Three‐Dimensionally Ordered Macroporous Polymeric Materials by Colloidal Crystal Templating for Reversible CO2 Capture

The design and preparation of porous materials with controlled structures and functionalities is crucial to a variety of absorption‐ or separation‐relevant applications, including CO₂ capture. Here, novel functional polymeric materials with three‐dimensionally ordered macroporous (3DOM) structures are prepared by using colloidal crystals as templates using relatively simple, rapid, and inexpensive approaches. These ordered structures are used for the reversible CO₂ capture from ambient air by humidity swing. Typically, the colloidal crystal template is synthesized from polymer latex particles of poly(methyl methacrylate) (PMMA) or polystyrene (PS). To maintain the functionality of the material, it is important to prevent the porous structure collapsing, which can occur by the hydrolysis of the ester bonds in conventional crosslinkers under basic conditions. This hydrolysis can be prevented by using a water‐soluble crosslinker containing two quaternary ammonium moieties, which can be used to prepare stable porous crosslinked polymers with the monomer (vinylbenzyl)trimethylammonium chloride (VBTMACl) and using a PMMA‐based colloidal crystal template. The hydroxide‐containing monomer and dicationic crosslinker are synthesized from their chloride precursors, avoiding the ion‐exchange step which causes shrinkage of the pores. An analysis of different methods for infiltrating the monomer solution into the colloidal crystal template shows that infiltration using capillary forces leads to fewer defects than infiltration under a partial vacuum. In addition, functional macroporous films with micrometer thickness are prepared from a template of PS‐based colloidal crystals in a thin film. In general, the colloidal crystal templated materials showed improved CO₂ absorption/desorption rates and swing sizes compared to a commercially available material with similar functional groups. This work could easily be extended to create a new generation of ordered macroporous polymeric materials with tunable functionalities for other applications.     

Cyclopentadithiophene–benzothiadiazole oligomers: Synthesis via direct arylation,X-ray crystallography,optical properties,solution casted field-effect transistor and photovoltaic characteristics

This article reports the synthesis, crystallographic structure and OFET and OPV performance of the conjugated oligomer of cyclopentadithiophene (CPDT) with benzothiadiazole (BT). Synthesis of the oligomer composed of the CPDT-BT-CPDT sequence is accomplished using direct arylation reactions. Theoretical and experimental X-ray single crystallography confirms that two CPDT-BT-CPDT molecules are not entirely disordered, but are actually stacking directly across each other at the central BT units with an intermolecular distance of 3.61 Å, providing valuable insight into the polymer bulk structure. The performance of the oligomer in OFET devices is investigated by fabricating bottom gate top contact devices and demonstrates a hole mobility of 5.0 × 10⁻³ cm² V⁻¹ s⁻¹. OPV devices of the oligomer blended with PC₆₁BM and PC₇₁BM show power conversion efficiency (PCE) of 1.61%. One potential use for the oligomer could be as a sensitiser in a ternary blend with P3HT–PC₆₁BM or PCPDTBT–PC₆₁BM OPVs; the PCE can be relatively increased by 3–9% depending on concentration, primarily as a result of increased short circuit current density.     

Impact of the injection‐level‐dependent lifetime on Voc,FF, ideality m,J02, and the dim light response in a commercial PERC cell

The injection‐level‐dependent (ILD) lifetime of the silicon wafer impacts many characteristics of the final photovoltaic cell. While efficiency is commonly understood to be impacted by the silicon bulk lifetime (at the maximum power point injection level), this work demonstrates the wide ranging impacts of ILD lifetime on the V_oc, the fill factor (FF), the diode ideality factor m, and the dim light response. Instead of a two‐diode model, we utilize a boundary + ILD bulk lifetime model to analyze a commercial passivated emitter rear contact (PERC) cell featuring an AlO_x dielectric rear passivation. The ILD lifetime is directly measured and used to calculate the bulk recombination current across injection levels. With this boundary + ILD lifetime model, we demonstrate the role of the ILD lifetime on many cell parameters in this PERC cell. For most high efficiency commercial p‐type monocrystalline solar cells, the typically lower bulk lifetime at the maximum power point versus the lifetime at the open circuit point reduces the measured FF and pseudo‐FF. This work illustrates that for a commercial PERC cell with AlO_x rear passivation, the ILD lifetime is the primary mechanism behind reduced FF, ideality factors greater than 1, and the source of the J₀₂ term in the two‐diode model. The crucial implications of this work are not only to better understand commercial PERC cell loss mechanisms but also to encourage a focus on different metrics in cell diagnostics. One such metric is the V_oc at 0.1 or 0.05 suns. Copyright © 2016 John Wiley & Sons, Ltd.     

Thermal sensor allocation for 3DICs using three dimensional thermal sensors

Stacking active layers leads to increased power density and overall higher temperatures in a three dimensional integrated circuit (3DIC). Thermal sensors are therefore crucial for run-time thermal management of 3DICs. A thermal sensor allocation method customized for 3DICs that utilizes ring oscillator based 3D sensors is introduced in this paper. A new 3D thermal map modeling method that facilitates efficient and very fast analyses is embodied in this thermal sensor distribution algorithm. Our results indicate that for a 4-layer stacked 3DIC, consisting of two layers of quad-core processors and one layer of L2 cache and one layer of main memory, less than 3.58% in maximum sensor reading error can be accomplished with a 53× speedup in the thermal evaluation time and thermal sensor distribution algorithm implementation.     

使用TPS62200作为OMAP1510的动态电压缩放器

毫无疑问的,延长便携式电子产品之电池使用寿命将有助于该产品的销售。对微处理器而言,降低内部时脉频率或降低核心电压均有助于降低其功率消耗。动态电压缩放(Dynamicvoltage scaling, DVS)技术常用来降低核心电压以降低功率消耗。本文将说明如何使用TPS62200降压型转换器来实现动态电压缩放技术并作为OMAP1510处理器之电源。下式说明了使用TI-DSP核心之微处理器的功率消耗计算方式:PC ～ (VC)2 × f其中PC代表核心功率消耗,VC为核心电压,f则为核心时脉频率。OMAP1510处理器具有两种操作模式:AWAKE(唤醒)模式以及低功耗的DE…     

CompactPCI系统管理

~~CompactPCI系统管理@Jeff Munch$凌华科技!技术长暨国际PICMG 3.0委员会主席     

News: EPA report targets 10 key research areas

Science.     

A 10-Gb/s laser/modulator driver IC with a dual-mode activelymatched output buffer

A laser/modulator driver IC for 10-Gb/s-SONET OC-192-fiber optic transmitters is described. Depending on the user application, the IC is capable of driving more than 100 mA of current into a laser diode or over 50 mA into an electro-absorption or Mach-Zehnder modulator. Rise and fall times below 20 pS are achieved. The driver employs a novel dual-mode actively matched output buffer that provides a dc-coupled back termination of either 25 or 50 Ω. Compared to an output buffer with a resistive termination, this buffer dissipates only half as much power. In addition, the buffer has the the ability to reject external bias and will therefore not load bias sources used to set laser threshold currents and modulator offset voltages. The low power consumption makes the IC most suitable for co-packaging with uncooled lasers and electro-absorption modulators. The driver is fabricated in a 0.25-μm gate length production GaAs PHEMT process with substrate thru vias, thin-film resistors, and MIM capacitors     

Antenna design strategy and demonstration for software-defined radio (SDR)

Antennas are a key enabling technology for software-defined radio (SDR). Although software is extremely flexible, SDR??s potential is limited by antenna size and performance. In this paper, we review typical antenna miniaturization techniques and fundamental theories that limit antenna size and performance including operational bandwidth, gain (or range), and radiation pattern. Possible antenna design strategies are discussed to meet the desired specifications in SDR based on observations from the limit theories. The application of strategies to enable multiband (resonant), continuous multiband (frequency independent), and instantaneous, ultra-wideband antennas are discussed qualitatively. Advantages, disadvantages, and design trade-off strategies for different types of antennas are compared from a system-level perspective. A design example for a compact ultra-wideband (UWB) antenna is presented for a software-defined platform. The example involves a direct-conversion radio developed in Wireless@VT that uses a Motorola RFIC having a 100 MHz?C6 GHz operational frequency range with a 9 kHz?C20 MHz channel bandwidth. The example antenna covers frequencies from 450 MHz to 6 GHz instantaneously with approximately 5-dBi realized gain over a finite-size ground plane, including return loss and omni-directional coverage.     

系统级封装技术及其应用

本文介绍了系统级封装技术及其兴起背景,对比了与SoC的异同。通过分析系统级封装的技术特点,阐述了其优势;分析了系统级封装的成本构成和特点。本文从集成电路产业链整合的观点,分析了国内系统级封装的机遇与挑战;以长电科技为例,介绍了系统级封装在设计、制造上的关键技术与当前的能力,并分析了未来的趋势和挑战。本丈还对当前的系统级封装产品与应用领域做了详细介绍。