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91.
氧化钨物理特征的测量 总被引:2,自引:0,他引:2
对铵钨青铜(ATB)、氢钨青铜(HTB),紫色氧化钨(TVO)和蓝色氧化钨(TBO)四种氧化钨粉的氮气吸附/脱附等温线数据的分析。可以得出其表面积,微孔体积,微孔分布,中孔体积,平均孔径和分数维数。吸附/脱附等温线数据的分析表明,TVO粉末具有最大的中孔体积,最小的微孔体积,最窄的孔径分布,最小的分数维数和最大的平均孔径,其有利于氢还原制取超细钨粉,而不利于掺杂工艺,HTB粉末具有最大的微孔体积,最宽的孔径分布,最高的分数维数和最小的平均孔径,对于掺杂工艺来说是有利的,ATB和ABO的上述参数界于TVO和HTB之间。结果表明,利用吸附/脱附等温线来研究氧化物的物理特征是一个很好的方法;在氧化钨用于氢还原工艺和掺杂工艺之前必须研究其物理特征。 相似文献
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Flame structure and NO emission characteristics in counterflow diffusion flame of blended fuel of H2/CO2/Ar have been numerically simulated with detailed chemistry. The combination of H2, CO2 and Ar as fuel is selected to clearly display the contribution of hydrocarbon products to flame structure and NO emission characteristics due to the breakdown of CO2. A radiative heat loss term is involved to correctly describe the flame dynamics especially at low strain rates. The detailed chemistry adopts the reaction mechanism of GRI 2.11, which consists of 49 species and 279 elementary reactions. All mechanisms including thermal, NO2, N2O and Fenimore are taken into account to separately evaluate the effects of CO2 addition on NO emission characteristics. The increase of added CO2 quantity causes flame temperature to fall since at high strain rates a diluent effect is prevailing and at low strain rates the breakdown of CO2 produces relatively populous hydrocarbon products and thus the existence of hydrocarbon products inhibits chain branching. It is also found that the contribution of NO production by N2O and NO2 mechanisms are negligible and that thermal mechanism is concentrated on only the reaction zone. As strain rate and CO2 quantity increase, NO production is remarkably augmented. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
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This letter investigates the scattering characteristic of the rivets on aircraft.The electric Field Integral Equation (EFIE)is used with the moment to calculate the current distribution on the surface of the rivet.With the application of Gaussian integral corresponding triangular cell,the time to fill the Z matrix is greatly reduced.Finally,the RCS of a type of rivet on aircraft is analyzed. 相似文献
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T.J. ChungJ.H. Park C.K. Choi D.-Y. Yoon 《International Journal of Heat and Mass Transfer》2002,45(14):3061-3064
The onset of convective instability in a fluid-saturated porous layer between the two horizontal plates heated isothermally from below has been analyzed theoretically by using propagation theory. In the analysis the thermal dispersion coefficient is assumed to be proportional to the streamwise velocity. The results show that both inertia and thermal dispersion stabilize the system. 相似文献
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Propolis collected by bees has many components that possess antifungal, anticancer and antioxidant properties. Cured ground pork meat was treated separately with 0.4% w/w ethanol‐extracted propolis (EEP 0.4%), 0.6% w/w water‐extracted propolis (WEP 0.6%), 0.8% w/w dried residue of ethanol‐extracted propolis (DREEP 0.8%) and 0.1% w/w potassium sorbate (PS 0.1%) and made into sausages. Thiobarbituric acid‐reactive substances (TBARS) were measured in the sausages to assess the effects of storage at 5, 10 and 20 °C after 0, 2 and 4 weeks. After 4 weeks of storage at 5 °C the sausages treated with EEP 0.4%, DREEP 0.8%, WEP 0.6% and PS 0.1% yielded TBARS values which were 50, 59, 35 and 91% respectively of the control value. There was an increase of 0.33 mg MDA kg?1, the lowest of all treatments, in TBARS for the 0.4% w/w EEP‐treated sausages. The curing process will control microbiological spoilage, as will potassium sorbate. © 2002 Society of Chemical Industry 相似文献
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