Thermodynamics of hydrogen production by the steam reforming of butanol: Analysis of inorganic gases and light hydrocarbons

The thermodynamics of butanol steam reformation for the production of hydrogen were simulated using a Gibbs free-energy-minimisation method with water–butanol molar feed ratios (WBFR) between 1 and 18, a pressure range of 1–50 bar and reaction temperatures from 300 to 900 °C. The differences in H₂ and CO production were calculated as functions of WBFR and temperature at 1 bar. On the basis of the equilibrium calculations with higher-hydrocarbon compounds excluded, the optimal operating conditions obtained were 600–800 °C, 1 bar and WBFR = 9–12. At these conditions, the yield of hydrogen and carbon monoxide was maximised and methane selectivity minimised. The yield of hydrogen was in the range of 75.13–81.27% (wet basis) with selectivities of 46.20–54.96%. This was achieved at a temperature of 800 °C and WBFR from 9 to 12. Carbon monoxide yield ranged between 65.48 and 55.57% (wet basis), with selectivities ranging from 14.56 to 10.66%. The formation of coke was completely inhibited at these operating conditions. In order to evaluate the effect of methane on coke formation at lower temperatures, simulations were performed in two sets, i.e., primary products (H₂, CO, CO₂ and C) including or excluding methane. The results indicate that some coke can be hydrogenated to methane at 300 °C and WBFR = 3, and that higher pressure favours hydrogenation reactions. Higher pressure had a negative effect on hydrogen and carbon monoxide yields.     

Etched multimode microfiber knot-type loop interferometer refractive index sensor

We propose a novel refractive index sensor based on multimode microfiber knot-type loop (NL) interferometer. The middle portion (~5 cm) of a 15 cm long multimode fiber is etched in 48% hydrofluoric acid to reduce its diameter to ~12 μm. A NL of diameter <1 mm is made from the etched fiber. The ends of etched fiber are spliced with single-mode fibers for launching and detecting light from the NL interferometer. The NL introduces path differences to produce interferometric spectra with free spectral range ~16 nm. The spectrum shifts as the surrounding refractive index of the loop is changed by adding chemicals. We observe the highest sensitivity of the NL interferometer ~172 nm/RIU (refractive index unit) at a refractive index value 1.370 as obtained experimentally using commonly available chemicals. The design could be used as simple, low cost, and highly sensitive biological and chemical sensor.     

Exogenous Spermidine Alleviates Low Temperature Injury in Mung Bean (Vigna radiata L.) Seedlings by Modulating Ascorbate-Glutathione and Glyoxalase Pathway

The role of exogenous spermidine (Spd) in alleviating low temperature (LT) stress in mung bean (Vigna radiata L. cv. BARI Mung-3) seedlings has been investigated. Low temperature stress modulated the non-enzymatic and enzymatic components of ascorbate-glutathione (AsA-GSH) cycle, increased H₂O₂ content and lipid peroxidation, which indicate oxidative damage of seedlings. Low temperature reduced the leaf relative water content (RWC) and destroyed leaf chlorophyll, which inhibited seedlings growth. Exogenous pretreatment of Spd in LT-affected seedlings significantly increased the contents of non-enzymatic antioxidants of AsA-GSH cycle, which include AsA and GSH. Exogenous Spd decreased dehydroascorbate (DHA), increased AsA/DHA ratio, decreased glutathione disulfide (GSSG) and increased GSH/GSSG ratio under LT stress. Activities of AsA-GSH cycle enzymes such as ascorbate peroxidase (APX), monodehydroascorbate reductase (MDHAR), dehydroascorbate reductase (DHAR) and glutathione reductase (GR) increased after Spd pretreatment in LT affected seedlings. Thus, the oxidative stress was reduced. Protective effects of Spd are also reflected from reduction of methylglyoxal (MG) toxicity by improving glyoxalase cycle components, and by maintaining osmoregulation, water status and improved seedlings growth. The present study reveals the vital roles of AsA-GSH and glyoxalase cycle in alleviating LT injury.     

Nanofractionation spotter technology for rapid contactless and high-resolution deposition of LC eluent for further off-line analysis

The development of a contactless postcolumn spotter technology capable of rapidly and accurately depositing LC eluent onto another platform (e.g., 1536-well microtiter plates) is described. Many detection methodologies are suitable for online analysis, such as mass spectrometry, UV-vis, and fluorescence. In some cases, when online analysis is less suitable, off-line postcolumn analysis is the methodology of choice and usually relies on LC-based fractionation prior to detection (e.g., MALDI-MS, Raman spectrsocopy, biochemical assays). As fractionation generally involves loss in resolution, the technology described here allows high-resolution contactless fractionation by tailoring the fractionation frequency to the chromatographic peaks and mixing in of postcolumn reagents. Droplet ejection at frequencies of at least 6 Hz could be performed in the nanoliter to low microliter range with repeatabilities of ～6%. Furthermore, multiple droplets can be ejected at the same position thereby allowing adjustment of fractionation volume and speed. The technology was evaluated, optimized, and validated prior to two proof-of-principle demonstrations comprising off-line chemical detection of injected fluorescein and off-line postcolumn biochemical detection of acetylcholine-binding protein ligands, both based on 1536-well plate reader analysis.     

Potentiometric urea biosensor based on multi-walled carbon nanotubes (MWCNTs)/silica composite material

A novel potentiometric urea biosensor has been fabricated with urease (Urs) immobilized multi-walled carbon nanotubes (MWCNTs) embedded in silica matrix deposited on the surface of indium tin oxide (ITO) coated glass plate. The enzyme Urs was covalently linked with the exposed free –COOH groups of functionalized MWCNTs (F-MWCNTs), which are subsequently incorporated within the silica matrix by sol–gel method. The Urs/MWCNTs/SiO₂/ITO composite modified electrode was characterized by Fourier transform infrared (FTIR) spectroscopy, thermal gravimetric analysis (TGA) and UV–visible spectroscopy. The morphologies and electrochemical performance of the modified Urs/MWCNTs/SiO₂/ITO electrode have been investigated by scanning electron microscopy (SEM) and potentiometric method, respectively. The synergistic effect of silica matrix, F-MWCNTs and biocompatibility of Urs/MWCNTs/SiO₂ made the biosensor to have the excellent electro catalytic activity and high stability. The resulting biosensor exhibits a good response performance to urea detection with a wide linear range from 2.18 × 10^? 5 to 1.07 × 10^? 3 M urea. The biosensor shows a short response time of 10–25 s and a high sensitivity of 23 mV/decade/cm².     

Study of hot electron degradation in submicrometer gate length MOS transistor fabricated with selectively doped substrate engineering

Investigations are made on the performance and hot electron degradation of sub-μm MOS transistors fabricated with an improved selectively doped substrate (SDS) and with the conventional deep punch through implant (DPI) structures. The sub-μm gate length of the transistor was defined by a novel subtractive photolithography technique. The technique is described and the process details are given. The sub-μm transistor performance is characterised by electron mobility, inverse subthreshold slope, substrate sensitivity and drain induced barrier lowering (DIBL) for the two structures. The substrate current and hot electron degradation effect (HED) were measured and the results are compared for SDS and DPI techniques. It is shown that SDS structure reduces HED and surface punchthrough effects in sub-μm MOS transistors.     

Analysis of carbohydrates in seven edible fruits of Bangladesh

Dry matter, ash, lignin, starch and soluble and insoluble dietary fibre contents of the edible parts of seven fruits of Bangladesh were determined. Analysis of the low molecular weight carbohydrates showed that all the fiuits, except lukluki and hogplum, contained substantial amounts of these materials of which glucose and fiuctose were the main components. The main constituent of the polysaccharides in all the fruits was glucose. The dietary fibre contents of the dry fruits ranged from 29% to 79%. Lukluki has by far the best combination of low fiee sugars and high dietary fibre, and pineapple the worst.     

PAINT: Priority aware interference mitigation techniques for improving coexistence in home area networks of smart grid

As smart grid (SG) home area networks (HANs) communicate with various smart devices such as meters, sensors, and actuators on a 2.4‐GHz unlicensed band, the coexistence of different wireless technologies in such networks is a common phenomenon due to the overlapping of channels. In this research, homogeneous and heterogeneous interference are considered to address the coexistence problem in smart utility networks (SUNs). The homogeneous interference is mitigated by utilizing the contention free period (CFP) and the contention access period (CAP) of the MAC layer superframe of IEEE 802.15.4g designed for SUNs. This frame is used to get access for the channel. For this, a slotted CSMA/CA algorithm is used for various priority levels of data with adjustable backoff period (BP) and clear channel assessment (CCA) period in order that nodes (devices) with high priority can achieve high probability of channel access. By modeling the proposed scheme using the Markov chain, the exactness of the proposed scheme is assessed based on throughput, channel access delay, energy consumption per bit, and probability of successful data transmission and collision. A performance evaluation of the proposed scheme is further investigated by comparing it with the existing scheme PA‐MAC. In addition, a channel switching mechanism is explored to mitigate the heterogeneous interference with the help of a Naive Bayes classifier prediction. Finally, the prediction indicates that by choosing the non‐coexisting and the non‐overlapping channel, the proposed channel switching mechanism effectively mitigates the heterogeneous interference.     

Study of electrical and microstructure properties of high dielectric hafnium oxide thin film for MOS devices

Hafnium oxide (HfO₂) has emerged as the most promising highkdielectric for MOS devices. As-deposited sputtered HfO₂ thin films have large number of defects resulting in increased oxide charge and leakage current. In this paper the effect of sputtering voltage, bias sputtering and post deposition thermal annealing is investigated. The I–V and C–V characteristics of the dielectric film are studied employing Al–HfO₂–Si MOS capacitor structure. It is found that oxide charge increases with increasing sputtering voltage. Thermal annealing in oxygen reduces the interface/oxide charges and leakage current. It is shown that applying substrate bias during film deposition leakage current is further reduced by an order of magnitude. The microstructure of thin film is examined by AFM. The reduction in surface roughness with bias sputtering is shown. The experimental results are presented and discussed for device application.