双膦胺镍-甲基铝氧烷体系催化苯乙烯聚合

研究了具有新型结构的双膦胺镍配合物N,N-双(二苯膦基)-对甲氧基苯胺二氯化镍-甲基铝氧烷(PNP-N i-MAO)催化体系对苯乙烯聚合的催化性能,考察了聚合温度、n(A l)∶n(PNP-N i)、PNP-N i的浓度和苯乙烯的浓度对催化活性、苯乙烯转化率、聚苯乙烯相对分子质量及其分布的影响,并用核磁共振和凝胶色谱对聚苯乙烯的结构进行了表征。实验结果表明,在聚合温度25℃、聚合时间1h、n(A l)∶n(PNP-N i)=300、c(苯乙烯)=2.3m ol/L、c(PNP-N i)=0.4mm ol/L、甲苯为溶剂的适宜条件下,苯乙烯的转化率可达95%以上,催化活性达到5×105g/(m ol.h)左右。核磁共振和凝胶色谱表征结果显示,所得聚苯乙烯为无规结构,重均相对分子质量约为1×104,相对分子质量分布Mw/Mn约为2。     

现代印刷与传统印刷的碰撞

印刷术的发明是中国人的骄傲。从1041年毕升发明活字印刷算起，经历了近千年的磨砺。“当代毕升”王选教授研制成功的中国汉字北大方正印前桌面系统，彻底淘汰了热排，淘汰了铅与火，改写了印前排版的历史，成为近代印刷的里程碑。虽然王选先生永远地离开了我们，但他对我国出版印刷事业所作的贡献将飚炳史册，光耀千秋。     

从做大到做强的主体是PCB企业（集团） 中国PCB工业如何从做大到做强!（6）

从做大到做强是中国PCB工业的唯一出路.而做强中国PCB工业的主体是中国的PCB企业(集团).只有大多数的中国PCB企业做大并做强了,中国PCB工业才能称得上是PCB强国.     

一种基于ECDSA的USB存储设备访问控制方案

文章针对使用USB存储设备造成的内部泄密问题,提出了一种USB存储设备访问控制方案,该方案对用户的身份认证基于安全强度很高的椭圆曲线数字签名算法,同时使用过滤器驱动程序实现了USB存储设备的读写控制,因而此方案具有较好的安全性、实用性和通用性。     

膨胀套管的弹塑性理论分析

分析认为，膨胀套管在膨胀过程中先进入弹性阶段，然后进入弹塑性阶段，最后进入塑性流动阶段。采用弹塑性分析方法，对膨胀套管膨胀过程中套管内壁的受力与变形进行了研究，模拟了其成形的过程，并建立了解析解，为膨胀套管膨胀操作过程中确定关键操作参数提供了理论支持。根据推导出的力学模型，计算出了外径107．9mm、钢级为J55的膨胀套管膨胀到直径139．7mm时膨胀芯头拉头处的轴向力为195．94kN。     

周宁水电站工程项目管理实践

福建周宁水电站工程由闽东水电开发有限公司负责项目管理。该项目严格按照《招投标法》进行工程和设备的招标,进行了多项设计优化,注重工程质量和安全文明生产,积极开展达标投产工作,实现了进度快、质量优、投资省、效益好的管理目标。     

PCI接口芯片s5935及其应用

s5935是AMCC公司生产的PCI接口芯片 ,可实现直通 (PASS-THRU)、邮箱 (MAILBOX)、FI FO/DMA三种工作方式。文章简要介绍了这三种工作方式 ,并给出了s5935的WDM驱动编程。     

An object replication algorithm for real-time distributed databases

A real-time distributed database system (RTDDBS) must maintain the consistency constraints of objects and must also guarantee the time constraints imposed by each request arriving at the system. Such a time constraint of a request is usually defined as a deadline period, which means that the request must be serviced on or before its time constraint. Servicing these requests may incur I/O costs, control-message transferring costs or data-message transferring costs. As a result, in our work, we first present a mathematical model that considers all these costs. Using this cost model, our objective is to service all the requests on or before their respective deadline periods and minimize the total servicing cost. To this end, from theoretical standpoint, we design a dynamic object replication algorithm, referred to as Real-time distributed dynamic Window Mechanism (RDDWM), that adapts to the random patterns of read-write requests. Using competitive analysis, from practical perspective, we study the performance of RDDWM algorithm under two different extreme conditions, i.e., when the deadline period of each request is sufficiently long and when the deadline period of each request is very short. Several illustrative examples are provided for the ease of understanding. Recommended by: Ashfaq Khokhar     

Personal telecommunication radiation safety and the precautionary principle

The approach to risk management for RF and microwave radiation has been to establish guidelines for maximum permissible levels of exposure. These guidelines are based on evaluations of the relevant scientific literature and, with safety margins to account for uncertainties and gaps in scientific knowledge, offer a significant level of protection against established hazards of RF and microwave radiation for short-term exposures. One can argue, on this basis, that the precautionary principle - specifically, safety factors -have been used to guide the making and promulgation of existing permissible-exposure standards for RF and microwave radiation. Therefore, discussions on the appropriateness of the precautionary principle for RF radiation may be "much ado about nothing". Clearly, this approach to "pre caution" neither has stifled technological development, nor has it helped to enforce the acceptance of zero risk, but it provided a basis for action when science was unable to give a clear answer.