全文获取类型
收费全文 | 170565篇 |
免费 | 8062篇 |
国内免费 | 3844篇 |
专业分类
电工技术 | 5680篇 |
技术理论 | 5篇 |
综合类 | 7843篇 |
化学工业 | 26798篇 |
金属工艺 | 10056篇 |
机械仪表 | 8408篇 |
建筑科学 | 9980篇 |
矿业工程 | 3122篇 |
能源动力 | 3445篇 |
轻工业 | 8858篇 |
水利工程 | 2810篇 |
石油天然气 | 5575篇 |
武器工业 | 683篇 |
无线电 | 18358篇 |
一般工业技术 | 26483篇 |
冶金工业 | 7063篇 |
原子能技术 | 1313篇 |
自动化技术 | 35991篇 |
出版年
2024年 | 359篇 |
2023年 | 1491篇 |
2022年 | 2418篇 |
2021年 | 3341篇 |
2020年 | 2622篇 |
2019年 | 2185篇 |
2018年 | 16528篇 |
2017年 | 15850篇 |
2016年 | 12159篇 |
2015年 | 3839篇 |
2014年 | 4337篇 |
2013年 | 5237篇 |
2012年 | 8618篇 |
2011年 | 15112篇 |
2010年 | 13133篇 |
2009年 | 10375篇 |
2008年 | 11392篇 |
2007年 | 12226篇 |
2006年 | 4984篇 |
2005年 | 5527篇 |
2004年 | 3991篇 |
2003年 | 3640篇 |
2002年 | 2819篇 |
2001年 | 2113篇 |
2000年 | 2474篇 |
1999年 | 2734篇 |
1998年 | 2231篇 |
1997年 | 1801篇 |
1996年 | 1867篇 |
1995年 | 1491篇 |
1994年 | 1221篇 |
1993年 | 866篇 |
1992年 | 711篇 |
1991年 | 576篇 |
1990年 | 402篇 |
1989年 | 332篇 |
1988年 | 279篇 |
1987年 | 184篇 |
1986年 | 123篇 |
1985年 | 88篇 |
1984年 | 57篇 |
1983年 | 36篇 |
1982年 | 40篇 |
1968年 | 43篇 |
1966年 | 42篇 |
1965年 | 46篇 |
1958年 | 37篇 |
1957年 | 36篇 |
1955年 | 63篇 |
1954年 | 68篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
Bing Yang Yu Zhou Wenjie Yu Song Zhang Hongxiang Chen Ju Ye 《Polymer International》2019,68(4):675-683
In order to improve the dispersity and stability of the nano‐SiO2 aqueous system with high solid content, a kind of polyacrylic acid dispersant with methoxysilicon end groups (KH590‐PAA) was synthesized by photopolymerization of acrylic acid (AA) initiated with (3‐mercaptopropyl)trimethoxysilane (KH590). After adding KH590‐PAA into the nano‐SiO2 aqueous dispersion system (20 wt% solid content), the viscosity and the curing time of the system were measured with a rotational viscometer and the inverted bottle method. Moreover, the dispersion mechanism of KH590‐PAA for the nano‐SiO2 aqueous system was researched by measuring the adsorption capacity, the particle size and the zeta potential of the nanoparticles with a conductivity meter, dynamic light scattering, SEM and TEM, respectively. The results showed that the methoxysilicon groups in KH590‐PAA could react with hydroxyl groups on the surface of nano‐SiO2 in the process of stirring, which enhanced the adsorption capacity of the dispersant and then increased the surface charge of the particles. Therefore, electrostatic repulsion and steric hindrance effects between the SiO2 nanoparticles could be further enhanced by adding the KH590‐PAA dispersant, and then the nano‐SiO2 aqueous system exhibited better dispersity and stability. Besides, the dispersion properties of SiO2 nanoparticles in water were closely related to the addition amount and the molecular weight of the KH590‐PAA dispersant. © 2018 Society of Chemical Industry 相似文献
42.
Kang Zhang Rong‐rong Wang Kai‐rui Zhang Fei Cheng Yu Tian Yi Lin Mi Zhou Pu‐xin Zhu 《Polymer International》2020,69(3):274-279
A series of hyperbranched poly(citric polyethylene glycol) (PCPEG) materials with varied polyethylene glycol (PEG) chain lengths as plasticizers were mixed with maize starch (MS) via cooking and film‐forming. The structure, pasting property, plasticization, aging property, moisture absorption and compatibility of plasticized starches were studied by means of Fourier transform infrared spectroscopy, X‐ray diffraction, rapid viscosity analysis, tension testing, moisture absorption measurements and scanning electron microscopy. Compared with PEG and citric acid, PCPEG was more effective in promoting starch chain movement and inhibiting the retrogradation of starch film. Also, PCPEG/MS had smaller moisture content. The longer the plasticizer chain, the better were the aging resistance and moisture resistance of starch. But with an increase of PEG chain length, mechanical properties of PCPEG/MS deteriorated and the compatibility between PCPEG and MS decreased. The hyperbranched derivative of PEG with longer chain exhibited improved plasticization and compatibility with starch. © 2019 Society of Chemical Industry 相似文献
43.
44.
Chaoxin Li Yi Zhou Yuming Tian Yuanyuan Zhao Kaiyue Wang Guomin Li Yuesheng Chai 《Ceramics International》2019,45(5):5613-5616
Ceramics with mullite whiskers were prepared from coal fly ash and Al2O3 raw materials, with AlF3 used as an additive. The phase structures and microstructures of the ceramics were identified via X-ray diffraction and scanning electron microscopy, respectively. The results show that pickling of coal fly ash is an effective method for enhancing the flexural strength of ceramics. Sintering temperature and AlF3 addition were also key factors influencing the creation of ideal ceramics. The ceramic made from pickled coal fly ash, 6?wt% AlF3, and sintered at 1200?°C, exhibited the highest flexural strength of 59.1?MPa, and had a bulk density of 1.32?g/cm3 and porosity of 26.8%. The results show that ceramic materials made under these conditions are ideal candidates for manufacturing ceramic proppants for the exploitation of unconventional oil and gas resources. 相似文献
45.
46.
三元复合驱油体系中驱油剂的协同效应,会使油水间的界面张力大幅度下降,原油采收率大幅度提高;但三元复合驱油体系的色谱分离现象也会破坏其协同效应和完整性,揭示色谱分离现象及其影响因素对于改善三元复合驱油效果具有十分重要意义。以油藏工程和分析化学理论为指导,以化学分析和物理模拟为技术途径,并以大庆喇嘛甸油田典型区块地质特征和流体性质为研究对象,开展强碱三元复合驱色谱分离现象及其影响因素研究。结果表明,采用前置高浓度聚合物段塞后,可以有效扩大波及体积,但表面活性剂与碱和聚合物之间无因次等浓距增加,色谱分离现象加剧。大庆油区喇嘛甸油田不同区块油水性质差异对色谱分离现象存在影响,原因在于部分重烷基苯石油磺酸进入油相,影响水相中浓度检测值。强碱三元复合驱油体系中表面活性剂与碱和聚合物之间色谱分离程度比较严重,碱与聚合物之间较弱。 相似文献
47.
48.
Strength of Materials - A metallographic method, dilatometry, and X-ray diffraction were applied to investigate the effects of undercooling and holding time on bainitic transformation,... 相似文献
49.
In this study, 30 subjects were exposed to different combinations of air temperature (Ta: 24, 27, and 30°C) and CO2 level (8000, 10 000, and 12 000 ppm) in a high-humidity (RH: 85%) underground climate chamber. Subjective assessments, physiological responses, and cognitive performance were investigated. The results showed that as compared with exposure to Ta = 24°C, exposure to 30°C at all CO2 levels caused subjects to feel uncomfortably warm and experience stronger odor intensity, while increased mental effort and greater intensity of acute health symptoms were reported. However, no significant effects of Ta on task performance or physiological responses were found. This indicated that subjects had to exert more effort to maintain their performance in an uncomfortably warm environment. Increasing CO2 from 8000 to 12 000 ppm at all Ta caused subjects to report higher rates of headache, fatigue, agitation, and feeling depressed, although the results were statistically significant only at 24 and 27°C. The text typing performance and systolic blood pressure (SBP) decreased significantly at this exposure, whereas diastolic blood pressure (DBP) and thermal discomfort increased significantly. These effects suggest higher arousal/stress. No significant interaction effect of Ta and CO2 concentration on human responses was identified. 相似文献
50.
Anti-washout and tissue adhesion properties are essential for the clinical application of injectable bone materials. In this study, we prepared calcium phosphate cement (CPC) with anti-washout and tissue adhesion properties and attempted to build covalent bonds between CPC and the amino groups in bone tissue under a self-regulating pH system in the CPC (acidic to basic). The results of push-out tests demonstrated that a significant enhancement (from 6.42 ± 0.76 N to 61.5 ± 4.09 N) in tissue adhesion was obtained with the addition of 6% (w/w) oxidized sodium alginate (OSA) in CPC. The FTIR, XRD, anti-washout test, XPS, pH test, and SEM results suggested that the synergistic effect of OSA-citric acid (CA) led to the formation of a three-dimensional gel network structure in the CPC, and the Schiff base reaction between aldehyde and amino groups induced adhesion between CPC and the bone tissue. Further, the addition of less OSA had no significant negative effect on the hydration properties of CPC. Our work aims to promote the development of injectable bone material in clinical applications. 相似文献