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71.
Ainhoa Fernández-Tena Itziar Otaegi Lourdes Irusta Victor Sebastián Gonzalo Guerrica-Echevarria Alejandro Jesus Müller Nora Aranburu 《大分子材料与工程》2023,308(12):2300213
In this work, the effectiveness of seven commercial compatibilizers is tested in polylactide (PLA)/poly(ε-caprolactone) (PCL) blends with different compositions to obtain a high-impact PLA. None of the compatibilizers is effective for 90/10 and 80/20 PLA/PCL compositions, as no improvement of the impact strength is observed. For the 70/30 composition, compatibilizers having glycidyl methacrylate (GMA) and acrylate groups in their structure are proved the most effective, as the morphological change towards co-continuity induced by them leads to significant impact strength improvements (of ≈345% and 90% with respect to the neat PLA and the noncompatibilized PLA/PCL 70/30 blend, respectively). The 70/30 PLA/PCL composition, as it shows the best balance of properties, and the best compatibilizer (ElvaloyPTW) are chosen to carry out the optimization of the compatibilizer content. It is found that adding 6 phr to the blend results in highly toughened and ductile blends while maintaining a high modulus and yield strength values. Larger compatibilizer contents lead to even higher impact strength values, but the low-strain mechanical properties are notably reduced. Thus, in this work, a simple and easily scalable method to produce high-impact PLA is shown, as it implies the compounding of three commercially available components without involving any toxic solvents. 相似文献
72.
73.
The water time constant and mechanical time constant greatly influences the power and speed oscillations of hydro-turbine-generator unit. This paper discusses the turbine power transients in response to different nature and changes in the gate position. The work presented here analyses the characteristics of hydraulic system with an emphasis on changes in the above time constants. The simulation study is based on mathematical first-, second-, third- and fourth-order transfer function models. The study is further extended to identify discrete time-domain models and their characteristic representation without noise and with noise content of 10 & 20 dB signal-to-noise ratio (SNR). The use of self-tuned control approach in minimising the speed deviation under plant parameter changes and disturbances is also discussed. 相似文献
74.
It has been reported that treatment of wood surfaces with aqueous solutions of chromium trioxide imparts some beneficial properties like weather resistance and some degree of water repellency. The work presented here aims at finding alternative ways of fixing chromium in wood with the avoidance of the very acidic and strong oxidant conditions of chromic acid solutions. This is because these solutions may affect the strength of wood, and are known to have a very high human toxicity. In this study, chromium has been fixed into wood from hexavalent chromium solutions at pH's of ~1.5 (CrO3 aq.), ~3.8–3.9 (K2Cr2O7 aq.) and ~9.5–10.3 (K2CrO4 aq.). For the CrO3-solutions the effects of temperature and reaction time on the fixation of chromium were investigated. For the dichromate and chromate solutions, fixation experiments were carried out with Cr-concentration and reaction times as variables. It is shown that a 3%-fixation level of chromium in small wood specimens can be attained from dichromate and chromate solutions without significant mechanical damage to wood. On the other hand, even diluted CrO3-solutions (0.01 M) impart serious strength reductions in wood at temperatures of 90° C and higher when reacted for 8 hours, and the chromium content of wood resulting from such treatment is of the order of only 1%. 相似文献
75.
A method to prepare water sensitive composites employing crosslinked poly(vinyl amine) (PVAm) and Cu(II) ions as reticulation agent is disclosed in this work. This article presents in detail, the reticulation reaction and its pH dependence, as well as its electrical, rheological, and thermal properties of the PVAm‐Cu(II) composites obtained. The complex bonds formed between the Cu(II) ions and the amine groups of PVAm produce an interesting network of crosslinked structures that generate a microporous morphology when the material is extruded. This characteristic favors fast absorption of water when it is wetted, and a concomitant decrease in its apparent resistivity in a very short period of time. Furthermore, they present an excellent thermal stability and suitable processability. These characteristics make them interesting candidates to design ultra fast water sensors. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
76.
Luciana da Cunha Fernanda M. B. Coutinho Viviane G. Teixeira Edgar F. O. de Jesus Ailton S. Gomes 《Polymer Bulletin》2008,61(3):319-330
Polyacrylamide chains were grafted onto styrene-divinylbenzene (S-DVB) copolymer beads using gamma
radiation from a 60Co source by applying the simultaneous method. S-DVB macroporous
copolymer was synthesized by aqueous suspension polymerization and characterized by determining apparent
density, surface area, pore volume distribution and water uptake. Optical and electron microscopies
were used in order to observe the copolymer morphology. The effect of parameters such as monomers concentration,
irradiation dose and presence of inhibitor (Mohr’s salt) on grafting reaction was studied. The grafting
reaction was evaluated with the aid of elemental analysis, FTIR, HR-MAS NMR spectrometry, thermogravimetry
(TG) and electron microscopy. Grafting yield (evaluated by nitrogen content) increased with acrylamide
concentration and irradiation dose increasing. However, above determined values of those parameters
it is observed a tendency of decreasing on the grafting yield. The presence of Mohr’s salt inhibited
the production of homopolymer as well as the progress of the grafting reaction. 相似文献
77.
R. Mateus A. P. Jesus B. Braizinha J. Cruz J. V. Pinto J. P. Ribeiro 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2002,190(1-4):117-121
A method for proton-induced γ-ray analysis (PIGE) of Li (either elemental or isotopic composition) in thick samples is presented in this work, which is based on a code that integrates the nuclear reaction excitation function, measured at the same experimental conditions, along the depth of the sample. The energy steps needed to define accurately the excitation function are used as energy intervals for the integration procedure. The excitation function and cross-sections of the reaction 7Li(p,p′γ)7Li, for protons in the energy range 0.60–2.5 MeV, were obtained and used as input to calculate lithium concentrations in thick and intermediate samples. The calculated thick target yields of samples with several amounts of lithium were compared with the respective measured yields, showing that this is a reliable and accurate method for PIGE analysis of Li in thick samples. 相似文献
78.
Sintered nanoscale silver is a promising interconnection material for semiconductor devices because it provides improved joint properties compared with solder and wire bonds. It has higher electrical and thermal conductivity and is capable of higher operating temperature. Joints with die shear strength above 20 MPa can be formed at around 250°C even without applied pressure. Sintered silver joints were also found to be an order of magnitude more reliable than solder joints and wire bonds. In this work, the electromigration behavior of sintered nanosilver material under conditions of high applied current density and elevated temperature was investigated. Thin strips of sintered nanosilver formed on ceramic substrates were tested under current densities exceeding 150 kA/cm2 at temperatures of 150°C and above. Results based on the percentage change in sample resistance showed that the sintered silver lasted at least ten times longer than aluminum wire bonds. Examination of failed strips revealed that hairline cracks formed during sintering were the main cause of failure. Otherwise, defect-free samples exhibited a 10-fold increase in lifetime over wire bonds under similar conditions. 相似文献
79.
Patrícia ValderramaRonei Jesus Poppi 《Chemometrics and Intelligent Laboratory Systems》2011,106(2):160-165
The second order standard addition method and spectrofluorimetry were used for determination of ibuprofen enantiomers in human plasma and urine. The methodology was based on chiral recognition of ibuprofen by formation of an inclusion complex with a chiral auxiliary, β-cyclodextrin, in the presence of 1-butanol. The strategy combines the use of PARAFAC, for extraction of the pure analyte signal, with the standard addition method, for determinations in presence of a matrix effect. A specific PARAFAC model was built for each sample and the scores were related to (S)-ibuprofen concentration using a linear regression in the standard addition method. Feasible results were obtained for determinations in the molar fraction range from 50 to 80% of (S)-ibuprofen, providing absolute errors lowers than 4.0% for plasma and urine. 相似文献
80.
Martin Me Court Eric Imbert Pascale Vincensini-fort Jérôme Mars Hervé Ribot Dominique Persegol Thierry Jacquemin Josette Toussan-berger Denis Trystram José Camargo da Costa Mahmoud Helal Atman Guerchaoui Noureddine Mhaya Ignacio Jesus Ania de Briseno Chien Nguyen Duc Laurent Chety 《电信纪事》1989,44(3-4):194-197