) group on VEG1. The natural ligands of VEG1 were characterized as two isomers of testosterone, whereas ligands of
VEG2 and OBP were fatty acids or their derivatives. Our findings suggest that the binding specificity of VEG1 for steroids
is governed by the presence of an O-GlcNac moiety on the protein. This specificity was confirmed by the binding of radiolabeled testosterone only by VEG1 in
an in-gel binding assay. This is the first evidence for a post-translational modification in the process of odorant discrimination
by olfactory binding proteins. 相似文献
84.
85.
Magaly Caillon-Caravanier Jennifer Jones Frédéric Montigny Jean-Pierre David Daniel Lemordant 《Journal of power sources》2010,195(2):614-620
Lithium-ion batteries for space applications, such as satellites, are subjected to cosmic radiations, in particular, γ-irradiation. In this study, the effects of this radiation on electrolytes and their components used in the lithium-ion batteries are investigated. The conductivity and viscosity of the samples have been measured before and after the irradiation. The modifications are evaluated by spectral analyses such as Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (1H and 13C NMR), solid phase microextraction-gas chromatography (SPME-GC) and gas chromatography-mass spectroscopy (GC-MS). The experimental results show that only the samples containing vinylene carbonate and/or the lithium salt LiPF6 are degraded by γ-radiation. 相似文献
86.
Thomas Unfer Jean-Pierre Boeuf François Rogier 《Computer Physics Communications》2010,181(2):247-1019
The breakdown of a gas gap at high products of pd (pressure × distance) is a multi-scale phenomenon in both time and space. This is especially true when the plasma is interacting with a gas flow, a problem of considerable recent interest in the context of aerodynamic applications of surface discharges. This paper presents a contribution to the numerical modeling of such discharges. We describe here a new approach for adaptive meshing which is suitable for use with the explicit asynchronous integration scheme described in our previous publication. Rather than relying on a family of nested grids as is commonly done, this technique is based on a single unstructured mesh with possible non-conforming cells at the interface between coarse and fine areas. Substantial computational time saving has been achieved for a surface dielectric barrier discharge configuration of the kind proposed as plasma actuators for flow control. 相似文献
87.
Khuram Shahzad Jan Deckers Jean-Pierre Kruth Jef Vleugels 《Journal of Materials Processing Technology》2013,213(9):1484-1494
Innovative powder preparation and post-processing techniques can be employed to obtain high density ceramic parts by means of indirect selective laser sintering. Thermally induced phase separation (TIPS) was used to produce polymer and polymer–ceramic composite particles. The effect of polymer concentration, cooling rate, stirring and alumina particles on polymer and polymer–ceramic composite particles was investigated. Homogeneous spherical alumina–polypropylene (PP) composite powder was synthesized by TIPS for selective laser sintering (SLS). Green Al2O3–PP component parts with a density of 34% could be produced by conventional SLS of the polymer under optimized laser power, scan speed, scan spacing and powder preheating temperature. Various post-processing techniques like pressure infiltration (PI), warm isostatic pressing (WIPing) or a combination of both were applied to increase the green density of the Al2O3–PP SLM parts. Infiltrating the open porosity green SLS parts with a 30 vol% alumina-powder based ethanol suspension allowed to increase the sintered density, i.e. after polymer debinding and pressureless sintering in air at 1600 °C, from 38 to 64% of the theoretical density (TD). WIPing of the SLS and SLS/infiltrated green parts at 135 °C and 64 MPa allowed raising the green density up to 93 and 83% TD and a sintered density up to 89 and 88% TD, respectively. 相似文献
88.
89.
Pierre Abel Pascal Gros Didier Loisel Cristina Russo Dos Santos Jean-Pierre Paris 《电信纪事》2000,55(3-4):131-142
In this paper we will present CyberNet, an interactive 3D dynamic information visualization tool designed to evaluate the added value this technology brings to network management. This paper explains how 3D metaphoric worlds may help the user and points out the problems raised by the dynamic nature of the information. It focuses on the solutions that were adopted to cope with these problems. We first present some prototypes of network administration tools implemented using the CyberNet framework. Secondly we explain how information is collected and structured, and then we show how this structured information may be mapped onto 3D graphical components in order to automatically build and update metaphoric 3D worlds. The last part of the paper presents the user interaction mechanisms provided by the system. 相似文献
90.
Charlotte Bernard Jean-Pierre Aimé Sophie Marsaudon Raphaël Levy Anne Marie Bonnot Cattien Nguyen Denis Mariolle François Bertin Amal Chabli 《Nanoscale research letters》2007,2(7):309-318
Evaporation of fluid at micro and nanometer scale may be used to self-assemble nanometre-sized particles in suspension. Evaporating
process can be used to gently control flow in micro and nanofluidics, thus providing a potential mean to design a fine pattern
onto a surface or to functionalize a nanoprobe tip. In this paper, we present an original experimental approach to explore
this open and rather virgin domain. We use an oscillating tip at an air liquid interface with a controlled dipping depth of
the tip within the range of the micrometer. Also, very small dipping depths of a few ten nanometers were achieved with multi
walls carbon nanotubes glued at the tip apex. The liquid is an aqueous solution of functionalized nanoparticles diluted in
water. Evaporation of water is the driving force determining the arrangement of nanoparticles on the tip. The results show
various nanoparticles deposition patterns, from which the deposits can be classified in two categories. The type of deposit
is shown to be strongly dependent on whether or not the triple line is pinned and of the peptide coating of the gold nanoparticle.
In order to assess the classification, companion dynamical studies of nanomeniscus and related dissipation processes involved
with thinning effects are presented. 相似文献